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Investigation on the improved hydrolysis of aluminum–calcium hydride-salt mixture elaborated by ball milling

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Listed:
  • Liu, Yongan
  • Wang, Xinhua
  • Liu, Haizhen
  • Dong, Zhaohui
  • Li, Shouquan
  • Ge, Hongwei
  • Yan, Mi

Abstract

A novel Al based hydrogen production material is prepared by high energy ball milling using Al, CaH2 and different salts as the starting materials. The parameters affecting the Al–H2O reaction are investigated and discussed. Among the salts added, NiCl2 shows the best activation capability. The addition amount of both CaH2 and NiCl2 is found to be an important factor affecting the hydrolysis process during which a kind of hydrocalumite, Ca2Al(OH)6Cl(H2O)2, is generated and facilitates the removal of the by-product layer. Milling time can also generate significant impacts on the hydrogen generation performances of the mixture and 3 h proves to be the optimum choice in this work. The 3 h milled Al-10 mol% CaH2-10 mol% NiCl2 sample shows a hydrogen yield of 92.1% and mHGR (maximum hydrogen generation rate) of 1566.3 ml min−1 g−1. A preliminary study is carried out to understand the optimization mechanisms.

Suggested Citation

  • Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Investigation on the improved hydrolysis of aluminum–calcium hydride-salt mixture elaborated by ball milling," Energy, Elsevier, vol. 84(C), pages 714-721.
    • Handle: RePEc:eee:energy:v:84:y:2015:i:c:p:714-721
    DOI: 10.1016/j.energy.2015.03.035
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    References listed on IDEAS

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    1. Liu, Yongan & Wang, Xinhua & Dong, Zhaohui & Liu, Haizhen & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2013. "Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3," Energy, Elsevier, vol. 53(C), pages 147-152.
    2. Fan, Mei-Qiang & Liu, Shu-sheng & Zhang, Yao & Zhang, Jian & Sun, Li-Xian & Xu, Fen, 2010. "Superior hydrogen storage properties of MgH2–10 wt.% TiC composite," Energy, Elsevier, vol. 35(8), pages 3417-3421.
    3. Macanás, Jorge & Soler, Lluís & Candela, Angélica María & Muñoz, Maria & Casado, Juan, 2011. "Hydrogen generation by aluminum corrosion in aqueous alkaline solutions of inorganic promoters: The AlHidrox process," Energy, Elsevier, vol. 36(5), pages 2493-2501.
    4. Zhao, Zhongwei & Chen, Xingyu & Hao, Mingming, 2011. "Hydrogen generation by splitting water with Al–Ca alloy," Energy, Elsevier, vol. 36(5), pages 2782-2787.
    5. Fan, Mei-qiang & Sun, Li-xian & Xu, Fen, 2010. "Feasibility study of hydrogen production for micro fuel cell from activated Al–In mixture in water," Energy, Elsevier, vol. 35(3), pages 1333-1337.
    6. Fan, Mei–qiang & Sun, Li–xian & Xu, Fen, 2010. "Experiment assessment of hydrogen production from activated aluminum alloys in portable generator for fuel cell applications," Energy, Elsevier, vol. 35(7), pages 2922-2926.
    7. Huang, Yao-Hui & Su, Chia-Chi & Wang, Shu-Ling & Lu, Ming-Chun, 2012. "Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis," Energy, Elsevier, vol. 46(1), pages 242-247.
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    Cited by:

    1. Yang, Weijuan & Zhang, Tianyou & Liu, Jianzhong & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature," Energy, Elsevier, vol. 93(P1), pages 451-457.
    2. Su, Ming & Hu, Haiping & Gan, Jianchang & Ye, Wenhua & Zhang, Wenhua & Wang, Huihu, 2021. "Thermodynamics, kinetics and reaction mechanism of hydrogen production from a novel Al alloy/NaCl/g-C3N4 composite by low temperature hydrolysis," Energy, Elsevier, vol. 218(C).
    3. Guan, Xu & Zhou, Zheng & Luo, Ping & Wu, Fengshun & Dong, Shijie, 2019. "Hydrogen generation from the reaction of Al-based composites activated by low-melting-point metals/oxides/salts with water," Energy, Elsevier, vol. 188(C).
    4. Xiao, Fei & Guo, Yanpei & Li, Jianmin & Yang, Rongjie, 2018. "Hydrogen generation from hydrolysis of activated aluminum composites in tap water," Energy, Elsevier, vol. 157(C), pages 608-614.
    5. Xiao, Fei & Yang, Rongjie & Li, Jianmin, 2019. "Hydrogen generation from hydrolysis of activated aluminum/organic fluoride/bismuth composites with high hydrogen generation rate and good aging resistance in air," Energy, Elsevier, vol. 170(C), pages 159-169.
    6. Guo, Junyan & Gao, Ruihong & Tong, Zhaoming & Zhang, Haijun & Duan, Hongjuan & Huang, Liang & Lu, Lilin & Jia, Quanli & Zhang, Shaowei, 2023. "Three eagles with one arrow: Simultaneous production of hydrogen, aluminum ethoxide, and supported metal catalysts via efficient and facile reaction between aluminum and ethanol," Energy, Elsevier, vol. 263(PD).

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