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Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis

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  • Huang, Yao-Hui
  • Su, Chia-Chi
  • Wang, Shu-Ling
  • Lu, Ming-Chun

Abstract

A recyclable and reusable Ru/Al2O3 catalyst is prepared for hydrogen generation from the hydrolysis process of alkaline sodium borohydride (NaBH4) solution. The hydrogen generation rate by the hydrolysis and methanolysis of alkaline NaBH4 was explored as a function of NaOH concentration. Meantime, the byproducts derived from the spent alkaline NaBH4 solution were characterized by X-ray diffraction (XRD), scanning electro microscope/energy dispersive spectrometer (SEM/EDS) and NMR (Nuclear Magnetic Resonance). The effect of NaOH concentration on the hydrogen generation from the hydrolysis of NaBH4 significantly depends on the type of catalysts. With increasing NaOH concentration, the hydrogen generation rates decrease when using ruthenium (Ru) composite as a catalyst. The hydrogen generation rate of the methanolysis of NaBH4 is significantly inhibited in the presence of NaOH as compared with the hydrolysis of NaBH4. The durability test of the Ru/Al2O3 catalyst shows that the hydrogen generation rate decreases with recycling and reuse. The XRD and NMR analysis results show that the borate hydrate (NaBO2 H2O) was derived from the hydrolysis of 20 wt% and 30 wt% NaBH4.

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  • Huang, Yao-Hui & Su, Chia-Chi & Wang, Shu-Ling & Lu, Ming-Chun, 2012. "Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis," Energy, Elsevier, vol. 46(1), pages 242-247.
    • Handle: RePEc:eee:energy:v:46:y:2012:i:1:p:242-247
    DOI: 10.1016/j.energy.2012.08.027
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    1. Li, Qiming & Chen, Yingbo & Lee, Dong Joo & Li, Fang & Kim, Hern, 2012. "Preparation of Y-zeolite/CoCl2 doped PVDF composite nanofiber and its application in hydrogen production," Energy, Elsevier, vol. 38(1), pages 144-150.
    2. Chinnappan, Amutha & Kang, Hyuck-Chul & Kim, Hern, 2011. "Preparation of PVDF nanofiber composites for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 36(2), pages 755-759.
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    5. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Investigation on the improved hydrolysis of aluminum–calcium hydride-salt mixture elaborated by ball milling," Energy, Elsevier, vol. 84(C), pages 714-721.
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    9. Oh, Taek Hyun & Gang, Byeong Gyu & Kim, Hyuntak & Kwon, Sejin, 2015. "Sodium borohydride hydrogen generator using Co–P/Ni foam catalysts for 200 W proton exchange membrane fuel cell system," Energy, Elsevier, vol. 90(P1), pages 1163-1170.
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    11. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Effect of salts addition on the hydrogen generation of Al–LiH composite elaborated by ball milling," Energy, Elsevier, vol. 89(C), pages 907-913.
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