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Hydrogen generation from hydrolysis of activated aluminum composites in tap water

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  • Xiao, Fei
  • Guo, Yanpei
  • Li, Jianmin
  • Yang, Rongjie

Abstract

Activated aluminum composites Al-X(X = Sn, Bi, Bi-Sn) were prepared by high-energy milling, and characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Their hydrogen generation was systematically investigated in tap water. The experimental results suggest that the ternary Al-Bi-Sn composites show the better hydrolysis properties than binary composites Al-Bi and Al-Sn owing to the synergistic effect of metal Bi and Sn. The 3 h milled Al-7.5%Bi-2.5%Sn composite exhibits the highest hydrogen conversion yield with the maximum hydrogen generation rate of 9.5 mL s−1 g−1 at 35 °C. In addition, the effect of initial reaction temperature and water quality on the hydrolysis properties, the methods of protecting the activity of activated Al composites are discussed as well.

Suggested Citation

  • Xiao, Fei & Guo, Yanpei & Li, Jianmin & Yang, Rongjie, 2018. "Hydrogen generation from hydrolysis of activated aluminum composites in tap water," Energy, Elsevier, vol. 157(C), pages 608-614.
    • Handle: RePEc:eee:energy:v:157:y:2018:i:c:p:608-614
    DOI: 10.1016/j.energy.2018.05.201
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    References listed on IDEAS

    as
    1. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Effect of salts addition on the hydrogen generation of Al–LiH composite elaborated by ball milling," Energy, Elsevier, vol. 89(C), pages 907-913.
    2. Sun, Qian & Zou, Meishuai & Guo, Xiaoyan & Yang, Rongjie & Huang, Haitao & Huang, Peng & He, Xiangdong, 2015. "A study of hydrogen generation by reaction of an activated Mg–CoCl2 (magnesium–cobalt chloride) composite with pure water for portable applications," Energy, Elsevier, vol. 79(C), pages 310-314.
    3. Yang, Weijuan & Zhang, Tianyou & Zhou, Junhu & Shi, Wei & Liu, Jianzhong & Cen, Kefa, 2015. "Experimental study on the effect of low melting point metal additives on hydrogen production in the aluminum–water reaction," Energy, Elsevier, vol. 88(C), pages 537-543.
    4. Liu, Yongan & Wang, Xinhua & Dong, Zhaohui & Liu, Haizhen & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2013. "Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3," Energy, Elsevier, vol. 53(C), pages 147-152.
    5. Zou, Mei-Shuai & Huang, Hai-Tao & Sun, Qian & Guo, Xiao-Yan & Yang, Rong-Jie, 2014. "Effect of the storage environment on hydrogen production via hydrolysis reaction from activated Mg-based materials," Energy, Elsevier, vol. 76(C), pages 673-678.
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    Cited by:

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    3. Su, Ming & Hu, Haiping & Gan, Jianchang & Ye, Wenhua & Zhang, Wenhua & Wang, Huihu, 2021. "Thermodynamics, kinetics and reaction mechanism of hydrogen production from a novel Al alloy/NaCl/g-C3N4 composite by low temperature hydrolysis," Energy, Elsevier, vol. 218(C).
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    5. Xinyue Gao & Chang’an Wang & Wengang Bai & Yujie Hou & Defu Che, 2022. "Aluminum-Based Fuels as Energy Carriers for Controllable Power and Hydrogen Generation—A Review," Energies, MDPI, vol. 16(1), pages 1-22, December.
    6. Xiao, Fei & Yang, Rongjie & Li, Jianmin, 2019. "Hydrogen generation from hydrolysis of activated aluminum/organic fluoride/bismuth composites with high hydrogen generation rate and good aging resistance in air," Energy, Elsevier, vol. 170(C), pages 159-169.
    7. Ma, Miaolian & Yang, Lingli & Ouyang, Liuzhang & Shao, Huaiyu & Zhu, Min, 2019. "Promoting hydrogen generation from the hydrolysis of Mg-Graphite composites by plasma-assisted milling," Energy, Elsevier, vol. 167(C), pages 1205-1211.

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