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Preparation and characterization of novel MicroPCMs (microencapsulated phase-change materials) with hybrid shells via the polymerization of two alkoxy silanes

Author

Listed:
  • Li, Wenhong
  • Song, Guolin
  • Li, Shuhua
  • Yao, Youwei
  • Tang, Guoyi

Abstract

MicroPCMs (microencapsulated phase-change materials) were successfully synthesized using MPS (3-(trimethoxysilyl) propyl methacrylate) and VTMS (vinyltrimethoxysilane) as raw materials for hybrid shells, and n-octadecane as core materials. DSC (differential scanning calorimeter) results show that two types of crystals form in core materials of all MicroPCMs during crystallization. The weight ratio of MPS–VTMS, and pH values play significant roles on the performance of final product: n-Octadecane content of MicroPCMs increases from 58.7 wt.% to 76.0 wt.% and their thermal degradation temperature (2 wt.% weight loss) increases from 182.6 °C to 188.9 °C with the weight ratio of MPS–VTMS decreasing from 8:0 to 2:6 in neutral synthesis systems. However, the encapsulation of n-octadecane failed when only using VTMS as hybrid shell precursor; When the weight ratio of MPS–VTMS is fixed to 2:6, the encapsulation efficiency decreases in acidic or basic synthesis systems. The optimized final product, i.e., MicroPCMs obtained with the weight ratio of MPS–VTMS equaling to 2:6 in neutral conditions, display a best thermal properties with highest melting and crystallization latent heat of 166.74 J g−1 and 169.35 J g−1, and the n-octadecane content decreases only by 7.0 wt.% and 10.8 wt.% after thermal treatment and thermal cycling test, respectively.

Suggested Citation

  • Li, Wenhong & Song, Guolin & Li, Shuhua & Yao, Youwei & Tang, Guoyi, 2014. "Preparation and characterization of novel MicroPCMs (microencapsulated phase-change materials) with hybrid shells via the polymerization of two alkoxy silanes," Energy, Elsevier, vol. 70(C), pages 298-306.
  • Handle: RePEc:eee:energy:v:70:y:2014:i:c:p:298-306
    DOI: 10.1016/j.energy.2014.03.125
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    1. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    2. Salunkhe, Pramod B. & Shembekar, Prashant S., 2012. "A review on effect of phase change material encapsulation on the thermal performance of a system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5603-5616.
    3. Tyagi, V.V. & Kaushik, S.C. & Tyagi, S.K. & Akiyama, T., 2011. "Development of phase change materials based microencapsulated technology for buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1373-1391, February.
    4. Li, Wei & Zhang, Xing-xiang & Wang, Xue-chen & Tang, Guo-yi & Shi, Hai-feng, 2012. "Fabrication and morphological characterization of microencapsulated phase change materials (MicroPCMs) and macrocapsules containing MicroPCMs for thermal energy storage," Energy, Elsevier, vol. 38(1), pages 249-254.
    5. Yin, Dezhong & Ma, Li & Liu, Jinjie & Zhang, Qiuyu, 2014. "Pickering emulsion: A novel template for microencapsulated phase change materials with polymer–silica hybrid shell," Energy, Elsevier, vol. 64(C), pages 575-581.
    6. Tahan Latibari, Sara & Mehrali, Mohammad & Mehrali, Mehdi & Indra Mahlia, Teuku Meurah & Cornelis Metselaar, Hendrik Simon, 2013. "Synthesis, characterization and thermal properties of nanoencapsulated phase change materials via sol–gel method," Energy, Elsevier, vol. 61(C), pages 664-672.
    7. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    8. Li, Gang & Hwang, Yunho & Radermacher, Reinhard & Chun, Ho-Hwan, 2013. "Review of cold storage materials for subzero applications," Energy, Elsevier, vol. 51(C), pages 1-17.
    9. Zhang, Xiongwen & Kong, Xin & Li, Guojun & Li, Jun, 2014. "Thermodynamic assessment of active cooling/heating methods for lithium-ion batteries of electric vehicles in extreme conditions," Energy, Elsevier, vol. 64(C), pages 1092-1101.
    10. He, Fang & Wang, Xiaodong & Wu, Dezhen, 2014. "New approach for sol–gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor," Energy, Elsevier, vol. 67(C), pages 223-233.
    11. Bouadila, Salwa & Kooli, Sami & Skouri, Safa & Lazaar, Mariem & Farhat, Abdelhamid, 2014. "Improvement of the greenhouse climate using a solar air heater with latent storage energy," Energy, Elsevier, vol. 64(C), pages 663-672.
    12. Qiu, Xiaolin & Li, Wei & Song, Guolin & Chu, Xiaodong & Tang, Guoyi, 2012. "Microencapsulated n-octadecane with different methylmethacrylate-based copolymer shells as phase change materials for thermal energy storage," Energy, Elsevier, vol. 46(1), pages 188-199.
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    4. Qian, Tingting & Li, Jinhong & Min, Xin & Deng, Yong & Guan, Weimin & Ma, Hongwen, 2015. "Polyethylene glycol/mesoporous calcium silicate shape-stabilized composite phase change material: Preparation, characterization, and adjustable thermal property," Energy, Elsevier, vol. 82(C), pages 333-340.
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    6. Han, Pengju & Lu, Lixin & Qiu, Xiaolin & Tang, Yali & Wang, Jun, 2015. "Preparation and characterization of macrocapsules containing microencapsulated PCMs (phase change materials) for thermal energy storage," Energy, Elsevier, vol. 91(C), pages 531-539.

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