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Exergy analysis of alkanolamine-based CO2 removal unit with AspenPlus

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  • Geuzebroek, F.H.
  • Schneiders, L.H.J.M.
  • Kraaijveld, G.J.C.
  • Feron, P.H.M.

Abstract

An exergy analysis is conducted of a gas-fired CO2 capture process based on monoethanolamine (MEA) absorption technology. It is shown that with a combination of AspenPlus and ExerCom, it is possible to get a reasonable result for the exergy loss per unit operation. To enable this, certain modifications were made in the thermodynamics of the reaction of CO2 with MEA. In this reaction, ionic species are formed and an approach enabling the use of electrolytes is necessary. The results show that the major sources of exergy loss are the absorber, the flasher and the flue gas blower.

Suggested Citation

  • Geuzebroek, F.H. & Schneiders, L.H.J.M. & Kraaijveld, G.J.C. & Feron, P.H.M., 2004. "Exergy analysis of alkanolamine-based CO2 removal unit with AspenPlus," Energy, Elsevier, vol. 29(9), pages 1241-1248.
  • Handle: RePEc:eee:energy:v:29:y:2004:i:9:p:1241-1248
    DOI: 10.1016/j.energy.2004.03.083
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    References listed on IDEAS

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    1. Leites, I.L. & Sama, D.A. & Lior, N., 2003. "The theory and practice of energy saving in the chemical industry: some methods for reducing thermodynamic irreversibility in chemical technology processes," Energy, Elsevier, vol. 28(1), pages 55-97.
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    2. Khoa, T.D. & Shuhaimi, M. & Nam, H.M., 2012. "Application of three dimensional exergy analysis curves for absorption columns," Energy, Elsevier, vol. 37(1), pages 273-280.
    3. Wang, Ding & Sun, Lei & Xie, Yonghui, 2023. "Performance evaluation of CO2 pressurization and storage system combined with S–CO2 power generation process and absorption refrigeration cycle," Energy, Elsevier, vol. 273(C).
    4. Xiang, Yangyang & Zhou, Jingsong & Lin, Bowen & Xue, Xiaoao & Tian, Xingtao & Luo, Zhongyang, 2015. "Exergetic evaluation of renewable light olefins production from biomass via synthetic methanol," Applied Energy, Elsevier, vol. 157(C), pages 499-507.
    5. Ferrara, G. & Lanzini, A. & Leone, P. & Ho, M.T. & Wiley, D.E., 2017. "Exergetic and exergoeconomic analysis of post-combustion CO2 capture using MEA-solvent chemical absorption," Energy, Elsevier, vol. 130(C), pages 113-128.
    6. Muhammad Asif & Muhammad Suleman & Ihtishamul Haq & Syed Asad Jamal, 2018. "Post‐combustion CO2 capture with chemical absorption and hybrid system: current status and challenges," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(6), pages 998-1031, December.
    7. Mores, Patricia & Scenna, Nicolás & Mussati, Sergio, 2012. "CO2 capture using monoethanolamine (MEA) aqueous solution: Modeling and optimization of the solvent regeneration and CO2 desorption process," Energy, Elsevier, vol. 45(1), pages 1042-1058.
    8. Feyzi, Vafa & Beheshti, Masoud & Gharibi Kharaji, Abolfazl, 2017. "Exergy analysis: A CO2 removal plant using a-MDEA as the solvent," Energy, Elsevier, vol. 118(C), pages 77-84.
    9. Dong, Ruifeng & Lu, Hongfang & Yu, Yunsong & Zhang, Zaoxiao, 2012. "A feasible process for simultaneous removal of CO2, SO2 and NOx in the cement industry by NH3 scrubbing," Applied Energy, Elsevier, vol. 97(C), pages 185-191.
    10. Farajzadeh, R. & Eftekhari, A.A. & Dafnomilis, G. & Lake, L.W. & Bruining, J., 2020. "On the sustainability of CO2 storage through CO2 – Enhanced oil recovery," Applied Energy, Elsevier, vol. 261(C).
    11. Tola, Vittorio & Pettinau, Alberto, 2014. "Power generation plants with carbon capture and storage: A techno-economic comparison between coal combustion and gasification technologies," Applied Energy, Elsevier, vol. 113(C), pages 1461-1474.

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