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Development of 2D multiphase non-isothermal mass transfer model for DMFC system

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  • Ismail, A.
  • Kamarudin, S.K.
  • Daud, W.R.W.
  • Masdar, S.
  • Hasran, U.A.

Abstract

This paper presents a 2D multiphase non-isothermal mass transfer model for a single-cell direct methanol fuel cell (DMFC). The model includes the reaction of methanol and oxygen at the anode and cathode, respectively. In addition, it also considers the diffusion of every component involved in DMFC—i.e., methanol, water and oxygen at the diffusion layer and the methanol crossover phenomena. It also includes the relation between the temperature and concentration towards the power output. Later, the model was optimised and the result shows this model can generate up to 48 mWcm−2 of power density reflected to 190 mAcm−2 and 0.26 V of current density and voltage, respectively. It shows this study generate a good model compare to previous study, at a methanol concentration of 4 M and operating temperature of 60 °C.

Suggested Citation

  • Ismail, A. & Kamarudin, S.K. & Daud, W.R.W. & Masdar, S. & Hasran, U.A., 2018. "Development of 2D multiphase non-isothermal mass transfer model for DMFC system," Energy, Elsevier, vol. 152(C), pages 263-276.
    • Handle: RePEc:eee:energy:v:152:y:2018:i:c:p:263-276
    DOI: 10.1016/j.energy.2018.03.097
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    References listed on IDEAS

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    1. Na, Youngseung & Kwon, Jungmin & Kim, Hyun & Cho, Hyejung & Song, Inseob, 2013. "Characteristics of a direct methanol fuel cell system with the time shared fuel supplying approach," Energy, Elsevier, vol. 50(C), pages 406-411.
    2. Taner, Tolga, 2018. "Energy and exergy analyze of PEM fuel cell: A case study of modeling and simulations," Energy, Elsevier, vol. 143(C), pages 284-294.
    3. Prater, Daniel N. & Rusek, John J., 2003. "Energy density of a methanol/hydrogen-peroxide fuel cell," Applied Energy, Elsevier, vol. 74(1-2), pages 135-140, January.
    4. Oliveira, V.B. & Pereira, J.P. & Pinto, A.M.F.R., 2017. "Modeling of passive direct ethanol fuel cells," Energy, Elsevier, vol. 133(C), pages 652-665.
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    Cited by:

    1. Munjewar, Seema S. & Thombre, Shashikant B., 2019. "Effect of current collector roughness on performance of passive direct methanol fuel cell," Renewable Energy, Elsevier, vol. 138(C), pages 272-283.
    2. Lei, Gang & Zheng, Hualin & Zhang, Jun & Siong Chin, Cheng & Xu, Xinhai & Zhou, Weijiang & Zhang, Caizhi, 2023. "Analyzing characteristic and modeling of high-temperature proton exchange membrane fuel cells with CO poisoning effect," Energy, Elsevier, vol. 282(C).
    3. Fang, Shuo & Liu, Yuntao & Zhao, Chunhui & Huang, Lilian & Zhong, Zhi & Wang, Yun, 2021. "Polarization analysis of a micro direct methanol fuel cell stack based on Debye-Hückel ionic atmosphere theory," Energy, Elsevier, vol. 222(C).
    4. Fang, Shuo & Song, Nan & Liu, Yuntao & Zhou, Chaoyang & Zhao, Chunhui & Wang, Yun, 2023. "Oscillator design for high efficiency DC-DC of micro direct methanol fuel cell," Energy, Elsevier, vol. 284(C).
    5. Chen, Fengxiang & Chi, Xuncheng & Wei, Wei & Mo, Tiande & Li, Yu, 2023. "Model-based observer for direct methanol fuel cell concentration estimation by using second-order sliding-mode algorithm," Energy, Elsevier, vol. 263(PD).
    6. Zhang, Rongji & Cao, Jiamu & Wang, Weiqi & Zhou, Jing & Chen, Junyu & Chen, Liang & Chen, Weiping & Zhang, Yufeng, 2023. "An improved strategy of passive micro direct methanol fuel cell: Mass transport mechanism optimization dominated by a single hydrophilic layer," Energy, Elsevier, vol. 274(C).

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