IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v87y2010i4p1269-1272.html
   My bibliography  Save this article

Oil shale pyrolysis kinetics and variable activation energy principle

Author

Listed:
  • Al-Ayed, Omar S.
  • Matouq, M.
  • Anbar, Z.
  • Khaleel, Adnan M.
  • Abu-Nameh, Eyad

Abstract

A modified first order kinetic equation with variable activation energy is employed to model the total weight loss of Ellajjun oil shale samples. Fixed bed retort with 400 g of oil shale sample size is used in this study in 350-550 °C temperature range. Variable heating rate, h, in the range 2.6-5 °C min-1 are tested. Activation energy was allowed to vary as a function of oil shale conversion. The value of the activation energy increased from 98 to 120 kJ mol-1 while the corresponding frequency factor changed from 9.51 x 105 to 1.16 x 106. Fischer Assay analysis of the studied samples indicated 12.2 wt.% oil content. The oil shale decomposition ranged from 3.2% to 28.0%. The obtained kinetic data are modeled using variable heating rate, pyrolysis temperature and variable activation energy principle in a nitrogen sweeping medium. Good fit to the obtained experimental data is achieved.

Suggested Citation

  • Al-Ayed, Omar S. & Matouq, M. & Anbar, Z. & Khaleel, Adnan M. & Abu-Nameh, Eyad, 2010. "Oil shale pyrolysis kinetics and variable activation energy principle," Applied Energy, Elsevier, vol. 87(4), pages 1269-1272, April.
    • Handle: RePEc:eee:appene:v:87:y:2010:i:4:p:1269-1272
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306-2619(09)00264-5
    Download Restriction: Full text for ScienceDirect subscribers only
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Fagbemi, L & Khezami, L & Capart, R, 2001. "Pyrolysis products from different biomasses: application to the thermal cracking of tar," Applied Energy, Elsevier, vol. 69(4), pages 293-306, August.
    2. Xiao, Han-min & Ma, Xiao-qian & Lai, Zhi-yi, 2009. "Isoconversional kinetic analysis of co-combustion of sewage sludge with straw and coal," Applied Energy, Elsevier, vol. 86(9), pages 1741-1745, September.
    3. Sett, Angshu & Bhattacharya, S. C., 1988. "Mathematical modelling of a fluidised-bed charcoal gasifier," Applied Energy, Elsevier, vol. 30(3), pages 161-186.
    4. Yilgin, Melek & Pehlivan, Dursun, 2009. "Volatiles and char combustion rates of demineralised lignite and wood blends," Applied Energy, Elsevier, vol. 86(7-8), pages 1179-1186, July.
    5. Sand, U. & Sandberg, J. & Larfeldt, J. & Bel Fdhila, R., 2008. "Numerical prediction of the transport and pyrolysis in the interior and surrounding of dry and wet wood log," Applied Energy, Elsevier, vol. 85(12), pages 1208-1224, December.
    6. Belleville, P. & Capart, R. & Gelus, M., 1984. "Pyrolysis of large wood samples," Applied Energy, Elsevier, vol. 16(3), pages 223-237.
    7. Jaber, J. O. & Probert, S. D., 1999. "Pyrolysis and gasification kinetics of Jordanian oil-shales," Applied Energy, Elsevier, vol. 63(4), pages 269-286, August.
    8. Capart, R. & Falk, L. & Gelus, M., 1988. "Pyrolysis of wood macrocylinders under pressure: Application of a simple mathematical model," Applied Energy, Elsevier, vol. 30(1), pages 1-13.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pan, Luwei & Dai, Fangqin & Li, Guangqiang & Liu, Shuang, 2015. "A TGA/DTA-MS investigation to the influence of process conditions on the pyrolysis of Jimsar oil shale," Energy, Elsevier, vol. 86(C), pages 749-757.
    2. Shi, Yu & Zhang, Yulong & Song, Xianzhi & Cui, Qiliang & Lei, Zhihong & Song, Guofeng, 2023. "Injection energy utilization efficiency and production performance of oil shale in-situ exploitation," Energy, Elsevier, vol. 263(PB).
    3. Al-Ayed, Omar S. & Suliman, Mohd R. & Rahman, Nafi Abdel, 2010. "Kinetic modeling of liquid generation from oil shale in fixed bed retort," Applied Energy, Elsevier, vol. 87(7), pages 2273-2277, July.
    4. Song, Xianzhi & Zhang, Chengkai & Shi, Yu & Li, Gensheng, 2019. "Production performance of oil shale in-situ conversion with multilateral wells," Energy, Elsevier, vol. 189(C).
    5. Juan Jin & Weidong Jiang & Jiandong Liu & Junfeng Shi & Xiaowen Zhang & Wei Cheng & Ziniu Yu & Weixi Chen & Tingfu Ye, 2023. "Numerical Analysis of In Situ Conversion Process of Oil Shale Formation Based on Thermo-Hydro-Chemical Coupled Modelling," Energies, MDPI, vol. 16(5), pages 1-17, February.
    6. Wang, Qing & Zhao, Weizhen & Liu, Hongpeng & Jia, Chunxia & Li, Shaohua, 2011. "Interactions and kinetic analysis of oil shale semi-coke with cornstalk during co-combustion," Applied Energy, Elsevier, vol. 88(6), pages 2080-2087, June.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ahmed, I.I. & Gupta, A.K., 2011. "Particle size, porosity and temperature effects on char conversion," Applied Energy, Elsevier, vol. 88(12), pages 4667-4677.
    2. Arpa, Orhan & Yumrutas, Recep & Demirbas, Ayhan, 2010. "Production of diesel-like fuel from waste engine oil by pyrolitic distillation," Applied Energy, Elsevier, vol. 87(1), pages 122-127, January.
    3. Niu, Shengli & Han, Kuihua & Lu, Chunmei & Sun, Rongyue, 2010. "Thermogravimetric analysis of the relationship among calcium magnesium acetate, calcium acetate and magnesium acetate," Applied Energy, Elsevier, vol. 87(7), pages 2237-2242, July.
    4. Wanhe Hu & Jingxin Wang & Jianli Hu & Jamie Schuler & Shawn Grushecky & Changle Jiang & William Smith & Nan Nan & Edward M. Sabolsky, 2024. "Combustion Behaviors, Kinetics, and Thermodynamics of Naturally Decomposed and Torrefied Northern Red Oak ( Quercus rubra ) Forest Logging Residue," Energies, MDPI, vol. 17(7), pages 1-17, March.
    5. Junga, Robert & Pospolita, Janusz & Niemiec, Patrycja, 2020. "Combustion and grindability characteristics of palm kernel shells torrefied in a pilot-scale installation," Renewable Energy, Elsevier, vol. 147(P1), pages 1239-1250.
    6. Yi, Honghong & Yang, Zhongyu & Tang, Xiaolong & Zhao, Shunzheng & Gao, Fengyu & Wang, Jiangen & Huang, Yonghai & Yang, Kun & Shi, Yiran & Xie, Xizhou, 2018. "Variations of apparent activation energy based on thermodynamics analysis of zeolitic imidazolate frameworks including pyrolysis and combustion," Energy, Elsevier, vol. 151(C), pages 782-798.
    7. Wickramaarachchi, W.A.M.K.P. & Narayana, Mahinsasa, 2020. "Pyrolysis of single biomass particle using three-dimensional Computational Fluid Dynamics modelling," Renewable Energy, Elsevier, vol. 146(C), pages 1153-1165.
    8. Ngo, Son Ich & Nguyen, Thanh D.B. & Lim, Young-Il & Song, Byung-Ho & Lee, Uen-Do & Choi, Young-Tai & Song, Jae-Hun, 2011. "Performance evaluation for dual circulating fluidized-bed steam gasifier of biomass using quasi-equilibrium three-stage gasification model," Applied Energy, Elsevier, vol. 88(12), pages 5208-5220.
    9. Alam, Mahboob & Bhavanam, Anjireddy & Jana, Ashirbad & Viroja, Jaimin kumar S. & Peela, Nageswara Rao, 2020. "Co-pyrolysis of bamboo sawdust and plastic: Synergistic effects and kinetics," Renewable Energy, Elsevier, vol. 149(C), pages 1133-1145.
    10. Aniza, Ria & Chen, Wei-Hsin & Lin, Yu-Ying & Tran, Khanh-Quang & Chang, Jo-Shu & Lam, Su Shiung & Park, Young-Kwon & Kwon, Eilhann E. & Tabatabaei, Meisam, 2021. "Independent parallel pyrolysis kinetics of extracted proteins and lipids as well as model carbohydrates in microalgae," Applied Energy, Elsevier, vol. 300(C).
    11. Andrew N. Amenaghawon & Chinedu L. Anyalewechi & Charity O. Okieimen & Heri Septya Kusuma, 2021. "Biomass pyrolysis technologies for value-added products: a state-of-the-art review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14324-14378, October.
    12. Song, Xianzhi & Zhang, Chengkai & Shi, Yu & Li, Gensheng, 2019. "Production performance of oil shale in-situ conversion with multilateral wells," Energy, Elsevier, vol. 189(C).
    13. Nargess Puadian & Jingge Li & Shusheng Pang, 2014. "Analysis of Operation Parameters in a Dual Fluidized Bed Biomass Gasifier Integrated with a Biomass Rotary Dryer: Development and Application of a System Model," Energies, MDPI, vol. 7(7), pages 1-22, July.
    14. Huang, Zhian & Yu, Rongxia & Ding, Hao & Wang, Hongsheng & Quan, Sainan & Song, Donghong & Lei, Yukun & Gao, Yukun & Zhang, Yinghua & Wang, Pengfei, 2023. "Preparation and properties of tea polyphenol nanofoamed gel for preventing coal spontaneous combustion," Energy, Elsevier, vol. 284(C).
    15. Sandberg, Jan & Fdhila, Rebei Bel & Dahlquist, Erik & Avelin, Anders, 2011. "Dynamic simulation of fouling in a circulating fluidized biomass-fired boiler," Applied Energy, Elsevier, vol. 88(5), pages 1813-1824, May.
    16. Ziad Abu El-Rub & Joanna Kujawa & Samer Al-Gharabli, 2020. "Pyrolysis Kinetic Parameters of Omari Oil Shale Using Thermogravimetric Analysis," Energies, MDPI, vol. 13(16), pages 1-13, August.
    17. Motasemi, F. & Afzal, Muhammad T., 2013. "A review on the microwave-assisted pyrolysis technique," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 317-330.
    18. Gong, Junhui & Zhang, Mingrui, 2022. "Pyrolysis and autoignition behaviors of oriented strand board under power-law radiation," Renewable Energy, Elsevier, vol. 182(C), pages 946-957.
    19. Wang, Qing & Zhao, Weizhen & Liu, Hongpeng & Jia, Chunxia & Li, Shaohua, 2011. "Interactions and kinetic analysis of oil shale semi-coke with cornstalk during co-combustion," Applied Energy, Elsevier, vol. 88(6), pages 2080-2087, June.
    20. Hervy, Maxime & Weiss-Hortala, Elsa & Pham Minh, Doan & Dib, Hadi & Villot, Audrey & Gérente, Claire & Berhanu, Sarah & Chesnaud, Anthony & Thorel, Alain & Le Coq, Laurence & Nzihou, Ange, 2019. "Reactivity and deactivation mechanisms of pyrolysis chars from bio-waste during catalytic cracking of tar," Applied Energy, Elsevier, vol. 237(C), pages 487-499.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:87:y:2010:i:4:p:1269-1272. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.