IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v350y2023ics0306261923011601.html
   My bibliography  Save this article

Study on aging and external short circuit mechanisms of Li-ion cells with different electrode thicknesses

Author

Listed:
  • An, Zhoujian
  • Shi, Tianlu
  • Zhao, Yabing
  • Gong, Qiliang
  • Zhang, Dong
  • Bai, Jianhua
  • Du, Xiaoze

Abstract

Thermal runaway is one of the challenges associated with the widespread use of Li-ion batteries. The thermal runaway characteristics of Li-ion batteries are closely associated with the electrode materials, electrode structure design and degree of cycling deterioration. The energy density of Li-ion cells can be efficiently increased by expanding the electrode thickness, but cycle and thermal performance will be deteriorated with the increase of electrode thickness. The cycle performance and aging mechanisms of cells with different electrode thicknesses during cycling has been investigated in present research. Afterwards, the external short-circuit was conducted on aged cells to explore the effect of electrode thickness on cell thermal runaway behavior. The results showed that the ohmic internal resistance and polarization internal resistance of the thick-electrode cell increased continuously with cycling, and the capacity faded significantly. The increase in Li+ migration distance in a thick electrode will make the state of charge (SOC) distribution uneven along the thick direction. The thick electrode cell had the largest absolute temperature rise and temperature rise rate when it was short-circuited, which were 104.07 °C and 1.89 °C/s, respectively. The temperature of the area near the negative electrode of the cell was higher than that of the center and the positive electrode. The micro structure of electrode by SEM revealed that cycling can cause thick electrode material to crack, resulting in capacity loss. When thermal runaway developed, thick electrodes had the highest absolute temperature rise and temperature rise rate. As the current density increased, the thermal runaway would aggravate the damage to the positive electrode material, and the separator would close and shrink, thereby cutting off the reaction between the positive and negative electrodes.

Suggested Citation

  • An, Zhoujian & Shi, Tianlu & Zhao, Yabing & Gong, Qiliang & Zhang, Dong & Bai, Jianhua & Du, Xiaoze, 2023. "Study on aging and external short circuit mechanisms of Li-ion cells with different electrode thicknesses," Applied Energy, Elsevier, vol. 350(C).
  • Handle: RePEc:eee:appene:v:350:y:2023:i:c:s0306261923011601
    DOI: 10.1016/j.apenergy.2023.121796
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261923011601
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2023.121796?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhao, Rui & Liu, Jie & Gu, Junjie, 2015. "The effects of electrode thickness on the electrochemical and thermal characteristics of lithium ion battery," Applied Energy, Elsevier, vol. 139(C), pages 220-229.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Liao, Xiaolin & Sun, Peiyi & Xu, Mengqing & Xing, Lidan & Liao, Youhao & Zhang, Liping & Yu, Le & Fan, Weizhen & Li, Weishan, 2016. "Application of tris(trimethylsilyl)borate to suppress self-discharge of layered nickel cobalt manganese oxide for high energy battery," Applied Energy, Elsevier, vol. 175(C), pages 505-511.
    2. Lybbert, M. & Ghaemi, Z. & Balaji, A.K. & Warren, R., 2021. "Integrating life cycle assessment and electrochemical modeling to study the effects of cell design and operating conditions on the environmental impacts of lithium-ion batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    3. Xiong, Rui & Sun, Wanzhou & Yu, Quanqing & Sun, Fengchun, 2020. "Research progress, challenges and prospects of fault diagnosis on battery system of electric vehicles," Applied Energy, Elsevier, vol. 279(C).
    4. Oh, Ki-Yong & Epureanu, Bogdan I., 2016. "Characterization and modeling of the thermal mechanics of lithium-ion battery cells," Applied Energy, Elsevier, vol. 178(C), pages 633-646.
    5. Guan, Ting & Sun, Shun & Gao, Yunzhi & Du, Chunyu & Zuo, Pengjian & Cui, Yingzhi & Zhang, Lingling & Yin, Geping, 2016. "The effect of elevated temperature on the accelerated aging of LiCoO2/mesocarbon microbeads batteries," Applied Energy, Elsevier, vol. 177(C), pages 1-10.
    6. Rao, Zhonghao & Wang, Qingchao & Huang, Congliang, 2016. "Investigation of the thermal performance of phase change material/mini-channel coupled battery thermal management system," Applied Energy, Elsevier, vol. 164(C), pages 659-669.
    7. Liu, Yuanzhi & Zhang, Jie, 2019. "Design a J-type air-based battery thermal management system through surrogate-based optimization," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    8. Jiang, Z.Y. & Qu, Z.G. & Zhou, L. & Tao, W.Q., 2017. "A microscopic investigation of ion and electron transport in lithium-ion battery porous electrodes using the lattice Boltzmann method," Applied Energy, Elsevier, vol. 194(C), pages 530-539.
    9. Gu, Li & Gui, John Yupeng & Wang, Jing V. & Zhu, Guorong & Kang, Jianqiang, 2019. "Parameterized evaluation of thermal characteristics for a lithium-ion battery," Energy, Elsevier, vol. 178(C), pages 21-32.
    10. Liang, Jialin & Gan, Yunhua & Li, Yong & Tan, Meixian & Wang, Jianqin, 2019. "Thermal and electrochemical performance of a serially connected battery module using a heat pipe-based thermal management system under different coolant temperatures," Energy, Elsevier, vol. 189(C).
    11. Donghyeon Yoo & Jinhwan Park & Jaemin Moon & Changwan Kim, 2021. "Reliability-Based Design Optimization for Reducing the Performance Failure and Maximizing the Specific Energy of Lithium-Ion Batteries Considering Manufacturing Uncertainty of Porous Electrodes," Energies, MDPI, vol. 14(19), pages 1-15, September.
    12. Yang, Yue & Chen, Lei & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2020. "Capacity fade characteristics of lithium iron phosphate cell during dynamic cycle," Energy, Elsevier, vol. 206(C).
    13. Wang, Shunli & Shang, Liping & Li, Zhanfeng & Deng, Hu & Li, Jianchao, 2016. "Online dynamic equalization adjustment of high-power lithium-ion battery packs based on the state of balance estimation," Applied Energy, Elsevier, vol. 166(C), pages 44-58.
    14. Kang, Jihyeon & Atwair, Mohamed & Nam, Inho & Lee, Chul-Jin, 2023. "Experimental and numerical investigation on effects of thickness of NCM622 cathode in Li-ion batteries for high energy and power density," Energy, Elsevier, vol. 263(PE).
    15. Liang, Jialin & Gan, Yunhua & Tan, Meixian & Li, Yong, 2020. "Multilayer electrochemical-thermal coupled modeling of unbalanced discharging in a serially connected lithium-ion battery module," Energy, Elsevier, vol. 209(C).
    16. Zhao, Rui & Liu, Jie & Gu, Junjie, 2016. "Simulation and experimental study on lithium ion battery short circuit," Applied Energy, Elsevier, vol. 173(C), pages 29-39.
    17. Chang, Chia-Chin & Huang, Sin-Yi & Chen, Wei-Hsin, 2019. "Thermal and solid electrolyte interphase characterization of lithium-ion battery," Energy, Elsevier, vol. 174(C), pages 999-1011.
    18. He, Tengfei & Zhang, Teng & Wang, Zhirong & Cai, Qiong, 2022. "A comprehensive numerical study on electrochemical-thermal models of a cylindrical lithium-ion battery during discharge process," Applied Energy, Elsevier, vol. 313(C).
    19. Wang, Qinggong & Yao, Wei & Zhang, Hui & Lu, Xiaochen, 2018. "Analysis of the performance of an alkali metal thermoelectric converter (AMTEC) based on a lumped thermal-electrochemical model," Applied Energy, Elsevier, vol. 216(C), pages 195-211.
    20. Zhao, Rui & Liu, Jie & Gu, Junjie, 2017. "A comprehensive study on Li-ion battery nail penetrations and the possible solutions," Energy, Elsevier, vol. 123(C), pages 392-401.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:350:y:2023:i:c:s0306261923011601. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.