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Application of tris(trimethylsilyl)borate to suppress self-discharge of layered nickel cobalt manganese oxide for high energy battery

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  • Liao, Xiaolin
  • Sun, Peiyi
  • Xu, Mengqing
  • Xing, Lidan
  • Liao, Youhao
  • Zhang, Liping
  • Yu, Le
  • Fan, Weizhen
  • Li, Weishan

Abstract

Tris(trimethylsilyl)borate (TMSB) is applied to suppress the self-discharge of charged LiNi1/3Co1/3Mn1/3O2 (LNCM) under high potential. The contribution of TMSB is understood via physical and electrochemical characterizations. It is found that the charged LNCM under 4.5V suffers serious self-discharge: potential drops to 0.5V and crystal structure collapses, but this self-discharge is effectively suppressed by applying TMSB in a standard (STD) electrolyte. Different from the failure from cycling, which is caused mainly by the electrochemical oxidation decomposition of electrolyte, the self-discharge results from the interaction between charged LNCM and electrolyte. TMSB is preferentially oxidized in comparison with STD electrolyte, generating a solid electrolyte interphase film on LNCM, which avoids the direct contact between LNCM and electrolyte and thus suppresses the self-discharge of the charged LNCM.

Suggested Citation

  • Liao, Xiaolin & Sun, Peiyi & Xu, Mengqing & Xing, Lidan & Liao, Youhao & Zhang, Liping & Yu, Le & Fan, Weizhen & Li, Weishan, 2016. "Application of tris(trimethylsilyl)borate to suppress self-discharge of layered nickel cobalt manganese oxide for high energy battery," Applied Energy, Elsevier, vol. 175(C), pages 505-511.
  • Handle: RePEc:eee:appene:v:175:y:2016:i:c:p:505-511
    DOI: 10.1016/j.apenergy.2016.03.114
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    References listed on IDEAS

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    Cited by:

    1. Ding, Yin & Mu, Daobin & Wu, Borong & Wang, Rui & Zhao, Zhikun & Wu, Feng, 2017. "Recent progresses on nickel-rich layered oxide positive electrode materials used in lithium-ion batteries for electric vehicles," Applied Energy, Elsevier, vol. 195(C), pages 586-599.
    2. Shang, Wenxu & Yu, Wentao & Xiao, Xu & Ma, Yanyi & Chen, Ziqi & Ni, Meng & Tan, Peng, 2022. "Optimizing the charging protocol to address the self-discharge issues in rechargeable alkaline Zn-Co batteries," Applied Energy, Elsevier, vol. 308(C).

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