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Aluminium – Water hydrogen generator for domestic and mobile application

Author

Listed:
  • Zhuk, A.Z.
  • Shkolnikov, E.I.
  • Borodina, T.I.
  • Valiano, G.E.
  • Dolzhenko, A.V.
  • Kiseleva, E.A.
  • Kochanova, S.A.
  • Filippov, E.D.
  • Semenova, V.A.

Abstract

The study reports a novel hydrogen generation system. The system comprises Al based hydrogen generating composition with a reduced content of activating additives and an original fully automated Al-water hydrogen generator with capsule supply of hydrogen generating composition. The hydrogen generating composition was synthesized by means of mechanochemical activation of aluminum powder. Bi − 3.5 wt%. and Sn − 1.5 wt%. were used as activating additives. The combination of the proposed hydrogen generating composition and the design features of the generator made it possible to provide a high rate of hydrogen evolution (more than 30 ml/sec*g) and a hydrogen yield of 95–99 %. A high rate of hydrogen evolution was ensured by maintaining a temperature of at least 70 °C in the reaction zone. The heat of the aluminum oxidation reaction was utilized to maintain the necessary temperature. Based on the obtained experimental data, an assumption about the mechanism of the initial stage of the Al oxidation reaction was made. Some feasibility estimations of the hydrogen generation system are presented as well.

Suggested Citation

  • Zhuk, A.Z. & Shkolnikov, E.I. & Borodina, T.I. & Valiano, G.E. & Dolzhenko, A.V. & Kiseleva, E.A. & Kochanova, S.A. & Filippov, E.D. & Semenova, V.A., 2023. "Aluminium – Water hydrogen generator for domestic and mobile application," Applied Energy, Elsevier, vol. 334(C).
    • Handle: RePEc:eee:appene:v:334:y:2023:i:c:s0306261923000570
    DOI: 10.1016/j.apenergy.2023.120693
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    References listed on IDEAS

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    1. Zhuk, A.Z. & Borzenko, V.I. & Buzoverov, E.A. & Ivanov, P.P. & Shkolnikov, E.I., 2022. "Comparative analysis of hydrogen production technologies: Hydrothermal oxidation of the "carbonless" aluminum and water electrolysis," Renewable Energy, Elsevier, vol. 197(C), pages 1244-1250.
    2. Trowell, K.A. & Goroshin, S. & Frost, D.L. & Bergthorson, J.M., 2020. "Aluminum and its role as a recyclable, sustainable carrier of renewable energy," Applied Energy, Elsevier, vol. 275(C).
    3. Fan, Mei-Qiang & Mei, De-Sheng & Chen, Da & Lv, Chun-Ju & Shu, Kang-ying, 2011. "Portable hydrogen generation from activated Al–Li–Bi alloys in water," Renewable Energy, Elsevier, vol. 36(11), pages 3061-3067.
    4. Guan, Xu & Zhou, Zheng & Luo, Ping & Wu, Fengshun & Dong, Shijie, 2019. "Hydrogen generation from the reaction of Al-based composites activated by low-melting-point metals/oxides/salts with water," Energy, Elsevier, vol. 188(C).
    5. Bergthorson, Jeffrey M. & Yavor, Yinon & Palecka, Jan & Georges, William & Soo, Michael & Vickery, James & Goroshin, Samuel & Frost, David L. & Higgins, Andrew J., 2017. "Metal-water combustion for clean propulsion and power generation," Applied Energy, Elsevier, vol. 186(P1), pages 13-27.
    6. Fan, Mei–qiang & Sun, Li–xian & Xu, Fen, 2010. "Experiment assessment of hydrogen production from activated aluminum alloys in portable generator for fuel cell applications," Energy, Elsevier, vol. 35(7), pages 2922-2926.
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