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Impact of pressure on the dynamic behavior of CO2 hydrate slurry in a stirred tank reactor applied to cold thermal energy storage

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  • Dufour, Thomas
  • Hoang, Hong Minh
  • Oignet, Jérémy
  • Osswald, Véronique
  • Clain, Pascal
  • Fournaison, Laurence
  • Delahaye, Anthony

Abstract

Phase change material (PCM) slurries are considered as high-performance fluids for secondary refrigeration and cold thermal energy storage (CTES) systems thanks to their high energy density. Nevertheless, the efficiency of such system is limited by storage dynamic. In fact, PCM charging or discharging rate is governed by system design (storage tank, heat exchanger), heat transfer fluid temperature and flow rate (cold or hot source), and PCM temperature. However, with classical PCM (ice, paraffin…), phase change temperature depends only on material/fluid nature and composition. In the case of gas hydrates, phase change temperature is also controlled by pressure. In the current work, the influence of pressure on cold storage with gas hydrates was studied experimentally using a stirred tank reactor equipped with a cooling jacket. A tank reactor model was also developed to assess the efficiency of this storage process. The results showed that pressure can be used to adjust phase change temperature of CO2 hydrates, and consequently charging/discharging time. For the same operating conditions and during the same charging time, the amount of stored energy using CO2 hydrates can be three times higher than that using water. By increasing the initial pressure from 2.45 to 3.2MPa (at 282.15K), it is also possible to decrease the charging time by a factor of 3. Finally, it appears that the capacity of pressure to increase CO2-hydrate phase-change temperature can also improve system efficiency by decreasing thermal losses.

Suggested Citation

  • Dufour, Thomas & Hoang, Hong Minh & Oignet, Jérémy & Osswald, Véronique & Clain, Pascal & Fournaison, Laurence & Delahaye, Anthony, 2017. "Impact of pressure on the dynamic behavior of CO2 hydrate slurry in a stirred tank reactor applied to cold thermal energy storage," Applied Energy, Elsevier, vol. 204(C), pages 641-652.
    • Handle: RePEc:eee:appene:v:204:y:2017:i:c:p:641-652
    DOI: 10.1016/j.apenergy.2017.07.098
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    Cited by:

    1. Dufour, Thomas & Hoang, Hong Minh & Oignet, Jérémy & Osswald, Véronique & Fournaison, Laurence & Delahaye, Anthony, 2019. "Experimental and modelling study of energy efficiency of CO2 hydrate slurry in a coil heat exchanger," Applied Energy, Elsevier, vol. 242(C), pages 492-505.
    2. Pons, Michel & Delahaye, Anthony & Fournaison, Laurence & Dalmazzone, Didier, 2018. "Energy analysis of two-phase secondary refrigeration in steady-state operation, part 2: Exergy analysis and effects of phase change kinetics," Energy, Elsevier, vol. 161(C), pages 1291-1299.
    3. Emiliano Borri & Nan Hua & Adriano Sciacovelli & Dawei Wu & Yulong Ding & Yongliang Li & Vincenza Brancato & Yannan Zhang & Andrea Frazzica & Wenguang Li & Zhibin Yu & Yanio E. Milian & Svetlana Ushak, 2022. "Phase Change Slurries for Cooling and Storage: An Overview of Research Trends and Gaps," Energies, MDPI, vol. 15(19), pages 1-17, September.
    4. Choi, Sung & Park, Jungjoon & Kang, Yong Tae, 2019. "Experimental investigation on CO2 hydrate formation/dissociation for cold thermal energy harvest and transportation applications," Applied Energy, Elsevier, vol. 242(C), pages 1358-1368.
    5. Yang, Lizhong & Villalobos, Uver & Akhmetov, Bakytzhan & Gil, Antoni & Khor, Jun Onn & Palacios, Anabel & Li, Yongliang & Ding, Yulong & Cabeza, Luisa F. & Tan, Wooi Leong & Romagnoli, Alessandro, 2021. "A comprehensive review on sub-zero temperature cold thermal energy storage materials, technologies, and applications: State of the art and recent developments," Applied Energy, Elsevier, vol. 288(C).
    6. Cheng, Chuanxiao & Wang, Fan & Qi, Tian & Xu, Peiyuan & Zhang, Quanguo & Zhang, Zhiping & He, Chao & Zhang, Jun & Zheng, Jili & Zhao, Jiafei & Zhang, Hanquan & Xiao, Bo, 2021. "Depressurization-induced changes in memory effect of hydrate reformation correlated with sediment morphology," Energy, Elsevier, vol. 217(C).
    7. Kawasaki, Toshiyuki & Obara, Shin'ya, 2020. "CO2 hydrate heat cycle using a carbon fiber supported catalyst for gas hydrate formation processes," Applied Energy, Elsevier, vol. 269(C).

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