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Effect of air addition to methane on performance stability and coking over NiO–YSZ anodes of SOFC

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  • Aslannejad, H.
  • Barelli, L.
  • Babaie, A.
  • Bozorgmehri, S.

Abstract

The use of natural gas as fuel for solid oxide fuel cell is one of main potentials of this technology to be exploited as an efficient and profitable future power generation source. However, using direct methane (main component of natural gas) in conventional nickel-based fuel cells leads to carbon deposition problem which causes performance failure even in short period (24h). According to thermodynamic principles, fuel addition with oxygen carriers is a good solution to prevent carbon deposition problem. Among the different options, a deep investigation is here presented for the air addition case. Through experimental activity under different operating conditions and suitable performance and structural cell characterization, the 1:5 optimal air addition to methane is determined, providing outcomes of interest for SOFC operation optimization in case of direct methane feeding. In fact, through impedance spectroscopy analysis and voltage measurements, as well as ex-post structural analysis, it is proved that in these conditions both carbon deposition and anode layers delamination are avoided, also after 100h operation; moreover a cell stable operation at 0.6V is guaranteed. The proposed operation mode, therefore, represents a promising solution, to be deeply investigated in the future at stack level, for SOFCs directly fed with natural gas.

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  • Aslannejad, H. & Barelli, L. & Babaie, A. & Bozorgmehri, S., 2016. "Effect of air addition to methane on performance stability and coking over NiO–YSZ anodes of SOFC," Applied Energy, Elsevier, vol. 177(C), pages 179-186.
    • Handle: RePEc:eee:appene:v:177:y:2016:i:c:p:179-186
    DOI: 10.1016/j.apenergy.2016.05.127
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    1. Qu, Jifa & Wang, Wei & Chen, Yubo & Deng, Xiang & Shao, Zongping, 2016. "Stable direct-methane solid oxide fuel cells with calcium-oxide-modified nickel-based anodes operating at reduced temperatures," Applied Energy, Elsevier, vol. 164(C), pages 563-571.
    2. Ma, Ting & Yan, Min & Zeng, Min & Yuan, Jin-liang & Chen, Qiu-yang & Sundén, Bengt & Wang, Qiu-wang, 2015. "Parameter study of transient carbon deposition effect on the performance of a planar solid oxide fuel cell," Applied Energy, Elsevier, vol. 152(C), pages 217-228.
    3. Yan, Min & Zeng, Min & Chen, Qiuyang & Wang, Qiuwang, 2012. "Numerical study on carbon deposition of SOFC with unsteady state variation of porosity," Applied Energy, Elsevier, vol. 97(C), pages 754-762.
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    4. Silva-Mosqueda, Dulce María & Elizalde-Blancas, Francisco & Pumiglia, Davide & Santoni, Francesca & Boigues-Muñoz, Carlos & McPhail, Stephen J., 2019. "Intermediate temperature solid oxide fuel cell under internal reforming: Critical operating conditions, associated problems and their impact on the performance," Applied Energy, Elsevier, vol. 235(C), pages 625-640.
    5. Choi, Indae & Kim, Jung-Sik & Venkatesan, Vijay & Ranaweera, Manoj, 2017. "Fabrication and evaluation of a novel wavy Single Chamber Solid Oxide Fuel Cell via in-situ monitoring of curvature evolution," Applied Energy, Elsevier, vol. 195(C), pages 1038-1046.
    6. Mohamad Fairus Rabuni & Tao Li & Mohd Hafiz Dzarfan Othman & Faidzul Hakim Adnan & Kang Li, 2023. "Progress in Solid Oxide Fuel Cells with Hydrocarbon Fuels," Energies, MDPI, vol. 16(17), pages 1-36, September.
    7. Barelli, L. & Bidini, G. & Cinti, G. & Gallorini, F. & Pöniz, M., 2017. "SOFC stack coupled with dry reforming," Applied Energy, Elsevier, vol. 192(C), pages 498-507.
    8. Ahmad Fuzamy Mohd Abd Fatah & Ahmad Zaki Rosli & Ahmad Azmin Mohamad & Andanastuti Muchtar & Muhammed Ali S.A. & Noorashrina A. Hamid, 2022. "Electrochemical Evaluation of Nickel Oxide Addition toward Lanthanum Strontium Cobalt Ferrite Cathode for Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFCS)," Energies, MDPI, vol. 15(14), pages 1-15, July.
    9. Li, Bangxin & Irvine, John T.S. & Ni, Jiupai & Ni, Chengsheng, 2022. "High-performance and durable alcohol-fueled symmetrical solid oxide fuel cell based on ferrite perovskite electrode," Applied Energy, Elsevier, vol. 306(PB).
    10. Farnak, M. & Esfahani, J.A. & Bozorgmehri, S., 2020. "An experimental design of the solid oxide fuel cell performance by using partially oxidation reforming of natural gas," Renewable Energy, Elsevier, vol. 147(P1), pages 155-163.
    11. Lyu, Zewei & Shi, Wangying & Han, Minfang, 2018. "Electrochemical characteristics and carbon tolerance of solid oxide fuel cells with direct internal dry reforming of methane," Applied Energy, Elsevier, vol. 228(C), pages 556-567.
    12. Steil, M.C. & Nobrega, S.D. & Georges, S. & Gelin, P. & Uhlenbruck, S. & Fonseca, F.C., 2017. "Durable direct ethanol anode-supported solid oxide fuel cell," Applied Energy, Elsevier, vol. 199(C), pages 180-186.
    13. Orlando Corigliano & Leonardo Pagnotta & Petronilla Fragiacomo, 2022. "On the Technology of Solid Oxide Fuel Cell (SOFC) Energy Systems for Stationary Power Generation: A Review," Sustainability, MDPI, vol. 14(22), pages 1-73, November.

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