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Catalytic fast pyrolysis of lignocellulosic biomass for aromatic production: chemistry, catalyst and process

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  • Anqing Zheng
  • Liqun Jiang
  • Zengli Zhao
  • Zhen Huang
  • Kun Zhao
  • Guoqiang Wei
  • Haibin Li

Abstract

Catalytic fast pyrolysis (CFP) is one of most promising technologies for aromatic production in a single‐step process. In recent years, considerable efforts have been made on the CFP of biomass for aromatic productions. However, the successful commercialization of CFP has hindered by several technical barriers, such as the rational design of continuous reactor and the development of high efficient and stable zeolite catalysts. Here, we attempt to summarize the advances in CFP of biomass from four aspects: (1) reaction chemistry, (2) reactor and operating conditions for CFP, (3) catalysts for CFP, and (4) new processes for CFP. It is expected that this review could provide some guidance for solving the technical barriers aforementioned. WIREs Energy Environ 2017, 6:e234. doi: 10.1002/wene.234 This article is categorized under: Bioenergy > Science and Materials

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  • Anqing Zheng & Liqun Jiang & Zengli Zhao & Zhen Huang & Kun Zhao & Guoqiang Wei & Haibin Li, 2017. "Catalytic fast pyrolysis of lignocellulosic biomass for aromatic production: chemistry, catalyst and process," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 6(3), May.
    • Handle: RePEc:bla:wireae:v:6:y:2017:i:3:n:e234
    DOI: 10.1002/wene.234
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    1. Perkins, Greg & Bhaskar, Thallada & Konarova, Muxina, 2018. "Process development status of fast pyrolysis technologies for the manufacture of renewable transport fuels from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 292-315.
    2. Kawale, Harshal D. & Kishore, Nanda, 2021. "Comprehensive study on thermochemical putrefaction of Delonix Regia in non-catalytic, catalytic and hydro-catalytic pyrolysis atmospheres," Renewable Energy, Elsevier, vol. 173(C), pages 223-236.
    3. Liang, Jie & Shan, Guangcun & Sun, Yifei, 2021. "Catalytic fast pyrolysis of lignocellulosic biomass: Critical role of zeolite catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    4. Palizdar, A. & Sadrameli, S.M., 2020. "Catalytic upgrading of biomass pyrolysis oil over tailored hierarchical MFI zeolite: Effect of porosity enhancement and porosity-acidity interaction on deoxygenation reactions," Renewable Energy, Elsevier, vol. 148(C), pages 674-688.
    5. Nishu, & Li, Chong & Chai, Meiyun & Rahman, Md. Maksudur & Li, Yingkai & Sarker, Manobendro & Liu, Ronghou, 2021. "Performance of alkali and Ni-modified ZSM-5 during catalytic pyrolysis of extracted hemicellulose from rice straw for the production of aromatic hydrocarbons," Renewable Energy, Elsevier, vol. 175(C), pages 936-951.
    6. Sennai Mesfun & Leonidas Matsakas & Ulrika Rova & Paul Christakopoulos, 2019. "Technoeconomic Assessment of Hybrid Organosolv–Steam Explosion Pretreatment of Woody Biomass," Energies, MDPI, vol. 12(21), pages 1-18, November.
    7. Arabiourrutia, Miriam & Lopez, Gartzen & Artetxe, Maite & Alvarez, Jon & Bilbao, Javier & Olazar, Martin, 2020. "Waste tyre valorization by catalytic pyrolysis – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 129(C).
    8. Zeng, Kuo & Wang, Biao & Xia, Shengpeng & Cui, Chaoxian & Wang, Chenyang & Zheng, Anqing & Zhao, Kun & Zhao, Zengli & Li, Haibin & Isobaev, M.D., 2022. "Towards directional pyrolysis of xylan: Understanding the roles of alkali/alkaline earth metals and pyrolysis temperature," Energy, Elsevier, vol. 254(PA).

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