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Construction of Zn-doped RuO2 nanowires for efficient and stable water oxidation in acidic media

Author

Listed:
  • Dafeng Zhang

    (Henan Polytechnic University)

  • Mengnan Li

    (Henan Polytechnic University)

  • Xue Yong

    (Zhengzhou University
    The University of Sheffield)

  • Haoqiang Song

    (Zhengzhou University)

  • Geoffrey I. N. Waterhouse

    (The University of Auckland)

  • Yunfei Yi

    (Henan Polytechnic University)

  • Bingjie Xue

    (Henan Polytechnic University)

  • Dongliang Zhang

    (Henan Polytechnic University)

  • Baozhong Liu

    (Henan Polytechnic University)

  • Siyu Lu

    (Zhengzhou University)

Abstract

Oxygen evolution reaction catalysts capable of working efficiently in acidic media are highly demanded for the commercialization of proton exchange membrane water electrolysis. Herein, we report a Zn-doped RuO2 nanowire array electrocatalyst with outstanding catalytic performance for the oxygen evolution reaction under acidic conditions. Overpotentials as low as 173, 304, and 373 mV are achieved at 10, 500, and 1000 mA cm−2, respectively, with robust stability reaching to 1000 h at 10 mA cm−2. Experimental and theoretical investigations establish a clear synergistic effect of Zn dopants and oxygen vacancies on regulating the binding configurations of oxygenated adsorbates on the active centers, which then enables an alternative Ru−Zn dual-site oxide path of the reaction. Due to the change of reaction pathways, the energy barrier of rate-determining step is reduced, and the over-oxidation of Ru active sites is alleviated. As a result, the catalytic activity and stability are significantly enhanced.

Suggested Citation

  • Dafeng Zhang & Mengnan Li & Xue Yong & Haoqiang Song & Geoffrey I. N. Waterhouse & Yunfei Yi & Bingjie Xue & Dongliang Zhang & Baozhong Liu & Siyu Lu, 2023. "Construction of Zn-doped RuO2 nanowires for efficient and stable water oxidation in acidic media," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38213-1
    DOI: 10.1038/s41467-023-38213-1
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    References listed on IDEAS

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    1. Zhanwu Lei & Wenbin Cai & Yifei Rao & Kuan Wang & Yuyuan Jiang & Yang Liu & Xu Jin & Jianming Li & Zhengxing Lv & Shuhong Jiao & Wenhua Zhang & Pengfei Yan & Shuo Zhang & Ruiguo Cao, 2022. "Coordination modulation of iridium single-atom catalyst maximizing water oxidation activity," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Jakob Kibsgaard & Ib Chorkendorff, 2019. "Considerations for the scaling-up of water splitting catalysts," Nature Energy, Nature, vol. 4(6), pages 430-433, June.
    3. Yichao Lin & Ziqi Tian & Linjuan Zhang & Jingyuan Ma & Zheng Jiang & Benjamin J. Deibert & Ruixiang Ge & Liang Chen, 2019. "Chromium-ruthenium oxide solid solution electrocatalyst for highly efficient oxygen evolution reaction in acidic media," Nature Communications, Nature, vol. 10(1), pages 1-13, December.
    4. Yu Chen & Ben deGlee & Yu Tang & Ziyun Wang & Bote Zhao & Yuechang Wei & Lei Zhang & Seonyoung Yoo & Kai Pei & Jun Hyuk Kim & Yong Ding & P. Hu & Franklin Feng Tao & Meilin Liu, 2018. "A robust fuel cell operated on nearly dry methane at 500 °C enabled by synergistic thermal catalysis and electrocatalysis," Nature Energy, Nature, vol. 3(12), pages 1042-1050, December.
    5. Yin Qin & Tingting Yu & Sihao Deng & Xiao-Ye Zhou & Dongmei Lin & Qian Zhang & Zeyu Jin & Danfeng Zhang & Yan-Bing He & Hua-Jun Qiu & Lunhua He & Feiyu Kang & Kaikai Li & Tong-Yi Zhang, 2022. "RuO2 electronic structure and lattice strain dual engineering for enhanced acidic oxygen evolution reaction performance," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    6. Zuyun He & Jun Zhang & Zhiheng Gong & Hang Lei & Deng Zhou & Nian Zhang & Wenjie Mai & Shijun Zhao & Yan Chen, 2022. "Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
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