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Dynamic rhenium dopant boosts ruthenium oxide for durable oxygen evolution

Author

Listed:
  • Huanyu Jin

    (The University of Adelaide
    The University of Adelaide)

  • Xinyan Liu

    (University of Electronic Science and Technology of China)

  • Pengfei An

    (Chinese Academy of Sciences)

  • Cheng Tang

    (The University of Adelaide)

  • Huimin Yu

    (University of South Australia)

  • Qinghua Zhang

    (Chinese Academy of Sciences)

  • Hong-Jie Peng

    (University of Electronic Science and Technology of China)

  • Lin Gu

    (Chinese Academy of Sciences)

  • Yao Zheng

    (The University of Adelaide)

  • Taeseup Song

    (Hanyang University)

  • Kenneth Davey

    (The University of Adelaide)

  • Ungyu Paik

    (Hanyang University)

  • Juncai Dong

    (Chinese Academy of Sciences)

  • Shi-Zhang Qiao

    (The University of Adelaide)

Abstract

Heteroatom-doping is a practical means to boost RuO2 for acidic oxygen evolution reaction (OER). However, a major drawback is conventional dopants have static electron redistribution. Here, we report that Re dopants in Re0.06Ru0.94O2 undergo a dynamic electron accepting-donating that adaptively boosts activity and stability, which is different from conventional dopants with static dopant electron redistribution. We show Re dopants during OER, (1) accept electrons at the on-site potential to activate Ru site, and (2) donate electrons back at large overpotential and prevent Ru dissolution. We confirm via in situ characterizations and first-principle computation that the dynamic electron-interaction between Re and Ru facilitates the adsorbate evolution mechanism and lowers adsorption energies for oxygen intermediates to boost activity and stability of Re0.06Ru0.94O2. We demonstrate a high mass activity of 500 A gcata.−1 (7811 A gRe-Ru−1) and a high stability number of S-number = 4.0 × 106 noxygen nRu−1 to outperform most electrocatalysts. We conclude that dynamic dopants can be used to boost activity and stability of active sites and therefore guide the design of adaptive electrocatalysts for clean energy conversions.

Suggested Citation

  • Huanyu Jin & Xinyan Liu & Pengfei An & Cheng Tang & Huimin Yu & Qinghua Zhang & Hong-Jie Peng & Lin Gu & Yao Zheng & Taeseup Song & Kenneth Davey & Ungyu Paik & Juncai Dong & Shi-Zhang Qiao, 2023. "Dynamic rhenium dopant boosts ruthenium oxide for durable oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-35913-6
    DOI: 10.1038/s41467-023-35913-6
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    References listed on IDEAS

    as
    1. Jakob Kibsgaard & Ib Chorkendorff, 2019. "Considerations for the scaling-up of water splitting catalysts," Nature Energy, Nature, vol. 4(6), pages 430-433, June.
    2. Yichao Lin & Ziqi Tian & Linjuan Zhang & Jingyuan Ma & Zheng Jiang & Benjamin J. Deibert & Ruixiang Ge & Liang Chen, 2019. "Chromium-ruthenium oxide solid solution electrocatalyst for highly efficient oxygen evolution reaction in acidic media," Nature Communications, Nature, vol. 10(1), pages 1-13, December.
    3. Ya-Rong Zheng & Jerome Vernieres & Zhenbin Wang & Ke Zhang & Degenhart Hochfilzer & Kevin Krempl & Ting-Wei Liao & Francesco Presel & Thomas Altantzis & Jarmo Fatermans & Soren Bertelsen Scott & Nikla, 2022. "Monitoring oxygen production on mass-selected iridium–tantalum oxide electrocatalysts," Nature Energy, Nature, vol. 7(1), pages 55-64, January.
    4. Juan Wang & Lili Han & Bolong Huang & Qi Shao & Huolin L. Xin & Xiaoqing Huang, 2019. "Amorphization activated ruthenium-tellurium nanorods for efficient water splitting," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    5. Qian Dang & Haiping Lin & Zhenglong Fan & Lu Ma & Qi Shao & Yujin Ji & Fangfang Zheng & Shize Geng & Shi-Ze Yang & Ningning Kong & Wenxiang Zhu & Youyong Li & Fan Liao & Xiaoqing Huang & Mingwang Shao, 2021. "Iridium metallene oxide for acidic oxygen evolution catalysis," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
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    Cited by:

    1. Wenxiang Zhu & Xiangcong Song & Fan Liao & Hui Huang & Qi Shao & Kun Feng & Yunjie Zhou & Mengjie Ma & Jie Wu & Hao Yang & Haiwei Yang & Meng Wang & Jie Shi & Jun Zhong & Tao Cheng & Mingwang Shao & Y, 2023. "Stable and oxidative charged Ru enhance the acidic oxygen evolution reaction activity in two-dimensional ruthenium-iridium oxide," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Bingqing Wang & Meng Wang & Ziting Fan & Chao Ma & Shibo Xi & Lo‐Yueh Chang & Mingsheng Zhang & Ning Ling & Ziyu Mi & Shenghua Chen & Wan Ru Leow & Jia Zhang & Dingsheng Wang & Yanwei Lum, 2024. "Nanocurvature-induced field effects enable control over the activity of single-atom electrocatalysts," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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