Self-rolling of vanadium dioxide nanomembranes for enhanced multi-level solar modulation

Thermochromic window develops as a competitive solution for carbon emissions due to comprehensive advantages of its passivity and effective utilization of energy. How to further enhance the solar modulation ( $${\triangle T}_{{{{{{{\rm{sol}}}}}}}}$$ △ T sol ) of thermochromic windows while ensuring high luminous transmittance ( $${T}_{{{{{{{\rm{lum}}}}}}}}$$ T lum ) becomes the latest challenge to touch the limit of energy efficiency. Here, we show a smart window combining mechanochromism with thermochromism by self-rolling of vanadium dioxide (VO2) nanomembranes to enhance multi-level solar modulation. The mechanochromism is introduced by the temperature-controlled regulation of curvature of rolled-up smart window, which benefits from effective strain adjustment in VO2 nanomembranes upon the phase transition. Under geometry design and optimization, the rolled-up smart window with high $${\triangle T}_{{{{\rm{sol}}}}}$$ △ T sol and $${T}_{{{{{{\rm{lum}}}}}}}$$ T lum is achieved for the modulation of indoor temperature self-adapted to seasons and climate. Furthermore, such rolled-up smart window enables high infrared reflectance after triggered phase transition and acts as a smart lens protective cover for strong radiation. This work supports the feasibility of self-rolling technology in smart windows and lens protection, which promises broad interest and practical applications of self-adapting devices and systems for smart building, intelligent sensors and actuators with the perspective of energy efficiency.