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Realizing high-ranged thermoelectric performance in PbSnS2 crystals

Author

Listed:
  • Shaoping Zhan

    (Beihang University)

  • Tao Hong

    (Beihang University)

  • Bingchao Qin

    (Beihang University)

  • Yingcai Zhu

    (Beihang University)

  • Xiang Feng

    (Beihang University)

  • Lizhong Su

    (Beihang University)

  • Haonan Shi

    (Beihang University)

  • Hao Liang

    (Kunming University of Science and Technology)

  • Qianfan Zhang

    (Beihang University)

  • Xiang Gao

    (Center for High Pressure Science and Technology Advanced Research (HPSTAR))

  • Zhen-Hua Ge

    (Kunming University of Science and Technology)

  • Lei Zheng

    (Beihang University)

  • Dongyang Wang

    (Zhengzhou University)

  • Li-Dong Zhao

    (Beihang University
    Hangzhou Innovation Institute of Beihang University)

Abstract

Great progress has been achieved in p-type SnS thermoelectric compound recently, while the stagnation of the n-type counterpart hinders the construction of thermoelectric devices. Herein, n-type sulfide PbSnS2 with isostructural to SnS is obtained through Pb alloying and achieves a maximum ZT of ~1.2 and an average ZT of ~0.75 within 300–773 K, which originates from enhanced power factor and intrinsically ultralow thermal conductivity. Combining the optimized carrier concentration by Cl doping and enlarged Seebeck coefficient through activating multiple conduction bands evolutions with temperature, favorable power factors are maintained. Besides, the electron doping stabilizes the phase of PbSnS2 and the complex-crystal-structure induced strong anharmonicity results in ultralow lattice thermal conductivity. Moreover, a maximum power generation efficiency of ~2.7% can be acquired in a single-leg device. Our study develops a n-type sulfide PbSnS2 with high performance, which is a potential candidate to match the excellent p-type SnS.

Suggested Citation

  • Shaoping Zhan & Tao Hong & Bingchao Qin & Yingcai Zhu & Xiang Feng & Lizhong Su & Haonan Shi & Hao Liang & Qianfan Zhang & Xiang Gao & Zhen-Hua Ge & Lei Zheng & Dongyang Wang & Li-Dong Zhao, 2022. "Realizing high-ranged thermoelectric performance in PbSnS2 crystals," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-33684-0
    DOI: 10.1038/s41467-022-33684-0
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    References listed on IDEAS

    as
    1. Kanishka Biswas & Jiaqing He & Ivan D. Blum & Chun-I Wu & Timothy P. Hogan & David N. Seidman & Vinayak P. Dravid & Mercouri G. Kanatzidis, 2012. "High-performance bulk thermoelectrics with all-scale hierarchical architectures," Nature, Nature, vol. 489(7416), pages 414-418, September.
    2. Yingcai Zhu & Dongyang Wang & Tao Hong & Lei Hu & Toshiaki Ina & Shaoping Zhan & Bingchao Qin & Haonan Shi & Lizhong Su & Xiang Gao & Li-Dong Zhao, 2022. "Multiple valence bands convergence and strong phonon scattering lead to high thermoelectric performance in p-type PbSe," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Li-Dong Zhao & Shih-Han Lo & Yongsheng Zhang & Hui Sun & Gangjian Tan & Ctirad Uher & C. Wolverton & Vinayak P. Dravid & Mercouri G. Kanatzidis, 2014. "Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals," Nature, Nature, vol. 508(7496), pages 373-377, April.
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    Cited by:

    1. Bingchao Qin & Dongyang Wang & Tao Hong & Yuping Wang & Dongrui Liu & Ziyuan Wang & Xiang Gao & Zhen-Hua Ge & Li-Dong Zhao, 2023. "High thermoelectric efficiency realized in SnSe crystals via structural modulation," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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