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Biochars as Potential Adsorbers of CH 4 , CO 2 and H 2 S

Author

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  • Sumathi Sethupathi

    (Faculty of Engineering and Green Technology, Universiti Tunku Abdul Rahman, 31900 Kampar, Perak, Malaysia)

  • Ming Zhang

    (Department of Environmental Engineering, China Jiliang University, Hangzhou 310018, China)

  • Anushka Upamali Rajapaksha

    (Korea Biochar Research Center & School of Natural Resources and Environmental Science, Kangwon National University, Chuncheon 24341, Korea
    Department of Basic Sciences, Faculty of Health Sciences, The Open University of Sri Lanka, Nawala, Nugegoda 10250, Sri Lanka)

  • Sang Ryong Lee

    (National Institute of Animal Science, RDA, Wanju55365, Korea)

  • Norhusna Mohamad Nor

    (School of Chemical Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Pulau Pinang, Malaysia)

  • Abdul Rahman Mohamed

    (School of Chemical Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Pulau Pinang, Malaysia)

  • Mohammad Al-Wabel

    (Soil Science Department, College of Food & Agricultural Sciences, King Saud University, P.O. Box 2460, Riyadh 11451, Saudi Arabia)

  • Sang Soo Lee

    (Korea Biochar Research Center & School of Natural Resources and Environmental Science, Kangwon National University, Chuncheon 24341, Korea)

  • Yong Sik Ok

    (Korea Biochar Research Center & School of Natural Resources and Environmental Science, Kangwon National University, Chuncheon 24341, Korea)

Abstract

Methane gas, as one of the major biogases, is a potential source of renewable energy for power production. Biochar can be readily used to purify biogas contaminants such as H 2 S and CO 2 . This study assessed the adsorption of CH 4 , H 2 S, and CO 2 onto four different types of biochars. The adsorption dynamics of biochars were investigated in a fixed-bed column, by determining the breakthrough curves and adsorption capacities of biochars. The physicochemical properties of biochars were considered to justify the adsorption performance. The results showed that CH 4 was not adsorbed well by the subjected biochars whereas CO 2 and H 2 S were successfully captured. The H 2 S and CO 2 breakthrough capacity were related to both the surface adsorption and chemical reaction. The adsorption capacity was in the following order: perilla > soybean stover > Korean oak > Japanese oak biochars. The simultaneous adsorption also leads to a competition of sorption sites. Biochars are a promising material for the biogas purification industry.

Suggested Citation

  • Sumathi Sethupathi & Ming Zhang & Anushka Upamali Rajapaksha & Sang Ryong Lee & Norhusna Mohamad Nor & Abdul Rahman Mohamed & Mohammad Al-Wabel & Sang Soo Lee & Yong Sik Ok, 2017. "Biochars as Potential Adsorbers of CH 4 , CO 2 and H 2 S," Sustainability, MDPI, vol. 9(1), pages 1-10, January.
    • Handle: RePEc:gam:jsusta:v:9:y:2017:i:1:p:121-:d:87872
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    References listed on IDEAS

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    1. Ohimain, Elijah Ige & Izah, Sylvester Chibueze, 2017. "A review of biogas production from palm oil mill effluents using different configurations of bioreactors," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 242-253.
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    1. Tayibi, S. & Monlau, F. & Bargaz, A. & Jimenez, R. & Barakat, A., 2021. "Synergy of anaerobic digestion and pyrolysis processes for sustainable waste management: A critical review and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    2. Dissanayake, Pavani Dulanja & You, Siming & Igalavithana, Avanthi Deshani & Xia, Yinfeng & Bhatnagar, Amit & Gupta, Souradeep & Kua, Harn Wei & Kim, Sumin & Kwon, Jung-Hwan & Tsang, Daniel C.W. & Ok, , 2020. "Biochar-based adsorbents for carbon dioxide capture: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    3. Khan, Muhammad Usman & Lee, Jonathan Tian En & Bashir, Muhammad Aamir & Dissanayake, Pavani Dulanja & Ok, Yong Sik & Tong, Yen Wah & Shariati, Mohammad Ali & Wu, Sarah & Ahring, Birgitte Kiaer, 2021. "Current status of biogas upgrading for direct biomethane use: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    4. Xue Li & Hang Liu & Ning Liu & Zhentao Sun & Shifeng Fu & Xiumei Zhan & Jinfeng Yang & Rongxin Zhou & Hongda Zhang & Jiming Zhang & Xiaori Han, 2023. "Pyrolysis temperature had effects on the physicochemical properties of biochar," Plant, Soil and Environment, Czech Academy of Agricultural Sciences, vol. 69(8), pages 363-373.
    5. Chiappero, Marco & Norouzi, Omid & Hu, Mingyu & Demichelis, Francesca & Berruti, Franco & Di Maria, Francesco & Mašek, Ondřej & Fiore, Silvia, 2020. "Review of biochar role as additive in anaerobic digestion processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).

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