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Green Carbon Composite-Derived Polymer Resin and Waste Cotton Fibers for the Removal of Alizarin Red S Dye

Author

Listed:
  • Béchir Wanassi

    (Laboratoire du Génie Textile, LGTex, Université de Monastir, Ksar Hellal 5078, Tunisia
    Institut de Science des Matériaux de Mulhouse, UMR 7361 CNRS, UHA, 15, rue Jean-Starcky, 68057 Mulhouse, France)

  • Ichrak Ben Hariz

    (Société Tunisienne des Industries de Raffinage, P8, 7021 Zarzouna, Tunisia)

  • Camélia Matei Ghimbeu

    (Institut de Science des Matériaux de Mulhouse, UMR 7361 CNRS, UHA, 15, rue Jean-Starcky, 68057 Mulhouse, France)

  • Cyril Vaulot

    (Institut de Science des Matériaux de Mulhouse, UMR 7361 CNRS, UHA, 15, rue Jean-Starcky, 68057 Mulhouse, France)

  • Mejdi Jeguirim

    (Institut de Science des Matériaux de Mulhouse, UMR 7361 CNRS, UHA, 15, rue Jean-Starcky, 68057 Mulhouse, France)

Abstract

Phenolic resin and waste cotton fiber were investigated as green precursors for the successful synthesis using a soft template approach of a composite carbon with carbon nanofibers embedded in a porous carbon network with ordered and periodically pore structure. The optimal composite carbon (PhR/NC-1), exhibited a specific surface area of 394 m 2 ∙g −1 with the existence of both microporosity and mesoporosity. PhR/NC-1 carbon was evaluated as an adsorbent of Alizarin Red S (ARS) dye in batch solution. Various operating conditions were examined and the maximum adsorption capacity of 104 mg∙g −1 was achieved under the following conditions, i.e., T = 25 °C, pH = 3, contact time = 1440 min. The adsorption and desorption heat was assessed by flow micro-calorimetry (FMC), and the presence of both exothermic and endothermic peaks with different intensity was evidenced, meaning a partially reversible nature of ARS adsorption. A pseudo-second-order model proved to be the most suitable kinetic model to describe the ARS adsorption according to the linear regression factor. In addition, the best isotherm equilibrium has been achieved with a Freundlich model. The results show that the eco-friendly composite carbon derived from green phenolic resin mixed with waste cotton fibers improves the removal of ARS dye from textile effluents.

Suggested Citation

  • Béchir Wanassi & Ichrak Ben Hariz & Camélia Matei Ghimbeu & Cyril Vaulot & Mejdi Jeguirim, 2017. "Green Carbon Composite-Derived Polymer Resin and Waste Cotton Fibers for the Removal of Alizarin Red S Dye," Energies, MDPI, vol. 10(9), pages 1-17, September.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:9:p:1321-:d:110619
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    1. Mejdi Jeguirim & Lionel Limousy, 2017. "Biomass Chars: Elaboration, Characterization and Applications," Energies, MDPI, vol. 10(12), pages 1-7, December.
    2. Md. Matiar Rahman & Mahbubul Muttakin & Animesh Pal & Abu Zar Shafiullah & Bidyut Baran Saha, 2019. "A Statistical Approach to Determine Optimal Models for IUPAC-Classified Adsorption Isotherms," Energies, MDPI, vol. 12(23), pages 1-34, November.

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