IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v152y2020icp590-600.html
   My bibliography  Save this article

Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells

Author

Listed:
  • Ingabire, Providence Buregeya
  • Pan, Xueting
  • Haragirimana, Alphonse
  • Li, Na
  • Hu, Zhaoxia
  • Chen, Shouwen

Abstract

A series of quaternary aminated poly(arylene ether sulfone) (QPAES) nanocomposite membranes (QPAES-TiO2/g-C3N4) were fabricated by a double-component nanocomposite system of titanium dioxide/graphitic carbon nitride (TiO2/g-C3N4) and the polymer. TiO2 nanoparticles were firstly functionalized with the highly ion-conductive groups of g-C3N4 to synthesize TiO2/g-C3N4 nanocomposites. Their fundamental properties including water absorbing-swelling behavior, thermo-mechanical property, chemical stability, ion conductivity and fuel cell performance were investigated. The QPAES-TiO2/g-C3N4 membrane containing 0.45 wt% TiO2/g-C3N4 revealed considerable enhancements in ion conductivity, chemical stability and fuel cell performance. It absorbed water as high as 88.7% but expanded less than 13% in the membrane in-plane direction, and showed hydroxide conductivity of 43.8 mS/cm at 80 °C, besides, in a H2/O2 fuel cell, its maximum power density arrived at 64.3 mW/cm2 under a current density of 131.2 mA/cm2 at 80 °C. This work demonstrated that membrane with the proper content of TiO2/g-C3N4 nanocomposites could be a promising candidate for fuel cell applications.

Suggested Citation

  • Ingabire, Providence Buregeya & Pan, Xueting & Haragirimana, Alphonse & Li, Na & Hu, Zhaoxia & Chen, Shouwen, 2020. "Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells," Renewable Energy, Elsevier, vol. 152(C), pages 590-600.
  • Handle: RePEc:eee:renene:v:152:y:2020:i:c:p:590-600
    DOI: 10.1016/j.renene.2020.01.072
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120300914
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2020.01.072?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Benipal, Neeva & Qi, Ji & Gentile, Jacob C. & Li, Wenzhen, 2017. "Direct glycerol fuel cell with polytetrafluoroethylene (PTFE) thin film separator," Renewable Energy, Elsevier, vol. 105(C), pages 647-655.
    2. Neelakandan, S. & Kanagaraj, P. & Nagendran, A. & Rana, D. & Matsuura, T. & Muthumeenal, A., 2015. "Enhancing proton conduction of sulfonated poly (phenylene ether ether sulfone) membrane by charged surface modifying macromolecules for H2/O2 fuel cells," Renewable Energy, Elsevier, vol. 78(C), pages 306-313.
    3. Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    4. Deng, Hao & Wang, Dawei & Xie, Xu & Zhou, Yibo & Yin, Yan & Du, Qing & Jiao, Kui, 2016. "Modeling of hydrogen alkaline membrane fuel cell with interfacial effect and water management optimization," Renewable Energy, Elsevier, vol. 91(C), pages 166-177.
    5. Xu, Yixin & Ye, Niya & Zhang, Dengji & Yang, Yunfei & Yang, Jingshuai & He, Ronghuan, 2018. "Imidazolium functionalized poly(aryl ether ketone) anion exchange membranes having star main chains or side chains," Renewable Energy, Elsevier, vol. 127(C), pages 910-919.
    6. Osmieri, Luigi & Escudero-Cid, Ricardo & Monteverde Videla, Alessandro H.A. & Ocón, Pilar & Specchia, Stefania, 2018. "Application of a non-noble Fe-N-C catalyst for oxygen reduction reaction in an alkaline direct ethanol fuel cell," Renewable Energy, Elsevier, vol. 115(C), pages 226-237.
    7. Herranz, D. & Escudero-Cid, R. & Montiel, M. & Palacio, C. & Fatás, E. & Ocón, P., 2018. "Poly (vinyl alcohol) and poly (benzimidazole) blend membranes for high performance alkaline direct ethanol fuel cells," Renewable Energy, Elsevier, vol. 127(C), pages 883-895.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.
    2. Herranz, D. & Escudero-Cid, R. & Montiel, M. & Palacio, C. & Fatás, E. & Ocón, P., 2018. "Poly (vinyl alcohol) and poly (benzimidazole) blend membranes for high performance alkaline direct ethanol fuel cells," Renewable Energy, Elsevier, vol. 127(C), pages 883-895.
    3. Uma Devi, A. & Muthumeenal, A. & Sabarathinam, R.M. & Nagendran, A., 2017. "Fabrication and electrochemical properties of SPVdF-co-HFP/SPES blend proton exchange membranes for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 102(PA), pages 258-265.
    4. Muthumeenal, A. & Pethaiah, S. Sundar & Nagendran, A., 2016. "Investigation of SPES as PEM for hydrogen production through electrochemical reforming of aqueous methanol," Renewable Energy, Elsevier, vol. 91(C), pages 75-82.
    5. Chen, Bin & Xu, Haoran & Tan, Peng & Zhang, Yuan & Xu, Xiaoming & Cai, Weizi & Chen, Meina & Ni, Meng, 2019. "Thermal modelling of ethanol-fuelled Solid Oxide Fuel Cells," Applied Energy, Elsevier, vol. 237(C), pages 476-486.
    6. Zhengping Zhou & Oksana Zholobko & Xiang-Fa Wu & Ted Aulich & Jivan Thakare & John Hurley, 2020. "Polybenzimidazole-Based Polymer Electrolyte Membranes for High-Temperature Fuel Cells: Current Status and Prospects," Energies, MDPI, vol. 14(1), pages 1-27, December.
    7. Kusworo, Tutuk Djoko & Widayat, Widayat & Utomo, Dani Puji & Pratama, Yulius Harmawan Setya & Arianti, Riska Anindisa Vira, 2020. "Performance evaluation of modified nanohybrid membrane polyethersulfone-nano ZnO (PES-nano ZnO) using three combination effect of PVP, irradiation of ultraviolet and thermal for biodiesel purification," Renewable Energy, Elsevier, vol. 148(C), pages 935-945.
    8. Chino, Isabel & Hendrix, Kimberly & Keramati, Abtin & Muneeb, Omar & Haan, John L., 2019. "A split pH direct liquid fuel cell powered by propanol or glycerol," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    9. Simari, C. & Lo Vecchio, C. & Baglio, V. & Nicotera, I., 2020. "Sulfonated polyethersulfone/polyetheretherketone blend as high performing and cost-effective electrolyte membrane for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 159(C), pages 336-345.
    10. Cheng, Chaochao & Yang, Zirong & Liu, Zhi & Tongsh, Chasen & Zhang, Guobin & Xie, Biao & He, Shaoqing & Jiao, Kui, 2021. "Numerical investigation on the feasibility of metal foam as flow field in alkaline anion exchange membrane fuel cell," Applied Energy, Elsevier, vol. 302(C).
    11. Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    12. Wang, Bowen & Deng, Hao & Jiao, Kui, 2018. "Purge strategy optimization of proton exchange membrane fuel cell with anode recirculation," Applied Energy, Elsevier, vol. 225(C), pages 1-13.
    13. Lo Vecchio, Carmelo & Aricò, Antonino Salvatore & Monforte, Giuseppe & Baglio, Vincenzo, 2018. "EDTA-derived CoNC and FeNC electro-catalysts for the oxygen reduction reaction in acid environment," Renewable Energy, Elsevier, vol. 120(C), pages 342-349.
    14. Nagar, Harsha & Aniya, Vineet & Mondal, Prasenjit, 2020. "High proton conductivity dual modified ionic crosslink membrane for fuel cell application at low humidity condition with molecular dynamics simulations," Renewable Energy, Elsevier, vol. 160(C), pages 1036-1047.
    15. Eman A. El Desouky & Emad A. Soliman & Hessa H. Al-Rasheed & Ayman El-Faham & M. A. Abu-Saied, 2023. "Novel Proton Exchange Membranes Based on Sulfonated Poly(acrylonitrile- co -glycidyl methacrylate)/Poly(vinyl chloride) Composite," Sustainability, MDPI, vol. 15(14), pages 1-24, July.
    16. Fathabadi, Hassan, 2019. "Combining a proton exchange membrane fuel cell (PEMFC) stack with a Li-ion battery to supply the power needs of a hybrid electric vehicle," Renewable Energy, Elsevier, vol. 130(C), pages 714-724.
    17. Chino, Isabel & Vega, Lorenzo & Keramati, Abtin & Hendrix, Kimberly & Haan, John L., 2020. "A direct liquid fuel cell powered by 1,3- or 1,2-propanediol," Applied Energy, Elsevier, vol. 262(C).
    18. Altaf, Faizah & Batool, Rida & Gill, Rohama & Rehman, Zohaib Ur & Majeed, Hammad & Ahmad, Adnan & Shafiq, Muhammad & Dastan, Davoud & Abbas, Ghazanfar & Jacob, Karl, 2021. "Synthesis and electrochemical investigations of ABPBI grafted montmorillonite based polymer electrolyte membranes for PEMFC applications," Renewable Energy, Elsevier, vol. 164(C), pages 709-728.
    19. Luque-Centeno, J.M. & Martínez-Huerta, M.V. & Sebastián, D. & Lemes, G. & Pastor, E. & Lázaro, M.J., 2018. "Bifunctional N-doped graphene Ti and Co nanocomposites for the oxygen reduction and evolution reactions," Renewable Energy, Elsevier, vol. 125(C), pages 182-192.
    20. Deng, Hao & Wang, Dawei & Wang, Renfang & Xie, Xu & Yin, Yan & Du, Qing & Jiao, Kui, 2016. "Effect of electrode design and operating condition on performance of hydrogen alkaline membrane fuel cell," Applied Energy, Elsevier, vol. 183(C), pages 1272-1278.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:152:y:2020:i:c:p:590-600. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.