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Brønsted acidic ionic liquid catalyzed one-pot conversion of cellulose to furanic biocrude and identification of the products using LC-MS

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  • Amarasekara, Ananda S.
  • Gutierrez Reyes, Cristian D.

Abstract

The degradation of cellulose was studied using 1-(3-propylsulfonic)-3-methylimidazolium chloride and 1-(4-butylsulfonic)-3-methylimidazolium chloride acidic ionic liquids as catalysts in acetone at 120 °C for 3.5 h. The products were analyzed using LC-MS with a C18 column and 0.1% formic acid in water - methanol as the eluent solvent. Eleven cellulose degradation products were identified in the furanic biocrude formed using mass spectroscopy. The identified compounds include: 5-hydroxymethylfurfural (HMF), seven products formed from aldol condensation of HMF with one to three acetone molecules, one furfural-acetone aldol product and two HMF ether products. The percent conversions of cellulose to the furanic biocrude product for the two catalysts 1-(3-proylsulfonic)-3-methylimidazolium chloride and 1-(4-butylsulfonic)-3-methylimidazolium chloride were 25.7 and 19.3% respectively.

Suggested Citation

  • Amarasekara, Ananda S. & Gutierrez Reyes, Cristian D., 2019. "Brønsted acidic ionic liquid catalyzed one-pot conversion of cellulose to furanic biocrude and identification of the products using LC-MS," Renewable Energy, Elsevier, vol. 136(C), pages 352-357.
    • Handle: RePEc:eee:renene:v:136:y:2019:i:c:p:352-357
    DOI: 10.1016/j.renene.2018.12.108
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    References listed on IDEAS

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    1. Patel, Madhumita & Kumar, Amit, 2016. "Production of renewable diesel through the hydroprocessing of lignocellulosic biomass-derived bio-oil: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 1293-1307.
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    1. Li, Qingyin & Zhang, Shu & Wang, Yi & Xiang, Jun & Hu, Song & Yuan, Xiangzhou & Gholizadeh, Mortaza & Hu, Xun, 2021. "Ionic liquid coupled with nickel salt for enhancing the hydro-liquefaction efficiency of the major biomass components," Renewable Energy, Elsevier, vol. 175(C), pages 296-306.
    2. Peng, Lincai & Huangfu, Xin & Liu, Yao & Liu, Huai & Zhang, Junhua, 2022. "Natural lignocellulose welded Zr–Al bimetallic hybrids for the sustainable conversion of xylose to alkyl levulinate," Renewable Energy, Elsevier, vol. 193(C), pages 357-366.

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