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Surface modification of commercial carbon felt used as anode for Microbial Fuel Cells

Author

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  • Hidalgo, Diana
  • Tommasi, Tonia
  • Bocchini, Sergio
  • Chiolerio, Alessandro
  • Chiodoni, Angelica
  • Mazzarino, Italo
  • Ruggeri, Bernardo

Abstract

Commercial carbon felt is frequently used as anodic material in MFCs (Microbial Fuel Cells). In this work, it is modified through nitric acid activation and polyaniline deposition with the aim of improving power density. The modified anodic materials are characterized from both morphological and chemical point of views by FESEM (Field Emission Scanning Electron Microscope), EDS (Energy Dispersive Spectroscopy), FT-IR (Fourier Transform Infrared Spectroscopy), resistivity measurements and impedance spectroscopy. In addition, their performances are evaluated by comparing them with commercial carbon felt as anode material in a two-compartment laboratory MFC prototype using Saccaromyces cerevisiae as active microorganism in the anodic chamber. The electrochemical measurements are performed by means of LSV (Linear Sweep Voltammetry) and CI (Current Interrupt) techniques. The power density of the HNO3-treated and the polyaniline-covered carbon felts results 2.5 and 2.9 fold higher than commercial carbon felt, respectively. The increase of the power density obtained by both surface treatments seems to be related with a strong reduction of resistivity of the anodic material.

Suggested Citation

  • Hidalgo, Diana & Tommasi, Tonia & Bocchini, Sergio & Chiolerio, Alessandro & Chiodoni, Angelica & Mazzarino, Italo & Ruggeri, Bernardo, 2016. "Surface modification of commercial carbon felt used as anode for Microbial Fuel Cells," Energy, Elsevier, vol. 99(C), pages 193-201.
    • Handle: RePEc:eee:energy:v:99:y:2016:i:c:p:193-201
    DOI: 10.1016/j.energy.2016.01.039
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    Cited by:

    1. Ortiz-Martínez, V.M. & Salar-García, M.J. & Touati, K. & Hernández-Fernández, F.J. & de los Ríos, A.P. & Belhoucine, F. & Berrabbah, A. Alioua, 2016. "Assessment of spinel-type mixed valence Cu/Co and Ni/Co-based oxides for power production in single-chamber microbial fuel cells," Energy, Elsevier, vol. 113(C), pages 1241-1249.
    2. Christwardana, Marcelinus & Frattini, Domenico & Accardo, Grazia & Yoon, Sung Pil & Kwon, Yongchai, 2018. "Early-stage performance evaluation of flowing microbial fuel cells using chemically treated carbon felt and yeast biocatalyst," Applied Energy, Elsevier, vol. 222(C), pages 369-382.
    3. Frattini, Domenico & Accardo, Grazia & Duarte, Kimberley D.Z. & Kim, Do-Heyoung & Kwon, Yongchai, 2020. "Improved biofilm adhesion and electrochemical properties of a graphite-cement composite with silica nanoflowers versus two benchmark carbon felts," Applied Energy, Elsevier, vol. 261(C).
    4. Duarte, Kimberley D.Z. & Frattini, Domenico & Kwon, Yongchai, 2019. "High performance yeast-based microbial fuel cells by surfactant-mediated gold nanoparticles grown atop a carbon felt anode," Applied Energy, Elsevier, vol. 256(C).
    5. Enas Taha Sayed & Hussain Alawadhi & Khaled Elsaid & A. G. Olabi & Maryam Adel Almakrani & Shaikha Tamim Bin Tamim & Ghada H. M. Alafranji & Mohammad Ali Abdelkareem, 2020. "A Carbon-Cloth Anode Electroplated with Iron Nanostructure for Microbial Fuel Cell Operated with Real Wastewater," Sustainability, MDPI, vol. 12(16), pages 1-11, August.
    6. Wang, Yuyang & Wen, Qing & Chen, Ye & Zheng, Hongtao & Wang, Shuang, 2020. "Enhanced performance of microbial fuel cell with polyaniline/sodium alginate/carbon brush hydrogel bioanode and removal of COD," Energy, Elsevier, vol. 202(C).
    7. Wang, Yuyang & Wen, Qing & Chen, Ye & Li, Wei, 2020. "Conductive polypyrrole-carboxymethyl cellulose-titanium nitride/carbon brush hydrogels as bioanodes for enhanced energy output in microbial fuel cells," Energy, Elsevier, vol. 204(C).
    8. Schilirò, T. & Tommasi, T. & Armato, C. & Hidalgo, D. & Traversi, D. & Bocchini, S. & Gilli, G. & Pirri, C.F., 2016. "The study of electrochemically active planktonic microbes in microbial fuel cells in relation to different carbon-based anode materials," Energy, Elsevier, vol. 106(C), pages 277-284.
    9. Chen, Bor-Yann & Liao, Jia-Hui & Hsueh, Chung-Chuan & Qu, Ziwei & Hsu, An-Wei & Chang, Chang-Tang & Zhang, Shuping, 2018. "Deciphering biostimulation strategy of using medicinal herbs and tea extracts for bioelectricity generation in microbial fuel cells," Energy, Elsevier, vol. 161(C), pages 1042-1054.
    10. Sayed, Enas Taha & Abdelkareem, Mohammad Ali & Alawadhi, Hussain & Elsaid, Khaled & Wilberforce, Tabbi & Olabi, A.G., 2021. "Graphitic carbon nitride/carbon brush composite as a novel anode for yeast-based microbial fuel cells," Energy, Elsevier, vol. 221(C).
    11. Sekar, Aiswarya Devi & Jayabalan, Tamilmani & Muthukumar, Harshiny & Chandrasekaran, Nivedhini Iswarya & Mohamed, Samsudeen Naina & Matheswaran, Manickam, 2019. "Enhancing power generation and treatment of dairy waste water in microbial fuel cell using Cu-doped iron oxide nanoparticles decorated anode," Energy, Elsevier, vol. 172(C), pages 173-180.

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