IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v141y2017icp20-31.html
   My bibliography  Save this article

A fundamental investigation into chemical effects of carbon dioxide on intermediate temperature oxidation of biodiesel surrogate with laminar flow reactor

Author

Listed:
  • Li, Ang
  • Zhu, Lei
  • Deng, Zhiwei
  • Gao, Zhan
  • Huang, Zhen

Abstract

The chemical effects of carbon dioxide on the oxidation of biodiesel surrogate, methyl butanoate (MB) were investigated experimentally in the SJTU laminar flow reactor at equivalence ratios of 1.5, 1 and 0.5, at atmospheric pressure. Generally, there are three kinds of effects from carbon dioxide (CO2): thermal, dilution and chemical effects. In this study, argon was replaced by CO2 as the dilute gas as a way to isolate the chemical effects by keeping the factors of temperature profile and dilution ratio constant. Therefore, the differences in concentrations of species at the exit from the flow reactor could be attributed to the chemical effects of CO2. Good agreement was found between the experimental and the computational results. The chemical effects were classified into two types. First, there was the radical factor, by which the reaction CO2 + H = OH + CO played a significant role in the oxidation of MB. In CO2 atmosphere, radical factors led to the reduction in reactivity and suppressed the decomposition of MB. The second effect was the collision factor, which derived from the high frequency of third-body collisions of CO2. This collision factor contributed to the formation of carbon monoxide and ethane. Moreover, in the combustion of biodiesel engine with EGR, pure chemical effects of CO2 addition decreased the concentration of acetylene as well as suppressed formation of larger PAHs.

Suggested Citation

  • Li, Ang & Zhu, Lei & Deng, Zhiwei & Gao, Zhan & Huang, Zhen, 2017. "A fundamental investigation into chemical effects of carbon dioxide on intermediate temperature oxidation of biodiesel surrogate with laminar flow reactor," Energy, Elsevier, vol. 141(C), pages 20-31.
    • Handle: RePEc:eee:energy:v:141:y:2017:i:c:p:20-31
    DOI: 10.1016/j.energy.2017.09.050
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217315748
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.09.050?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Carraretto, C. & Macor, A. & Mirandola, A. & Stoppato, A. & Tonon, S., 2004. "Biodiesel as alternative fuel: Experimental analysis and energetic evaluations," Energy, Elsevier, vol. 29(12), pages 2195-2211.
    2. An, H. & Yang, W.M. & Chou, S.K. & Chua, K.J., 2012. "Combustion and emissions characteristics of diesel engine fueled by biodiesel at partial load conditions," Applied Energy, Elsevier, vol. 99(C), pages 363-371.
    3. Tsolakis, A. & Megaritis, A. & Wyszynski, M.L. & Theinnoi, K., 2007. "Engine performance and emissions of a diesel engine operating on diesel-RME (rapeseed methyl ester) blends with EGR (exhaust gas recirculation)," Energy, Elsevier, vol. 32(11), pages 2072-2080.
    4. Solaimuthu, C. & Ganesan, V. & Senthilkumar, D. & Ramasamy, K.K., 2015. "Emission reductions studies of a biodiesel engine using EGR and SCR for agriculture operations in developing countries," Applied Energy, Elsevier, vol. 138(C), pages 91-98.
    5. Gui, M.M. & Lee, K.T. & Bhatia, S., 2008. "Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock," Energy, Elsevier, vol. 33(11), pages 1646-1653.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Dexiang & Wang, Yijun & Zhang, Changhua & Li, Ping & Li, Xiangyuan, 2019. "Experimental and numerical investigation of vitiation effects on the auto-ignition of n-heptane at high temperatures," Energy, Elsevier, vol. 174(C), pages 922-931.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. How, H.G. & Teoh, Y.H. & Masjuki, H.H. & Kalam, M.A., 2012. "Impact of coconut oil blends on particulate-phase PAHs and regulated emissions from a light duty diesel engine," Energy, Elsevier, vol. 48(1), pages 500-509.
    2. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sharma, Meeta & Malhotra, R.K., 2009. "Influence of metal contaminants on oxidation stability of Jatropha biodiesel," Energy, Elsevier, vol. 34(9), pages 1271-1275.
    3. Hoseini, S.S. & Najafi, G. & Ghobadian, B. & Mamat, Rizalman & Sidik, Nor Azwadi Che & Azmi, W.H., 2017. "The effect of combustion management on diesel engine emissions fueled with biodiesel-diesel blends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 307-331.
    4. Jaliliantabar, Farzad & Ghobadian, Barat & Carlucci, Antonio Paolo & Najafi, Gholamhassan & Mamat, Rizalman & Ficarella, Antonio & Strafella, Luciano & Santino, Angelo & De Domenico, Stefania, 2020. "A comprehensive study on the effect of pilot injection, EGR rate, IMEP and biodiesel characteristics on a CRDI diesel engine," Energy, Elsevier, vol. 194(C).
    5. Gogoi, T.K. & Baruah, D.C., 2010. "A cycle simulation model for predicting the performance of a diesel engine fuelled by diesel and biodiesel blends," Energy, Elsevier, vol. 35(3), pages 1317-1323.
    6. Mofijur, M. & Atabani, A.E. & Masjuki, H.H. & Kalam, M.A. & Masum, B.M., 2013. "A study on the effects of promising edible and non-edible biodiesel feedstocks on engine performance and emissions production: A comparative evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 391-404.
    7. Lee, H.V. & Taufiq-Yap, Y.H. & Hussein, M.Z. & Yunus, R., 2013. "Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts," Energy, Elsevier, vol. 49(C), pages 12-18.
    8. Yunus khan, T.M. & Badruddin, Irfan Anjum & Badarudin, Ahmad & Banapurmath, N.R. & Salman Ahmed, N.J. & Quadir, G.A. & Al-Rashed, Abdullah A.A.A. & Khaleed, H.M.T. & Kamangar, Sarfaraz, 2015. "Effects of engine variables and heat transfer on the performance of biodiesel fueled IC engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 682-691.
    9. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    10. E, Jiaqiang & Pham, Minhhieu & Zhao, D. & Deng, Yuanwang & Le, DucHieu & Zuo, Wei & Zhu, Hao & Liu, Teng & Peng, Qingguo & Zhang, Zhiqing, 2017. "Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 620-647.
    11. Altarazi, Yazan S.M. & Abu Talib, Abd Rahim & Yu, Jianglong & Gires, Ezanee & Abdul Ghafir, Mohd Fahmi & Lucas, John & Yusaf, Talal, 2022. "Effects of biofuel on engines performance and emission characteristics: A review," Energy, Elsevier, vol. 238(PC).
    12. How, H.G. & Teoh, Y.H. & Krishnan, B. Navaneetha & Le, T.D. & Nguyen, H.T. & Prabhu, C., 2021. "Prediction of optimum Palm Oil Methyl Ester fuel blend for compression ignition engine using Response Surface Methodology," Energy, Elsevier, vol. 234(C).
    13. Arbab, M.I. & Masjuki, H.H. & Varman, M. & Kalam, M.A. & Imtenan, S. & Sajjad, H., 2013. "Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 133-147.
    14. Basha, Syed Ameer & Gopal, K. Raja & Jebaraj, S., 2009. "A review on biodiesel production, combustion, emissions and performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1628-1634, August.
    15. Xue, Jinlin & Grift, Tony E. & Hansen, Alan C., 2011. "Effect of biodiesel on engine performances and emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1098-1116, February.
    16. Sanjid, A. & Masjuki, H.H. & Kalam, M.A. & Rahman, S.M. Ashrafur & Abedin, M.J. & Palash, S.M., 2013. "Impact of palm, mustard, waste cooking oil and Calophyllum inophyllum biofuels on performance and emission of CI engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 664-682.
    17. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul, 2012. "Necessity of biodiesel utilization as a source of renewable energy in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5732-5740.
    18. Ghorbani, Afshin & Bazooyar, Bahamin, 2012. "Optimization of the combustion of SOME (soybean oil methyl ester), B5, B10, B20 and petrodiesel in a semi industrial boiler," Energy, Elsevier, vol. 44(1), pages 217-227.
    19. Rahman, S.M. Ashrafur & Masjuki, H.H. & Kalam, M.A. & Sanjid, A. & Abedin, M.J., 2014. "Assessment of emission and performance of compression ignition engine with varying injection timing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 221-230.
    20. Khandal, S.V. & Banapurmath, N.R. & Gaitonde, V.N. & Hiremath, S.S., 2017. "Paradigm shift from mechanical direct injection diesel engines to advanced injection strategies of diesel homogeneous charge compression ignition (HCCI) engines- A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 369-384.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:141:y:2017:i:c:p:20-31. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.