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Syntheses of carbon porous materials with varied pore sizes and their performances as catalyst supports during methanol oxidation reaction

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  • Lo, An-Ya
  • Hung, Chin-Te
  • Yu, Ningya
  • Kuo, Cheng-Tzu
  • Liu, Shang-Bin

Abstract

Carbon porous materials (CPMs) with extended ranges of pore size and morphology were replicated using various porous silicas, such as zeolites, mesoporous silicas, and photonic crystals, as templates by means of chemical vapor infiltration (CVI) method. The micro-, meso-, and macro-porous carbons so fabricated were adopted as supports for the metal (Pt) catalyst for direct methanol fuel cells (DMFCs), and the supported Pt/CPM electrocatalysts were characterized by a variety of different spectroscopic/analytical techniques, viz. transmission electron microscopy (TEM), Raman, X-ray photoelectron spectroscopy (XPS), gas physisorption/chemisorption analyses, and cyclic voltammetry (CV). That these Pt/CPMs were found to exhibit superior electrocatalytic activities compared to the commercial Pt/XC-72 with a comparable Pt loading during methanol oxidation reaction (MOR) is attributed to the presence of Pt nanoparticles (NPs; typically 1–3nm in size) that are highly dispersed in the CPMs, facilitating an improved tolerance for CO poisoning. While the MOR activity observed for various Pt/CPMs tend to increase with increasing pore size of the carbon supports, Pt catalyst supported on carbon substrates possessing microporosities was found to have superior stability in terms of tolerance for CO poisoning than those with greater pore size or having meso- and macroporosities.

Suggested Citation

  • Lo, An-Ya & Hung, Chin-Te & Yu, Ningya & Kuo, Cheng-Tzu & Liu, Shang-Bin, 2012. "Syntheses of carbon porous materials with varied pore sizes and their performances as catalyst supports during methanol oxidation reaction," Applied Energy, Elsevier, vol. 100(C), pages 66-74.
    • Handle: RePEc:eee:appene:v:100:y:2012:i:c:p:66-74
    DOI: 10.1016/j.apenergy.2012.05.043
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    Cited by:

    1. Fang, Yuan & Zhang, Tingting & Wang, Yonghui & Chen, Yuanzhen & Liu, Yan & Wu, Wenling & Zhu, Jianfeng, 2020. "The highly efficient cathode of framework structural Fe2O3/Mn2O3 in passive direct methanol fuel cells," Applied Energy, Elsevier, vol. 259(C).
    2. Mehmood, Asad & Ha, Heung Yong, 2014. "Performance restoration of direct methanol fuel cells in long-term operation using a hydrogen evolution method," Applied Energy, Elsevier, vol. 114(C), pages 164-171.
    3. Zainoodin, A.M. & Kamarudin, S.K. & Masdar, M.S. & Daud, W.R.W. & Mohamad, A.B. & Sahari, J., 2014. "High power direct methanol fuel cell with a porous carbon nanofiber anode layer," Applied Energy, Elsevier, vol. 113(C), pages 946-954.
    4. Borghei, Maryam & Scotti, Gianmario & Kanninen, Petri & Weckman, Timo & Anoshkin, Ilya V. & Nasibulin, Albert G. & Franssila, Sami & Kauppinen, Esko I. & Kallio, Tanja & Ruiz, Virginia, 2014. "Enhanced performance of a silicon microfabricated direct methanol fuel cell with PtRu catalysts supported on few-walled carbon nanotubes," Energy, Elsevier, vol. 65(C), pages 612-620.
    5. Mehmood, Asad & An, Myung-Gi & Ha, Heung Yong, 2014. "Physical degradation of cathode catalyst layer: A major contributor to accelerated water flooding in long-term operation of DMFCs," Applied Energy, Elsevier, vol. 129(C), pages 346-353.

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