IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v8y2017i1d10.1038_ncomms15938.html
   My bibliography  Save this article

High performance platinum single atom electrocatalyst for oxygen reduction reaction

Author

Listed:
  • Jing Liu

    (State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Menggai Jiao

    (University of Chinese Academy of Sciences
    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences)

  • Lanlu Lu

    (Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences)

  • Heather M. Barkholtz

    (Argonne National Laboratory)

  • Yuping Li

    (Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Ying Wang

    (College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan University)

  • Luhua Jiang

    (Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

  • Zhijian Wu

    (State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences)

  • Di-jia Liu

    (Argonne National Laboratory)

  • Lin Zhuang

    (College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan University)

  • Chao Ma

    (Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China)

  • Jie Zeng

    (Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China)

  • Bingsen Zhang

    (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences)

  • Dangsheng Su

    (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences
    Fritz Haber Institute of the Max Planck Society)

  • Ping Song

    (State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences)

  • Wei Xing

    (State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences)

  • Weilin Xu

    (State Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences)

  • Ying Wang

    (University of Chinese Academy of Sciences)

  • Zheng Jiang

    (Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences)

  • Gongquan Sun

    (Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences)

Abstract

For the large-scale sustainable implementation of polymer electrolyte membrane fuel cells in vehicles, high-performance electrocatalysts with low platinum consumption are desirable for use as cathode material during the oxygen reduction reaction in fuel cells. Here we report a carbon black-supported cost-effective, efficient and durable platinum single-atom electrocatalyst with carbon monoxide/methanol tolerance for the cathodic oxygen reduction reaction. The acidic single-cell with such a catalyst as cathode delivers high performance, with power density up to 680 mW cm−2 at 80 °C with a low platinum loading of 0.09 mgPt cm−2, corresponding to a platinum utilization of 0.13 gPt kW−1 in the fuel cell. Good fuel cell durability is also observed. Theoretical calculations reveal that the main effective sites on such platinum single-atom electrocatalysts are single-pyridinic-nitrogen-atom-anchored single-platinum-atom centres, which are tolerant to carbon monoxide/methanol, but highly active for the oxygen reduction reaction.

Suggested Citation

  • Jing Liu & Menggai Jiao & Lanlu Lu & Heather M. Barkholtz & Yuping Li & Ying Wang & Luhua Jiang & Zhijian Wu & Di-jia Liu & Lin Zhuang & Chao Ma & Jie Zeng & Bingsen Zhang & Dangsheng Su & Ping Song &, 2017. "High performance platinum single atom electrocatalyst for oxygen reduction reaction," Nature Communications, Nature, vol. 8(1), pages 1-10, August.
    • Handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_ncomms15938
    DOI: 10.1038/ncomms15938
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms15938
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/ncomms15938?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Jiajun Zhao & Cehuang Fu & Ke Ye & Zheng Liang & Fangling Jiang & Shuiyun Shen & Xiaoran Zhao & Lu Ma & Zulipiya Shadike & Xiaoming Wang & Junliang Zhang & Kun Jiang, 2022. "Manipulating the oxygen reduction reaction pathway on Pt-coordinated motifs," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Pu, Zonghua & Zhang, Gaixia & Hassanpour, Amir & Zheng, Dewen & Wang, Shanyu & Liao, Shijun & Chen, Zhangxin & Sun, Shuhui, 2021. "Regenerative fuel cells: Recent progress, challenges, perspectives and their applications for space energy system," Applied Energy, Elsevier, vol. 283(C).
    3. Jiachen Li & Yuqiang Ma & Cong Zhang & Chi Zhang & Huijun Ma & Zhaoqi Guo & Ning Liu & Ming Xu & Haixia Ma & Jieshan Qiu, 2023. "Green electrosynthesis of 3,3’-diamino-4,4’-azofurazan energetic materials coupled with energy-efficient hydrogen production over Pt-based catalysts," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    4. Jinfa Chang & Guanzhi Wang & Xiaoxia Chang & Zhenzhong Yang & Han Wang & Boyang Li & Wei Zhang & Libor Kovarik & Yingge Du & Nina Orlovskaya & Bingjun Xu & Guofeng Wang & Yang Yang, 2023. "Interface synergism and engineering of Pd/Co@N-C for direct ethanol fuel cells," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    5. Cong Liu & Bingbao Mei & Zhaoping Shi & Zheng Jiang & Junjie Ge & Wei Xing & Ping Song & Weilin Xu, 2024. "Operando formation of highly efficient electrocatalysts induced by heteroatom leaching," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_ncomms15938. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.