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Facilitating alkaline hydrogen evolution reaction on the hetero-interfaced Ru/RuO2 through Pt single atoms doping

Author

Listed:
  • Yiming Zhu

    (Tongji University)

  • Malte Klingenhof

    (Technische Universität Berlin, Department of Chemistry)

  • Chenlong Gao

    (Tongji University)

  • Toshinari Koketsu

    (Technische Universität Berlin, Department of Chemistry)

  • Gregor Weiser

    (Technische Universität Berlin, Department of Chemistry)

  • Yecan Pi

    (Yangzhou University)

  • Shangheng Liu

    (Xiamen University)

  • Lijun Sui

    (Tongji University)

  • Jingrong Hou

    (Tongji University)

  • Jiayi Li

    (Tongji University)

  • Haomin Jiang

    (Baoshan Iron & Steel Co., Ltd.
    State Key Laboratory of Development and Application Technology of Automotive Steels, Baosteel)

  • Limin Xu

    (Baoshan Iron & Steel Co., Ltd.
    Shanghai Engineering Research Center of Metals for Lightweight Transportation)

  • Wei-Hsiang Huang

    (National Synchrotron Radiation Research Center)

  • Chih-Wen Pao

    (National Synchrotron Radiation Research Center)

  • Menghao Yang

    (Tongji University)

  • Zhiwei Hu

    (Max Planck Institute for Chemical Physics of Solids)

  • Peter Strasser

    (Technische Universität Berlin, Department of Chemistry)

  • Jiwei Ma

    (Tongji University)

Abstract

Exploring an active and cost-effective electrocatalyst alternative to carbon-supported platinum nanoparticles for alkaline hydrogen evolution reaction (HER) have remained elusive to date. Here, we report a catalyst based on platinum single atoms (SAs) doped into the hetero-interfaced Ru/RuO2 support (referred to as Pt-Ru/RuO2), which features a low HER overpotential, an excellent stability and a distinctly enhanced cost-based activity compared to commercial Pt/C and Ru/C in 1 M KOH. Advanced physico-chemical characterizations disclose that the sluggish water dissociation is accelerated by RuO2 while Pt SAs and the metallic Ru facilitate the subsequent H* combination. Theoretical calculations correlate with the experimental findings. Furthermore, Pt-Ru/RuO2 only requires 1.90 V to reach 1 A cm−2 and delivers a high price activity in the anion exchange membrane water electrolyzer, outperforming the benchmark Pt/C. This research offers a feasible guidance for developing the noble metal-based catalysts with high performance and low cost toward practical H2 production.

Suggested Citation

  • Yiming Zhu & Malte Klingenhof & Chenlong Gao & Toshinari Koketsu & Gregor Weiser & Yecan Pi & Shangheng Liu & Lijun Sui & Jingrong Hou & Jiayi Li & Haomin Jiang & Limin Xu & Wei-Hsiang Huang & Chih-We, 2024. "Facilitating alkaline hydrogen evolution reaction on the hetero-interfaced Ru/RuO2 through Pt single atoms doping," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45654-9
    DOI: 10.1038/s41467-024-45654-9
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    as
    1. Jiaxi Zhang & Longhai Zhang & Jiamin Liu & Chengzhi Zhong & Yuanhua Tu & Peng Li & Li Du & Shengli Chen & Zhiming Cui, 2022. "OH spectator at IrMo intermetallic narrowing activity gap between alkaline and acidic hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Kang Jiang & Boyang Liu & Min Luo & Shoucong Ning & Ming Peng & Yang Zhao & Ying-Rui Lu & Ting-Shan Chan & Frank M. F. Groot & Yongwen Tan, 2019. "Single platinum atoms embedded in nanoporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    3. Jie Dai & Yinlong Zhu & Yu Chen & Xue Wen & Mingce Long & Xinhao Wu & Zhiwei Hu & Daqin Guan & Xixi Wang & Chuan Zhou & Qian Lin & Yifei Sun & Shih-Chang Weng & Huanting Wang & Wei Zhou & Zongping Sha, 2022. "Hydrogen spillover in complex oxide multifunctional sites improves acidic hydrogen evolution electrocatalysis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Kang Jiang & Min Luo & Zhixiao Liu & Ming Peng & Dechao Chen & Ying-Rui Lu & Ting-Shan Chan & Frank M. F. Groot & Yongwen Tan, 2021. "Rational strain engineering of single-atom ruthenium on nanoporous MoS2 for highly efficient hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    5. Yufei Zhao & Priyank V. Kumar & Xin Tan & Xinxin Lu & Xiaofeng Zhu & Junjie Jiang & Jian Pan & Shibo Xi & Hui Ying Yang & Zhipeng Ma & Tao Wan & Dewei Chu & Wenjie Jiang & Sean C. Smith & Rose Amal & , 2022. "Modulating Pt-O-Pt atomic clusters with isolated cobalt atoms for enhanced hydrogen evolution catalysis," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    6. Guangkai Li & Haeseong Jang & Shangguo Liu & Zijian Li & Min Gyu Kim & Qing Qin & Xien Liu & Jaephil Cho, 2022. "The synergistic effect of Hf-O-Ru bonds and oxygen vacancies in Ru/HfO2 for enhanced hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Yinlong Zhu & Hassan A. Tahini & Zhiwei Hu & Jie Dai & Yubo Chen & Hainan Sun & Wei Zhou & Meilin Liu & Sean C. Smith & Huanting Wang & Zongping Shao, 2019. "Unusual synergistic effect in layered Ruddlesden−Popper oxide enables ultrafast hydrogen evolution," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    8. Zhiqi Zhang & Jiapeng Liu & Jian Wang & Qi Wang & Yuhao Wang & Kai Wang & Zheng Wang & Meng Gu & Zhenghua Tang & Jongwoo Lim & Tianshou Zhao & Francesco Ciucci, 2021. "Single-atom catalyst for high-performance methanol oxidation," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    9. Wei Liu & Haisong Feng & Yusen Yang & Yiming Niu & Lei Wang & Pan Yin & Song Hong & Bingsen Zhang & Xin Zhang & Min Wei, 2022. "Highly-efficient RuNi single-atom alloy catalysts toward chemoselective hydrogenation of nitroarenes," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    10. Kai Ling Zhou & Zelin Wang & Chang Bao Han & Xiaoxing Ke & Changhao Wang & Yuhong Jin & Qianqian Zhang & Jingbing Liu & Hao Wang & Hui Yan, 2021. "Platinum single-atom catalyst coupled with transition metal/metal oxide heterostructure for accelerating alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    11. Wei Tan & Shaohua Xie & Duy Le & Weijian Diao & Meiyu Wang & Ke-Bin Low & Dave Austin & Sampyo Hong & Fei Gao & Lin Dong & Lu Ma & Steven N. Ehrlich & Talat S. Rahman & Fudong Liu, 2022. "Fine-tuned local coordination environment of Pt single atoms on ceria controls catalytic reactivity," Nature Communications, Nature, vol. 13(1), pages 1-16, December.
    12. Niancai Cheng & Samantha Stambula & Da Wang & Mohammad Norouzi Banis & Jian Liu & Adam Riese & Biwei Xiao & Ruying Li & Tsun-Kong Sham & Li-Min Liu & Gianluigi A. Botton & Xueliang Sun, 2016. "Platinum single-atom and cluster catalysis of the hydrogen evolution reaction," Nature Communications, Nature, vol. 7(1), pages 1-9, December.
    13. Kun Qi & Xiaoqiang Cui & Lin Gu & Shansheng Yu & Xiaofeng Fan & Mingchuan Luo & Shan Xu & Ningbo Li & Lirong Zheng & Qinghua Zhang & Jingyuan Ma & Yue Gong & Fan Lv & Kai Wang & Haihua Huang & Wei Zha, 2019. "Single-atom cobalt array bound to distorted 1T MoS2 with ensemble effect for hydrogen evolution catalysis," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    14. Fanpeng Cheng & Xianyun Peng & Lingzi Hu & Bin Yang & Zhongjian Li & Chung-Li Dong & Jeng-Lung Chen & Liang-Ching Hsu & Lecheng Lei & Qiang Zheng & Ming Qiu & Liming Dai & Yang Hou, 2022. "Accelerated water activation and stabilized metal-organic framework via constructing triangular active-regions for ampere-level current density hydrogen production," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
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