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Active oxygen species mediate the iron-promoting electrocatalysis of oxygen evolution reaction on metal oxyhydroxides

Author

Listed:
  • Qu Jiang

    (Shanghai Jiao Tong University)

  • Sihong Wang

    (Shanghai Jiao Tong University)

  • Chaoran Zhang

    (Shanghai Jiao Tong University)

  • Ziyang Sheng

    (Shanghai Jiao Tong University)

  • Haoyue Zhang

    (Shanghai Jiao Tong University)

  • Ruohan Feng

    (Shanghai Jiao Tong University)

  • Yuanman Ni

    (Shanghai Jiao Tong University)

  • Xiaoan Tang

    (Shanghai Jiao Tong University)

  • Yichuan Gu

    (Shanghai Jiao Tong University)

  • Xinhong Zhou

    (Shanghai Jiao Tong University)

  • Seunghwa Lee

    (Changwon National University)

  • Di Zhang

    (Shanghai Jiao Tong University)

  • Fang Song

    (Shanghai Jiao Tong University)

Abstract

Iron is an extraordinary promoter to impose nickel/cobalt (hydr)oxides as the most active oxygen evolution reaction catalysts, whereas the synergistic effect is actively debated. Here, we unveil that active oxygen species mediate a strong electrochemical interaction between iron oxides (FeOxHy) and the supporting metal oxyhydroxides. Our survey on the electrochemical behavior of nine supporting metal oxyhydroxides (M(O)OH) uncovers that FeOxHy synergistically promotes substrates that can produce active oxygen species exclusively. Tafel slopes correlate with the presence and kind of oxygen species. Moreover, the oxygen evolution reaction onset potentials of FeOxHy@M(O)OH coincide with the emerging potentials of active oxygen species, whereas large potential gaps are present for intact M(O)OH. Chemical probe experiments suggest that active oxygen species could act as proton acceptors and/or mediators for proton transfer and/or diffusion in cooperative catalysis. This discovery offers a new insight to understand the synergistic catalysis of Fe-based oxygen evolution reaction electrocatalysts.

Suggested Citation

  • Qu Jiang & Sihong Wang & Chaoran Zhang & Ziyang Sheng & Haoyue Zhang & Ruohan Feng & Yuanman Ni & Xiaoan Tang & Yichuan Gu & Xinhong Zhou & Seunghwa Lee & Di Zhang & Fang Song, 2023. "Active oxygen species mediate the iron-promoting electrocatalysis of oxygen evolution reaction on metal oxyhydroxides," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42646-z
    DOI: 10.1038/s41467-023-42646-z
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    References listed on IDEAS

    as
    1. Dong Young Chung & Pietro P. Lopes & Pedro Farinazzo Bergamo Dias Martins & Haiying He & Tomoya Kawaguchi & Peter Zapol & Hoydoo You & Dusan Tripkovic & Dusan Strmcnik & Yisi Zhu & Soenke Seifert & Su, 2020. "Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction," Nature Energy, Nature, vol. 5(3), pages 222-230, March.
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