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Embedding oxophilic rare-earth single atom in platinum nanoclusters for efficient hydrogen electro-oxidation

Author

Listed:
  • Xiaoning Wang

    (China University of Petroleum)

  • Yanfu Tong

    (China University of Petroleum)

  • Wenting Feng

    (China University of Petroleum)

  • Pengyun Liu

    (China University of Petroleum)

  • Xuejin Li

    (China University of Petroleum)

  • Yongpeng Cui

    (China University of Petroleum)

  • Tonghui Cai

    (China University of Petroleum)

  • Lianming Zhao

    (China University of Petroleum)

  • Qingzhong Xue

    (China University of Petroleum)

  • Zifeng Yan

    (China University of Petroleum)

  • Xun Yuan

    (Qingdao University of Science and Technology)

  • Wei Xing

    (China University of Petroleum)

Abstract

Designing Pt-based electrocatalysts with high catalytic activity and CO tolerance is challenging but extremely desirable for alkaline hydrogen oxidation reaction. Herein we report the design of a series of single-atom lanthanide (La, Ce, Pr, Nd, and Lu)-embedded ultrasmall Pt nanoclusters for efficient alkaline hydrogen electro-oxidation catalysis based on vapor filling and spatially confined reduction/growth of metal species. Mechanism studies reveal that oxophilic single-atom lanthanide species in Pt nanoclusters can serve as the Lewis acid site for selective OH- adsorption and regulate the binding strength of intermediates on Pt sites, which promotes the kinetics of hydrogen oxidation and CO oxidation by accelerating the combination of OH− and *H/*CO in kinetics and thermodynamics, endowing the electrocatalyst with up to 14.3-times higher mass activity than commercial Pt/C and enhanced CO tolerance. This work may shed light on the design of metal nanocluster-based electrocatalysts for energy conversion.

Suggested Citation

  • Xiaoning Wang & Yanfu Tong & Wenting Feng & Pengyun Liu & Xuejin Li & Yongpeng Cui & Tonghui Cai & Lianming Zhao & Qingzhong Xue & Zifeng Yan & Xun Yuan & Wei Xing, 2023. "Embedding oxophilic rare-earth single atom in platinum nanoclusters for efficient hydrogen electro-oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39475-5
    DOI: 10.1038/s41467-023-39475-5
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