IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37360-9.html
   My bibliography  Save this article

The built-in electric field across FeN/Fe3N interface for efficient electrochemical reduction of CO2 to CO

Author

Listed:
  • Jie Yin

    (Lanzhou University)

  • Jing Jin

    (Lanzhou University)

  • Zhouyang Yin

    (Brown University)

  • Liu Zhu

    (Electron Microscopy Centre of Lanzhou University, Lanzhou University)

  • Xin Du

    (Zhengzhou University)

  • Yong Peng

    (Electron Microscopy Centre of Lanzhou University, Lanzhou University)

  • Pinxian Xi

    (Lanzhou University)

  • Chun-Hua Yan

    (Lanzhou University
    Peking University)

  • Shouheng Sun

    (Brown University)

Abstract

Nanostructured metal-nitrides have attracted tremendous interest as a new generation of catalysts for electroreduction of CO2, but these structures have limited activity and stability in the reduction condition. Herein, we report a method of fabricating FeN/Fe3N nanoparticles with FeN/Fe3N interface exposed on the NP surface for efficient electrochemical CO2 reduction reaction (CO2RR). The FeN/Fe3N interface is populated with Fe−N4 and Fe−N2 coordination sites respectively that show the desired catalysis synergy to enhance the reduction of CO2 to CO. The CO Faraday efficiency reaches 98% at −0.4 V vs. reversible hydrogen electrode, and the FE stays stable from −0.4 to −0.9 V during the 100 h electrolysis time period. This FeN/Fe3N synergy arises from electron transfer from Fe3N to FeN and the preferred CO2 adsorption and reduction to *COOH on FeN. Our study demonstrates a reliable interface control strategy to improve catalytic efficiency of the Fe–N structure for CO2RR.

Suggested Citation

  • Jie Yin & Jing Jin & Zhouyang Yin & Liu Zhu & Xin Du & Yong Peng & Pinxian Xi & Chun-Hua Yan & Shouheng Sun, 2023. "The built-in electric field across FeN/Fe3N interface for efficient electrochemical reduction of CO2 to CO," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37360-9
    DOI: 10.1038/s41467-023-37360-9
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37360-9
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-37360-9?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Hong Bin Yang & Sung-Fu Hung & Song Liu & Kaidi Yuan & Shu Miao & Liping Zhang & Xiang Huang & Hsin-Yi Wang & Weizheng Cai & Rong Chen & Jiajian Gao & Xiaofeng Yang & Wei Chen & Yanqiang Huang & Hao M, 2018. "Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction," Nature Energy, Nature, vol. 3(2), pages 140-147, February.
    2. Peng Wang & Yingying Ren & Rutao Wang & Peng Zhang & Mingjie Ding & Caixia Li & Danyang Zhao & Zhao Qian & Zhiwei Zhang & Luyuan Zhang & Longwei Yin, 2020. "Atomically dispersed cobalt catalyst anchored on nitrogen-doped carbon nanosheets for lithium-oxygen batteries," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    3. Sai Zhang & Zheng-Qing Huang & Yuanyuan Ma & Wei Gao & Jing Li & Fangxian Cao & Lin Li & Chun-Ran Chang & Yongquan Qu, 2017. "Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2," Nature Communications, Nature, vol. 8(1), pages 1-11, August.
    4. Wen Ju & Alexander Bagger & Guang-Ping Hao & Ana Sofia Varela & Ilya Sinev & Volodymyr Bon & Beatriz Roldan Cuenya & Stefan Kaskel & Jan Rossmeisl & Peter Strasser, 2017. "Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    5. Bijandra Kumar & Mohammad Asadi & Davide Pisasale & Suman Sinha-Ray & Brian A. Rosen & Richard Haasch & Jeremiah Abiade & Alexander L. Yarin & Amin Salehi-Khojin, 2013. "Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction," Nature Communications, Nature, vol. 4(1), pages 1-8, December.
    6. Run Shi & Jiahao Guo & Xuerui Zhang & Geoffrey I. N. Waterhouse & Zhaojun Han & Yunxuan Zhao & Lu Shang & Chao Zhou & Lei Jiang & Tierui Zhang, 2020. "Efficient wettability-controlled electroreduction of CO2 to CO at Au/C interfaces," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ji Wei Sun & Xuefeng Wu & Peng Fei Liu & Jiacheng Chen & Yuanwei Liu & Zhen Xin Lou & Jia Yue Zhao & Hai Yang Yuan & Aiping Chen & Xue Lu Wang & Minghui Zhu & Sheng Dai & Hua Gui Yang, 2023. "Scalable synthesis of coordinatively unsaturated metal-nitrogen sites for large-scale CO2 electrolysis," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    2. Sung-Fu Hung & Aoni Xu & Xue Wang & Fengwang Li & Shao-Hui Hsu & Yuhang Li & Joshua Wicks & Eduardo González Cervantes & Armin Sedighian Rasouli & Yuguang C. Li & Mingchuan Luo & Dae-Hyun Nam & Ning W, 2022. "A metal-supported single-atom catalytic site enables carbon dioxide hydrogenation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Eamonn Murphy & Yuanchao Liu & Ivana Matanovic & Martina Rüscher & Ying Huang & Alvin Ly & Shengyuan Guo & Wenjie Zang & Xingxu Yan & Andrea Martini & Janis Timoshenko & Beatriz Roldán Cuenya & Iryna , 2023. "Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    4. Chia-Shuo Hsu & Jiali Wang & You-Chiuan Chu & Jui-Hsien Chen & Chia-Ying Chien & Kuo-Hsin Lin & Li Duan Tsai & Hsiao-Chien Chen & Yen-Fa Liao & Nozomu Hiraoka & Yuan-Chung Cheng & Hao Ming Chen, 2023. "Activating dynamic atomic-configuration for single-site electrocatalyst in electrochemical CO2 reduction," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    5. Yuzhu Zhou & Quan Zhou & Hengjie Liu & Wenjie Xu & Zhouxin Wang & Sicong Qiao & Honghe Ding & Dongliang Chen & Junfa Zhu & Zeming Qi & Xiaojun Wu & Qun He & Li Song, 2023. "Asymmetric dinitrogen-coordinated nickel single-atomic sites for efficient CO2 electroreduction," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Liuzhuang Xing & Qian Yang & Chen Zhu & Yilian Bai & Yurong Tang & Magnus Rueping & Yunfei Cai, 2023. "Poly(heptazine imide) ligand exchange enables remarkable low catalyst loadings in heterogeneous metallaphotocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Charles E. Creissen & Marc Fontecave, 2022. "Keeping sight of copper in single-atom catalysts for electrochemical carbon dioxide reduction," Nature Communications, Nature, vol. 13(1), pages 1-4, December.
    8. Jiqing Jiao & Qing Yuan & Meijie Tan & Xiaoqian Han & Mingbin Gao & Chao Zhang & Xuan Yang & Zhaolin Shi & Yanbin Ma & Hai Xiao & Jiangwei Zhang & Tongbu Lu, 2023. "Constructing asymmetric double-atomic sites for synergistic catalysis of electrochemical CO2 reduction," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    9. Yilong Zhao & Yunxuan Ding & Wenlong Li & Chang Liu & Yingzheng Li & Ziqi Zhao & Yu Shan & Fei Li & Licheng Sun & Fusheng Li, 2023. "Efficient urea electrosynthesis from carbon dioxide and nitrate via alternating Cu–W bimetallic C–N coupling sites," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Zhang, Xue & Li, Fanghua & Wang, Jiahong & Zhao, Haitao & Yu, Xue-Feng, 2021. "Strategy for improving the activity and selectivity of CO2 electroreduction on flexible carbon materials for carbon neutral," Applied Energy, Elsevier, vol. 298(C).
    11. Hassan Pourbabaei & Ali Salehi & Sepide Sadat Ebrahimi & Fazel Khodaparasrt, 2020. "Variations of soil physicochemical properties and vegetation cover under different altitudinal gradient, western Hyrcanean forest, north of Iran," Journal of Forest Science, Czech Academy of Agricultural Sciences, vol. 66(4), pages 159-169.
    12. Yan Lin & Tuo Wang & Lili Zhang & Gong Zhang & Lulu Li & Qingfeng Chang & Zifan Pang & Hui Gao & Kai Huang & Peng Zhang & Zhi-Jian Zhao & Chunlei Pei & Jinlong Gong, 2023. "Tunable CO2 electroreduction to ethanol and ethylene with controllable interfacial wettability," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    13. Wang, Honglin & Liu, Yanrong & Laaksonen, Aatto & Krook-Riekkola, Anna & Yang, Zhuhong & Lu, Xiaohua & Ji, Xiaoyan, 2020. "Carbon recycling – An immense resource and key to a smart climate engineering: A survey of technologies, cost and impurity impact," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    14. Mingxu Sun & Jiamin Cheng & Miho Yamauchi, 2024. "Gas diffusion enhanced electrode with ultrathin superhydrophobic macropore structure for acidic CO2 electroreduction," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    15. Shulin Liu & Minghua Dong & Yuxuan Wu & Sen Luan & Yu Xin & Juan Du & Shaopeng Li & Huizhen Liu & Buxing Han, 2022. "Solid surface frustrated Lewis pair constructed on layered AlOOH for hydrogenation reaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    16. Pribyl-Kranewitter, B. & Beard, A. & Gîjiu, C.L. & Dinculescu, D. & Schmidt, T.J., 2022. "Influence of low-temperature electrolyser design on economic and environmental potential of CO and HCOOH production: A techno-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    17. Lin Li & Ying Lv & Hongting Sheng & Yonglei Du & Haifeng Li & Yapei Yun & Ziyi Zhang & Haizhu Yu & Manzhou Zhu, 2023. "A low-nuclear Ag4 nanocluster as a customized catalyst for the cyclization of propargylamine with CO2," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    18. Shuo Zhang & Jianghua Wu & Mengting Zheng & Xin Jin & Zihan Shen & Zhonghua Li & Yanjun Wang & Quan Wang & Xuebin Wang & Hui Wei & Jiangwei Zhang & Peng Wang & Shanqing Zhang & Liyan Yu & Lifeng Dong , 2023. "Fe/Cu diatomic catalysts for electrochemical nitrate reduction to ammonia," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    19. Lin, Mei-Chen & Lin, Yu-Ling, 2021. "Idiosyncratic skewness and cross-section of stock returns: Evidence from Taiwan," International Review of Financial Analysis, Elsevier, vol. 77(C).
    20. Zhigang Chen & Yafeng Xu & Ding Ding & Ge Song & Xingxing Gan & Hao Li & Wei Wei & Jian Chen & Zhiyun Li & Zhongmiao Gong & Xiaoming Dong & Chengfeng Zhu & Nana Yang & Jingyuan Ma & Rui Gao & Dan Luo , 2022. "Thermal migration towards constructing W-W dual-sites for boosted alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37360-9. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.