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Effect of current density on the solid electrolyte interphase formation at the lithium∣Li6PS5Cl interface

Author

Listed:
  • Sudarshan Narayanan

    (University of Oxford
    The Faraday Institution Quad One)

  • Ulderico Ulissi

    (Nissan Technical Centre Europe)

  • Joshua S. Gibson

    (University of Oxford
    The Faraday Institution Quad One)

  • Yvonne A. Chart

    (University of Oxford
    The Faraday Institution Quad One)

  • Robert S. Weatherup

    (University of Oxford
    The Faraday Institution Quad One)

  • Mauro Pasta

    (University of Oxford
    The Faraday Institution Quad One)

Abstract

Understanding the chemical composition and morphological evolution of the solid electrolyte interphase (SEI) formed at the interface between the lithium metal electrode and an inorganic solid-state electrolyte is crucial for developing reliable all-solid-state lithium batteries. To better understand the interaction between these cell components, we carry out X-ray photoemission spectroscopy (XPS) measurements during lithium plating on the surface of a Li6PS5Cl solid-state electrolyte pellet using an electron beam. The analyses of the XPS data highlight the role of Li plating current density on the evolution of a uniform and ionically conductive (i.e., Li3P-rich) SEI capable of decreasing the electrode∣solid electrolyte interfacial resistance. The XPS findings are validated via electrochemical impedance spectrsocopy measurements of all-solid-state lithium-based cells.

Suggested Citation

  • Sudarshan Narayanan & Ulderico Ulissi & Joshua S. Gibson & Yvonne A. Chart & Robert S. Weatherup & Mauro Pasta, 2022. "Effect of current density on the solid electrolyte interphase formation at the lithium∣Li6PS5Cl interface," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34855-9
    DOI: 10.1038/s41467-022-34855-9
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    References listed on IDEAS

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