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Gas permeation through graphdiyne-based nanoporous membranes

Author

Listed:
  • Zhihua Zhou

    (Xiamen University)

  • Yongtao Tan

    (University of Manchester
    University of Manchester)

  • Qian Yang

    (University of Manchester
    University of Manchester)

  • Achintya Bera

    (University of Manchester
    University of Manchester)

  • Zecheng Xiong

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Mehmet Yagmurcukardes

    (Izmir Institute of Technology)

  • Minsoo Kim

    (University of Manchester
    University of Manchester)

  • Yichao Zou

    (University of Manchester)

  • Guanghua Wang

    (Xiamen University)

  • Artem Mishchenko

    (University of Manchester
    University of Manchester)

  • Ivan Timokhin

    (University of Manchester
    University of Manchester)

  • Canbin Wang

    (Xiamen University)

  • Hao Wang

    (Xiamen University)

  • Chongyang Yang

    (Xiamen University)

  • Yizhen Lu

    (Xiamen University)

  • Radha Boya

    (University of Manchester
    University of Manchester)

  • Honggang Liao

    (Xiamen University)

  • Sarah Haigh

    (University of Manchester)

  • Huibiao Liu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Francois M. Peeters

    (University of Antwerp)

  • Yuliang Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Andre K. Geim

    (University of Manchester
    University of Manchester)

  • Sheng Hu

    (Xiamen University)

Abstract

Nanoporous membranes based on two dimensional materials are predicted to provide highly selective gas transport in combination with extreme permeance. Here we investigate membranes made from multilayer graphdiyne, a graphene-like crystal with a larger unit cell. Despite being nearly a hundred of nanometers thick, the membranes allow fast, Knudsen-type permeation of light gases such as helium and hydrogen whereas heavy noble gases like xenon exhibit strongly suppressed flows. Using isotope and cryogenic temperature measurements, the seemingly conflicting characteristics are explained by a high density of straight-through holes (direct porosity of ∼0.1%), in which heavy atoms are adsorbed on the walls, partially blocking Knudsen flows. Our work offers important insights into intricate transport mechanisms playing a role at nanoscale.

Suggested Citation

  • Zhihua Zhou & Yongtao Tan & Qian Yang & Achintya Bera & Zecheng Xiong & Mehmet Yagmurcukardes & Minsoo Kim & Yichao Zou & Guanghua Wang & Artem Mishchenko & Ivan Timokhin & Canbin Wang & Hao Wang & Ch, 2022. "Gas permeation through graphdiyne-based nanoporous membranes," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-31779-2
    DOI: 10.1038/s41467-022-31779-2
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    References listed on IDEAS

    as
    1. S. Hu & M. Lozada-Hidalgo & F. C. Wang & A. Mishchenko & F. Schedin & R. R. Nair & E. W. Hill & D. W. Boukhvalov & M. I. Katsnelson & R. A. W. Dryfe & I. V. Grigorieva & H. A. Wu & A. K. Geim, 2014. "Proton transport through one-atom-thick crystals," Nature, Nature, vol. 516(7530), pages 227-230, December.
    2. P. Z. Sun & Q. Yang & W. J. Kuang & Y. V. Stebunov & W. Q. Xiong & J. Yu & R. R. Nair & M. I. Katsnelson & S. J. Yuan & I. V. Grigorieva & M. Lozada-Hidalgo & F. C. Wang & A. K. Geim, 2020. "Limits on gas impermeability of graphene," Nature, Nature, vol. 579(7798), pages 229-232, March.
    3. P. Z. Sun & M. Yagmurcukardes & R. Zhang & W. J. Kuang & M. Lozada-Hidalgo & B. L. Liu & H.-M. Cheng & F. C. Wang & F. M. Peeters & I. V. Grigorieva & A. K. Geim, 2021. "Exponentially selective molecular sieving through angstrom pores," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
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