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Unassisted selective solar hydrogen peroxide production by an oxidised buckypaper-integrated perovskite photocathode

Author

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  • Rashmi Mehrotra

    (Ulsan National Institute of Science and Technology (UNIST)
    Ulsan National Institute of Science and Technology (UNIST))

  • Dongrak Oh

    (Ulsan National Institute of Science and Technology (UNIST)
    Ulsan National Institute of Science and Technology (UNIST))

  • Ji-Wook Jang

    (Ulsan National Institute of Science and Technology (UNIST)
    Ulsan National Institute of Science and Technology (UNIST)
    Ulsan National Institute of Science and Technology (UNIST))

Abstract

Hydrogen peroxide (H2O2) is an eco-friendly oxidant and a promising energy source possessing comparable energy density to that of compressed H2. The current H2O2 production strategies mostly depend on the anthraquinone oxidation process, which requires significant energy and numerous organic chemicals. Photocatalyst-based solar H2O2 production comprises single-step O2 reduction to H2O2, which is a simple and eco-friendly method. However, the solar-to-H2O2 conversion efficiency is limited by the low performance of the inorganic semiconductor-based photoelectrodes and low selectivity and stability of the H2O2 production electrocatalyst. Herein, we demonstrate unassisted solar H2O2 production using an oxidised buckypaper as the H2O2 electrocatalyst combined with a high-performance inorganic-organic hybrid (perovskite) photocathode, without the need for additional bias or sacrificial agents. This integrated photoelectrode system shows 100% selectivity toward H2O2 and a solar-to-chemical conversion efficiency of ~1.463%.

Suggested Citation

  • Rashmi Mehrotra & Dongrak Oh & Ji-Wook Jang, 2021. "Unassisted selective solar hydrogen peroxide production by an oxidised buckypaper-integrated perovskite photocathode," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26832-5
    DOI: 10.1038/s41467-021-26832-5
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    1. Je Min Yu & Jungho Lee & Yoon Seo Kim & Jaejung Song & Jiyeon Oh & Sang Myeon Lee & Mingyu Jeong & Yongseon Kim & Ja Hun Kwak & Seungho Cho & Changduk Yang & Ji-Wook Jang, 2020. "High-performance and stable photoelectrochemical water splitting cell with organic-photoactive-layer-based photoanode," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    2. Gao-Feng Han & Feng Li & Wei Zou & Mohammadreza Karamad & Jong-Pil Jeon & Seong-Wook Kim & Seok-Jin Kim & Yunfei Bu & Zhengping Fu & Yalin Lu & Samira Siahrostami & Jong-Beom Baek, 2020. "Building and identifying highly active oxygenated groups in carbon materials for oxygen reduction to H2O2," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    3. Xiaopeng Zheng & Bo Chen & Jun Dai & Yanjun Fang & Yang Bai & Yuze Lin & Haotong Wei & Xiao Cheng Zeng & Jinsong Huang, 2017. "Defect passivation in hybrid perovskite solar cells using quaternary ammonium halide anions and cations," Nature Energy, Nature, vol. 2(7), pages 1-9, July.
    4. Lei Meng & Jingbi You & Yang Yang, 2018. "Addressing the stability issue of perovskite solar cells for commercial applications," Nature Communications, Nature, vol. 9(1), pages 1-4, December.
    5. Ji-Wook Jang & Chun Du & Yifan Ye & Yongjing Lin & Xiahui Yao & James Thorne & Erik Liu & Gregory McMahon & Junfa Zhu & Ali Javey & Jinghua Guo & Dunwei Wang, 2015. "Enabling unassisted solar water splitting by iron oxide and silicon," Nature Communications, Nature, vol. 6(1), pages 1-5, November.
    6. Kentaro Mase & Masaki Yoneda & Yusuke Yamada & Shunichi Fukuzumi, 2016. "Seawater usable for production and consumption of hydrogen peroxide as a solar fuel," Nature Communications, Nature, vol. 7(1), pages 1-7, September.
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    1. Chaoran Dong & Yilong Yang & Xuemin Hu & Yoonjun Cho & Gyuyong Jang & Yanhui Ao & Luyang Wang & Jinyou Shen & Jong Hyeok Park & Kan Zhang, 2022. "Self-cycled photo-Fenton-like system based on an artificial leaf with a solar-to-H2O2 conversion efficiency of 1.46%," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Hong-chao Li & Qiang Wan & Congcong Du & Jiafei Zhao & Fumin Li & Ying Zhang & Yanping Zheng & Mingshu Chen & Kelvin H. L. Zhang & Jianyu Huang & Gang Fu & Sen Lin & Xiaoqing Huang & Haifeng Xiong, 2022. "Layered Pd oxide on PdSn nanowires for boosting direct H2O2 synthesis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.

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