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Fe-promoted Ni catalyst with extremely high loading and oxygen vacancy for lipid deoxygenation into green diesel

Author

Listed:
  • Wang, Fei
  • Xu, Hui
  • Yu, Songyin
  • Zhu, Hao
  • Du, Yuchan
  • Zhang, Zeng
  • You, Chaoqun
  • Jiang, Xiaoxiang
  • Jiang, Jianchun

Abstract

The catalytic performance of Ni catalyst in lipid deoxygenation into green diesel is commonly limited by the quantity of accessible active sites, the specific surface area, and the acidity of the catalyst. To cope with these problems, the Fe-promoted Ni catalyst on ZrO2 with 60 wt% Ni loading (60%Ni–Fe/ZrO2) is synthesized by the co-precipitation method. The deoxygenation of oleic acid over 60%Ni–Fe/ZrO2 catalyst attained 98.7% conversion and 91.8% alkane yield, much higher than that of 20%Ni–Fe/ZrO2-2 prepared with the impregnation method (42.8% conversion and 16.2% alkane yield). The kinetics of octadecanol hydrotreatment revealed that the activation energy over 60%Ni–Fe/ZrO2 was much lower than Ni–Fe/ZrO2-2 (78.48 kJ/mol vs.191.90 kJ/mol). From the catalyst characterizations, the excellent performance of 60%Ni–Fe/ZrO2 was ascribed to its fine Ni particles, abundant Ni sites, high surface area, and coordinated acidity. Moreover, the mechanism of lipid deoxygenation over 60%Ni–Fe/ZrO2 was proposed.

Suggested Citation

  • Wang, Fei & Xu, Hui & Yu, Songyin & Zhu, Hao & Du, Yuchan & Zhang, Zeng & You, Chaoqun & Jiang, Xiaoxiang & Jiang, Jianchun, 2022. "Fe-promoted Ni catalyst with extremely high loading and oxygen vacancy for lipid deoxygenation into green diesel," Renewable Energy, Elsevier, vol. 197(C), pages 40-49.
    • Handle: RePEc:eee:renene:v:197:y:2022:i:c:p:40-49
    DOI: 10.1016/j.renene.2022.07.079
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    References listed on IDEAS

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    1. Lycourghiotis, Sotiris & Kordouli, Eleana & Kordulis, Christos & Bourikas, Kyriakos, 2021. "Transformation of residual fatty raw materials into third generation green diesel over a nickel catalyst supported on mineral palygorskite," Renewable Energy, Elsevier, vol. 180(C), pages 773-786.
    2. Cao, Xincheng & Long, Feng & Wang, Fei & Zhao, Jiaping & Xu, Junming & Jiang, Jianchun, 2021. "Chemoselective decarboxylation of higher aliphatic esters to diesel-range alkanes over the NiCu/Al2O3 bifunctional catalyst under mild reaction conditions," Renewable Energy, Elsevier, vol. 180(C), pages 1-13.
    3. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
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    Cited by:

    1. Tsiotsias, Anastasios I. & Hafeez, Sanaa & Charisiou, Nikolaos D. & Al-Salem, Sultan M. & Manos, George & Constantinou, Achilleas & AlKhoori, Sara & Sebastian, Victor & Hinder, Steven J. & Baker, Mark, 2023. "Selective catalytic deoxygenation of palm oil to produce green diesel over Ni catalysts supported on ZrO2 and CeO2–ZrO2: Experimental and process simulation modelling studies," Renewable Energy, Elsevier, vol. 206(C), pages 582-596.
    2. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.

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