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Local field in liquid dielectrics: A two-parameter mean field approach

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  • Bonneville, R.

Abstract

In the molecular field approximation, one derives an expression of the static dielectric constant of an isotropic liquid involving renormalized expressions of the molecular dipole and polarizability. The long-range moderate attractive forces are treated as a perturbation of the short-range intense repulsions, so that two parameters λ and η describe the short-range correlations and the long-range order, respectively. On the condition of a superposition hypothesis, the model is compared in its hard-sphere limit (λ=0, η=1) with the available experimental data about a series of organic liquids and with Onsager's continuum approach.

Suggested Citation

  • Bonneville, R., 1980. "Local field in liquid dielectrics: A two-parameter mean field approach," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 102(1), pages 49-69.
    • Handle: RePEc:eee:phsmap:v:102:y:1980:i:1:p:49-69
    DOI: 10.1016/0378-4371(80)90060-6
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    1. Korndörfer, Martin & Krumpal, Ivar & Schmukle, Stefan C., 2014. "Measuring and explaining tax evasion: Improving self-reports using the crosswise model," Journal of Economic Psychology, Elsevier, vol. 45(C), pages 18-32.

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