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Effect of low-temperature oxidation on the pyrolysis and combustion of whole oil

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  • Murugan, Pulikesi
  • Mahinpey, Nader
  • Mani, Thilakavathi
  • Asghari, Koorosh

Abstract

Low-temperature oxidation (LTO) of the Fosterton crude oil mixed with its reservoir sand has been investigated in a tubular reactor. Reservoir sand saturated with 15wt% of crude oil (20.5° API gravity) was subjected to air injection at low-temperature (220°C) for a period of time (17h and 30min), resulting in the formation of an oxygenated hydrocarbon fuel. The vent gases were analyzed for the content of CO, CO2, and oxygen and the residue was analyzed to determine the elemental composition and calorific value. The presence of LTO region was verified from the values of apparent H/C ratio. In addition, thermal behavior and combustion kinetics of the residue was investigated using thermogravimetric analysis (TGA). TG involves both non-isothermal and isothermal analysis and kinetic data was derived from isothermal studies. The general model for nth order reaction was used to obtain the kinetic parameters of the coke oxidation reaction. The activation energy, frequency factor and order of the reactions were determined using the model.

Suggested Citation

  • Murugan, Pulikesi & Mahinpey, Nader & Mani, Thilakavathi & Asghari, Koorosh, 2010. "Effect of low-temperature oxidation on the pyrolysis and combustion of whole oil," Energy, Elsevier, vol. 35(5), pages 2317-2322.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:5:p:2317-2322
    DOI: 10.1016/j.energy.2010.02.022
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    References listed on IDEAS

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    1. Onyekonwu, M.O. & Falade, G.K., 1989. "Recovery of light oil using in situ combustion thermal recovery methods," Energy, Elsevier, vol. 14(3), pages 153-159.
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    Cited by:

    1. Versan KOK, Mustafa, 2011. "Thermo-oxidative characterization and kinetics of tar sands," Energy, Elsevier, vol. 36(8), pages 5338-5342.
    2. Yang, Junyu & Xu, Qianghui & Jiang, Hang & Shi, Lin, 2021. "Reaction model of low asphaltene heavy oil from ramped temperature oxidation experimental analyses and numerical simulations," Energy, Elsevier, vol. 219(C).
    3. Zhao, Shuai & Pu, Wanfen & Peng, Xiaoqiang & Zhang, Jizhou & Ren, Hao, 2021. "Low-temperature oxidation of heavy crude oil characterized by TG, DSC, GC-MS, and negative ion ESI FT-ICR MS," Energy, Elsevier, vol. 214(C).
    4. Khansari, Zeinab & Kapadia, Punitkumar & Mahinpey, Nader & Gates, Ian D., 2014. "A new reaction model for low temperature oxidation of heavy oil: Experiments and numerical modeling," Energy, Elsevier, vol. 64(C), pages 419-428.

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