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Hydrogen peroxide for improving premixed methane–air combustion

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  • Ting, David S.-K.
  • Reader, Graham T.

Abstract

In this study, the effects of hydrogen peroxide on laminar, premixed, methane–air flames at atmospheric pressure and temperature were investigated using CHEMKIN III and GRI 3.5 mechanism. The range of fuel/air equivalence ratio (φ) was varied from 0.6 to 1.2, and the amount of hydrogen peroxide was altered from 0% to 20% volumetric fraction of the methane–hydrogen peroxide (air excluded) mixture. The burning velocity was found to increase with increasing hydrogen peroxide addition, with a relatively larger increase for the fuel-richer mixtures (ΔSu up to 15 cm/s for φ≈1.2). The adiabatic flame temperature rose with hydrogen peroxide addition, and the temperature rise per unit hydrogen peroxide addition was more significantly (ΔT up to 100 K) for the leaner mixtures. For the same mixture stoichiometry, adding hydrogen peroxide also increased CO concentration and NOx emissions somewhat. Accordingly, the benefits of adding hydrogen peroxide to the combustion conditions considered here can be best realized by burning leaner mixtures.

Suggested Citation

  • Ting, David S.-K. & Reader, Graham T., 2005. "Hydrogen peroxide for improving premixed methane–air combustion," Energy, Elsevier, vol. 30(2), pages 313-322.
    • Handle: RePEc:eee:energy:v:30:y:2005:i:2:p:313-322
    DOI: 10.1016/j.energy.2004.04.039
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    Cited by:

    1. Wang, Shuofeng & Ji, Changwei & Zhang, Jian & Zhang, Bo, 2011. "Comparison of the performance of a spark-ignited gasoline engine blended with hydrogen and hydrogen–oxygen mixtures," Energy, Elsevier, vol. 36(10), pages 5832-5837.
    2. Wu, Fang-Hsien & Chen, Guan-Bang, 2020. "Numerical study of hydrogen peroxide enhancement of ammonia premixed flames," Energy, Elsevier, vol. 209(C).
    3. Chen, Guan-Bang & Li, Yueh-Heng & Cheng, Tsarng-Sheng & Chao, Yei-Chin, 2013. "Chemical effect of hydrogen peroxide addition on characteristics of methane–air combustion," Energy, Elsevier, vol. 55(C), pages 564-570.
    4. Nguyen, Kim-Bao & Dan, Tomohisa & Asano, Ichiro, 2014. "Combustion, performance and emission characteristics of direct injection diesel engine fueled by Jatropha hydrogen peroxide emulsion," Energy, Elsevier, vol. 74(C), pages 301-308.

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