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Effects of the carbonization temperature and intermediate cooling mode on the properties of coal-based activated carbon

Author

Listed:
  • Zhao, Can
  • Ge, Lichao
  • Li, Xi
  • Zuo, Mingjin
  • Xu, Chunyao
  • Chen, Simo
  • Li, Qian
  • Wang, Yang
  • Xu, Chang

Abstract

To optimize the production of coal-based activated carbon, the effects of carbonization temperature on the surface functional groups, crystal characteristics, degree of graphitization, thermal stability and mechanical strength of char were studied; additionally, the effects of intermediate cooling on the pore structure, adsorption capacity and mechanical strength of activated carbon were studied. The results showed that the raw material lost many functional groups during carbonization. Carbonization improved the degree of graphitization, thermal stability and mechanical strength of the raw material, and char with a high degree of graphitization, a high thermal stability and mechanical strength was obtained with a higher carbonization temperature. The activated carbon prepared by direct heating after carbonization had a more developed pore structure, adsorption capacity and mechanical strength. The pore structure of the activated carbon was mainly produced during activation. Finally, the optimal conditions were determined as follows: a carbonization temperature of 800 °C and direct heating for activation after carbonization. The yield of the activated carbon was 48.2%, the Brunauer–Emmett–Teller specific surface area was 494 m2∙g−1, the total pore volume was 0.29 cm3∙g−1, the iodine value was 785 mg∙g−1, the compressive strength was 23.5 daN, and the wear strength was 83.5%.

Suggested Citation

  • Zhao, Can & Ge, Lichao & Li, Xi & Zuo, Mingjin & Xu, Chunyao & Chen, Simo & Li, Qian & Wang, Yang & Xu, Chang, 2023. "Effects of the carbonization temperature and intermediate cooling mode on the properties of coal-based activated carbon," Energy, Elsevier, vol. 273(C).
  • Handle: RePEc:eee:energy:v:273:y:2023:i:c:s0360544223005716
    DOI: 10.1016/j.energy.2023.127177
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    References listed on IDEAS

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    1. Zhu, Wenkun & Li, Xiaohui & Sun, Rui & Yan, Yonghong & Liu, Jing & Wang, Zhuozhi & Yu, Xing, 2023. "Microstructural evolution of coal to char after pyrolysis using laser-induced breakdown spectroscopy and Raman spectroscopy," Energy, Elsevier, vol. 267(C).
    2. Ge, Lichao & Zhao, Can & Chen, Simo & Li, Qian & Zhou, Tianhong & Jiang, Han & Li, Xi & Wang, Yang & Xu, Chang, 2022. "An analysis of the carbonization process and volatile-release characteristics of coal-based activated carbon," Energy, Elsevier, vol. 257(C).
    3. Ge, Lichao & Zhao, Can & Zhou, Tianhong & Chen, Simo & Li, Qian & Wang, Xuguang & Shen, Dong & Wang, Yang & Xu, Chang, 2023. "An analysis of the carbonization process of coal-based activated carbon at different heating rates," Energy, Elsevier, vol. 267(C).
    4. Li, He & Shi, Shiliang & Lin, Baiquan & Lu, Jiexin & Ye, Qing & Lu, Yi & Wang, Zheng & Hong, Yidu & Zhu, Xiangnan, 2019. "Effects of microwave-assisted pyrolysis on the microstructure of bituminous coals," Energy, Elsevier, vol. 187(C).
    5. Xin, Lin & An, Mingyu & Feng, Mingze & Li, Kaixuan & Cheng, Weimin & Liu, Weitao & Hu, Xiangming & Wang, Zhigang & Han, Limin, 2021. "Study on pyrolysis characteristics of lump coal in the context of underground coal gasification," Energy, Elsevier, vol. 237(C).
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    1. Zhao, Can & Ge, Lichao & Zuo, Mingjin & Mai, Longhui & Chen, Simo & Li, Xiaolong & Li, Qian & Wang, Yang & Xu, Chang, 2023. "Study on the mechanical strength and iodine adsorption behavior of coal-based activated carbon based on orthogonal experiments," Energy, Elsevier, vol. 282(C).

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