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Investigation of an ammonium carbamate–based SCR system for NOx reduction in diesel engines under transient conditions

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  • Raza, Hassan
  • Woo, Sanghee
  • Kim, Hongsuk

Abstract

The deNOx performance of a selective catalytic reduction (SCR) system using ammonium carbamate (AC) was investigated and compared with that of a urea water solution (UWS). The effects of the NH3/NOx (α) ratio, injection threshold temperature (Tinj), and a zero-dimensional ammonia adsorption-desorption model on NOx conversion efficiency were evaluated. World harmonized transient cycle (WHTC) and non-road transient cycle (NRTC) tests were conducted using a 3.9-L diesel engine over a Cu-zeolite catalyst. The NOx conversion efficiency of AC in the WHTC and NRTC was increased compared with that of UWS during the cold phase by 6.43% and 8.71%, respectively, and during the hot phase by 14.79% and 11.93%, respectively. Gaseous ammonia injection at a low Tinj can explain improved deNOx performance, as increasing Tinj leads to a decrease in NOx conversion efficiency. Increasing the α ratio effectively increases NOx conversion efficiency, but a high α ratio leads to ammonia slip. Ammonia injection using a model-based control increased cold-start deNOx performance. These promising results provide an alternative pathway to controlling NOx emissions from heavy-duty diesel engines.

Suggested Citation

  • Raza, Hassan & Woo, Sanghee & Kim, Hongsuk, 2022. "Investigation of an ammonium carbamate–based SCR system for NOx reduction in diesel engines under transient conditions," Energy, Elsevier, vol. 251(C).
  • Handle: RePEc:eee:energy:v:251:y:2022:i:c:s0360544222008210
    DOI: 10.1016/j.energy.2022.123918
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    References listed on IDEAS

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    1. Kumar, Madan & Tsujimura, Taku & Suzuki, Yasumasa, 2018. "NOx model development and validation with diesel and hydrogen/diesel dual-fuel system on diesel engine," Energy, Elsevier, vol. 145(C), pages 496-506.
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    Cited by:

    1. Zhao, Weihua & Yan, Junhao & Gao, Suya & Lee, Timothy H. & Li, Xiangrong, 2022. "The combustion and emission characteristics of a common-rail diesel engine fueled with diesel and higher alcohols blends with a high blend ratio," Energy, Elsevier, vol. 261(PB).

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