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POLYMER BRUSH-INDUCED ELECTROLESS COPPER PLATING TO FABRICATE Cu/CaCO3 COMPOSITE POWDER

Author

Listed:
  • QIHONG LI

    (Guangxi Key Laboratory of Calcium Carbonate, Resources Comprehensive Utilization, College of Materials and Chemical Engineering, Hezhou University, Hezhou City 542899, P. R. China†Guangxi Hezhou Kelong Micro-powder Co., Ltd., Hezhou City 542899, P. R. China)

  • GUANGCHAO QIN

    (#x2020;Guangxi Hezhou Kelong Micro-powder Co., Ltd., Hezhou City 542899, P. R. China‡Department of Chemical and Materials Engineering, Hefei University, Hefei City 230601, P. R. China)

  • JUNJUN HUANG

    (#x2020;Guangxi Hezhou Kelong Micro-powder Co., Ltd., Hezhou City 542899, P. R. China‡Department of Chemical and Materials Engineering, Hefei University, Hefei City 230601, P. R. China)

  • CHENGMEI GUI

    (Guangxi Key Laboratory of Calcium Carbonate, Resources Comprehensive Utilization, College of Materials and Chemical Engineering, Hezhou University, Hezhou City 542899, P. R. China§College of Chemical and Material Engineering, Chaohu University, Hefei City, 230009, P. R. China)

  • JINGUO BEI

    (#x2020;Guangxi Hezhou Kelong Micro-powder Co., Ltd., Hezhou City 542899, P. R. China)

  • HUABIN HUANG

    (#x2020;Guangxi Hezhou Kelong Micro-powder Co., Ltd., Hezhou City 542899, P. R. China)

  • PENG LI

    (#x2020;Guangxi Hezhou Kelong Micro-powder Co., Ltd., Hezhou City 542899, P. R. China)

  • QIANG DONG

    (#x2021;Department of Chemical and Materials Engineering, Hefei University, Hefei City 230601, P. R. China)

  • ZHENMING CHEN

    (Guangxi Key Laboratory of Calcium Carbonate, Resources Comprehensive Utilization, College of Materials and Chemical Engineering, Hezhou University, Hezhou City 542899, P. R. China†Guangxi Hezhou Kelong Micro-powder Co., Ltd., Hezhou City 542899, P. R. China‡Department of Chemical and Materials Engineering, Hefei University, Hefei City 230601, P. R. China)

Abstract

Electroless plating can be used to prepare metal particle/CaCO3 composite powder, but the use of noble metal as catalytic site would increase the cost. In this work, we adopt the combined 3-amino-propyltriethoxysilane (KH550) modification and NiCl2 activation to coat CaCO3 powder by a uniform layer of Ni particles/polymer brush which acts as non-noble metal catalyst, then, a low-cost electroless plating to prepare Cu particle/CaCO3 composite powder was developed. Results showed hydrolyzed KH550 coated on the CaCO3 surface in the form of polymer brush. The active group on the polymer brush surface could chemisorb Ni2+ and then Ni particles/polymer brush was attached on its surface. The Ni particle/polymer brush structure acted as catalytic site and could catalyze electroless copper plating on its surface. The Mplated particle∕M(plated particle+CaCO3) is 1%, its average diameter is about 100nm. This means that the dependable technology has great potential application in preparing metal inorganic powder at a low cost.

Suggested Citation

  • Qihong Li & Guangchao Qin & Junjun Huang & Chengmei Gui & Jinguo Bei & Huabin Huang & Peng Li & Qiang Dong & Zhenming Chen, 2021. "POLYMER BRUSH-INDUCED ELECTROLESS COPPER PLATING TO FABRICATE Cu/CaCO3 COMPOSITE POWDER," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 28(02), pages 1-6, February.
    • Handle: RePEc:wsi:srlxxx:v:28:y:2021:i:02:n:s0218625x20500535
    DOI: 10.1142/S0218625X20500535
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