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FABRICATION OF BIPHASE BiVO4 PARTICLES WITH ENHANCED PHOTOCATALYTIC PERFORMANCE VIA A SURFACTANT-FREE HYDROTHERMAL ROUTE

Author

Listed:
  • HONGZHI QIAN

    (School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu 210044, P. R. China)

  • MIN LAI

    (School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu 210044, P. R. China†Collaborative Innovation Centre of Atmospheric Environment and Equipment Technology, Nanjing, Jiangsu 210044, P. R. China‡Jiangsu Research Center for Ocean Survey Technology, Nanjing, Jiangsu 210044, P. R. China)

  • XIAOGU HUANG

    (School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu 210044, P. R. China)

  • WEI WANG

    (School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu 210044, P. R. China)

  • CHAOQI XU

    (School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu 210044, P. R. China)

  • HAIBO YONG

    (School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu 210044, P. R. China)

  • YAN WEN

    (School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu 210044, P. R. China)

  • YINGJIE ZHOU

    (School of Physics and Optoelectronic Engineering, Nanjing University of Information Science and Technology, Nanjing, Jiangsu 210044, P. R. China)

Abstract

Biphase bismuth vanadate (BiVO4) particles have been synthesized using a surfactant-free hydrothermal strategy. Biphase BiVO4 were formed at pH=3, 5 and 7 with a bandgap between 2.28eV and 2.86eV, which are those of monoclinic and tetragonal phases, respectively. Photocatalytic tests on the degradation of rhodamine B (RhB) under visible-light irradiation showed that biphase BiVO4 with both monoclinic and tetragonal structures synthesized at pH=3 achieved enhanced photocatalytic performance in comparison with pure monoclinic and tetragonal phases, which was attributed to the heterostructures leading to low recombination rate of electron–hole pairs.

Suggested Citation

  • Hongzhi Qian & Min Lai & Xiaogu Huang & Wei Wang & Chaoqi Xu & Haibo Yong & Yan Wen & Yingjie Zhou, 2016. "FABRICATION OF BIPHASE BiVO4 PARTICLES WITH ENHANCED PHOTOCATALYTIC PERFORMANCE VIA A SURFACTANT-FREE HYDROTHERMAL ROUTE," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 23(05), pages 1-5, October.
  • Handle: RePEc:wsi:srlxxx:v:23:y:2016:i:05:n:s0218625x16500323
    DOI: 10.1142/S0218625X16500323
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    Keywords

    Biphase; BiVO4; heterostructures; photocatalytic performance;
    All these keywords.

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