IDEAS home Printed from https://ideas.repec.org/a/wsi/srlxxx/v15y2008i04ns0218625x08011512.html
   My bibliography  Save this article

Electronic And Structural Parameters Of Phosphorus–Oxygen Bonds In Inorganic Phosphate Crystals

Author

Listed:
  • V. V. ATUCHIN

    (Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russia)

  • V. G. KESLER

    (Laboratory of Physical Bases of Integrated Microelectronics, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russia)

  • N. V. PERVUKHINA

    (Laboratory of Crystal Chemistry, Institute of Inorganic Chemistry, SB RAS, Novosibirsk 630090, Russia)

Abstract

Wide set of experimental results on binding energy of photoelectrons emitted fromP2p,P2s, andO1score levels has been observed for inorganic phosphate crystals and the parameters were compared using energy differencesΔ(O1s-P2p)andΔ (O1s-P2s)as most robust characteristics. Linear dependence of the binding energy difference on mean chemical bond lengthL(P–O) between phosphorus and oxygen atoms has been found. The functions are of the forms:Δ (O1s-P2p) (eV) = 375.54 + 0.146 · L(P–O) (pm)andΔ (O1s-P2s) (eV) = 320.77 + 0.129 · L(P–O) (pm). The dependencies are general for inorganic phosphates and may be used in quantitative component analysis of X-ray photoemission spectra of complex oxide compounds including functional groups with different coordination ofPandOatoms.

Suggested Citation

  • V. V. Atuchin & V. G. Kesler & N. V. Pervukhina, 2008. "Electronic And Structural Parameters Of Phosphorus–Oxygen Bonds In Inorganic Phosphate Crystals," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 15(04), pages 391-399.
    • Handle: RePEc:wsi:srlxxx:v:15:y:2008:i:04:n:s0218625x08011512
    DOI: 10.1142/S0218625X08011512
    as

    Download full text from publisher

    File URL: http://www.worldscientific.com/doi/abs/10.1142/S0218625X08011512
    Download Restriction: Access to full text is restricted to subscribers
    File URL: https://libkey.io/10.1142/S0218625X08011512?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wsi:srlxxx:v:15:y:2008:i:04:n:s0218625x08011512. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Tai Tone Lim (email available below). General contact details of provider: http://www.worldscinet.com/srl/srl.shtml .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.