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SYMMETRY BREAKING OF ASiF4MOLECULE BY F1sEXCITATION

Author

Listed:
  • KAZUMASA OKADA

    (Department of Chemistry, Hiroshima University, Higashi-Hiroshima 739-8526, Japan)

  • YUSUKE TAMENORI

    (SPring-8/Japan Synchrotron Radiation Research Institute, Mikazuki, Hyogo 679-5198, Japan)

  • INOSUKE KOYANO

    (Department of Material Science, Himeji Institute of Technology, Kamigori, Hyogo 678-1297, Japan)

  • KIYOSHI UEDA

    (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan)

Abstract

Angle-resolved ion yield spectroscopy revealed that ionic fragmentation of aTdsymmetry moleculeSiF4is anisotropic after F1sphotoexcitation. The anisotropic fragmentation is interpreted as being due to preferential bond rupture at the F1score-hole site. The probability of the bond rupture at the core-hole site is three times as large as those at other sites. The origin of the preferential bond rupture is discussed in terms of symmetry breaking due to dynamical core-hole localization.

Suggested Citation

  • Kazumasa Okada & Yusuke Tamenori & Inosuke Koyano & Kiyoshi Ueda, 2002. "SYMMETRY BREAKING OF ASiF4MOLECULE BY F1sEXCITATION," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 9(01), pages 89-92.
    • Handle: RePEc:wsi:srlxxx:v:09:y:2002:i:01:n:s0218625x02001999
    DOI: 10.1142/S0218625X02001999
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