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Spectroscopy And Excited-State Dynamics Of Benzene-Trimer Ion

Author

Listed:
  • K. OHASHI

    (Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Fukuoka 812, Japan)

  • Y. NAKAI

    (Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Fukuoka 812, Japan)

  • T. SHIBATA

    (Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Fukuoka 812, Japan)

  • N. NISHI

    (Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Fukuoka 812, Japan)

Abstract

The photodissociation of(C6H6)3+is studied in the rangehν=0.9–3.0eV. The electronic spectrum of(C6H6)3+shows the main band athν≈1.29eVand a side band at ≈1.02 eV. The(C6H6)3+ion retains spectroscopic features characteristic of(C6H6)2+, suggesting that the positive charge is carried by a dimer subunit in(C6H6)3+. The major fragment ion changes smoothly from(C6H6)2+toC6H6+with increasing photon energy from 0.9 to 1.8 eV. The product branching ratios and the kinetic energy of theC6H6+fragment are consistent with a two-step model for the formation ofC6H6+.

Suggested Citation

  • K. Ohashi & Y. Nakai & T. Shibata & N. Nishi, 1996. "Spectroscopy And Excited-State Dynamics Of Benzene-Trimer Ion," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 3(01), pages 601-605.
    • Handle: RePEc:wsi:srlxxx:v:03:y:1996:i:01:n:s0218625x9600108x
    DOI: 10.1142/S0218625X9600108X
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