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PROTON TUNNELING IN THE S1STATE OF TROPOLONE–M1(M=Ar,Kr,Xe,CH4,CD4,N2)CLUSTERS

Author

Listed:
  • H. SEKIYA

    (Institute of Advanced Material Study, and Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University, Kasuga-shi, Fukuoka 816, Japan)

  • H. HAMABE

    (Institute of Advanced Material Study, and Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University, Kasuga-shi, Fukuoka 816, Japan)

  • T. NAKAJIMA

    (Institute of Advanced Material Study, and Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University, Kasuga-shi, Fukuoka 816, Japan)

  • Y. NISHIMURA

    (Institute of Advanced Material Study, and Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University, Kasuga-shi, Fukuoka 816, Japan)

Abstract

TheS1←S0fluorescence excitation spectra of jet-cooled tropolone–M1(M=Ar,Kr,Xe,CH4,CD4,N2)clusters have been measured to investigate the effect of intermolecular interactions on proton tunneling. It has been found that the${\rm O}_0^0 $tunneling splittings of tropolone–CH4/CD4and tropolone–N2are significantly smaller than that of tropolone.

Suggested Citation

  • H. Sekiya & H. Hamabe & T. Nakajima & Y. Nishimura, 1996. "PROTON TUNNELING IN THE S1STATE OF TROPOLONE–M1(M=Ar,Kr,Xe,CH4,CD4,N2)CLUSTERS," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 3(01), pages 493-497.
    • Handle: RePEc:wsi:srlxxx:v:03:y:1996:i:01:n:s0218625x96000899
    DOI: 10.1142/S0218625X96000899
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