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Dipole Activity And Polarisation Of Surface Phonons In Thin Ionic Films

Author

Listed:
  • M.B. LEE

    (IRC Surface Science, Univ. of Liverpool, P.O. Box 147, Liverpool L69 3BX, UK)

  • B.G. FREDERICK

    (IRC Surface Science, Univ. of Liverpool, P.O. Box 147, Liverpool L69 3BX, UK)

  • G. APAI

    (Analytical Technology Divison, Kodak Research Laboratories, Eastman-Kodak Co., Rochester, NY 14652, USA)

Abstract

Surface phonon spectra in ultrathinα-Al2O3films prepared on metallic substrates show excitation of modes in the frequency range of the surface dipole forbidden ω_-branches according to the dielectric theory of EELS. We compare calculations of thez-polarisation of the FuchsKliewer modes based on lattice dynamics with dielectric theory and semi-microscopic results for a simple NaCl lattice type thin film in the limit ofk→0 appropriate to the dipolar-scattering regime. The form of the primary-beam-energy-dependence of the ω_-branch in thinα-Al2O3films is similar to the lattice dynamics prediction but is of much greater intensity. While the strongk-dependence may be attributed in part to significantz-polarisation of the ω_-branch, mixing with microscopic surface modes seems likely.

Suggested Citation

  • M.B. Lee & B.G. Frederick & G. Apai, 1994. "Dipole Activity And Polarisation Of Surface Phonons In Thin Ionic Films," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 1(04), pages 635-639.
  • Handle: RePEc:wsi:srlxxx:v:01:y:1994:i:04:n:s0218625x94000837
    DOI: 10.1142/S0218625X94000837
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