IDEAS home Printed from https://ideas.repec.org/a/wly/greenh/v11y2021i2p313-330.html
   My bibliography  Save this article

Investigation of cellulose acetate/gamma‐cyclodextrin MOF based mixed matrix membranes for CO2/CH4 gas separation

Author

Listed:
  • Ovaid Mehmood
  • Sarah Farrukh
  • Arshad Hussain
  • Mohammad Younas
  • Zarrar Salahuddin
  • Erum Pervaiz
  • Muhammad Ayoub

Abstract

This work is aimed to investigate the permeation characteristic of CA/γ‐CD‐metal organic framework (MOF) based mixed matrix membranes (MMM) for CO2/CH4 separation. The defect‐free CA/γ‐CD‐MOF MMMs with dense, isotropic morphology were fabricated using solution casting method. The fabricated membranes were characterized through Fourier transform infrared spectroscopy (FT‐IR), X‐ray diffraction (XRD), scanning electron microscopy (SEM), ultimate tensile testing, and contact angle measurements. The characterization techniques revealed the uniform dispersion of filler in cellulose acetate matrix and absence of the agglomerates or cracks in the synthesized membrane samples. Moreover, the CO2/CH4 separation performance of fabricated membrane was evaluated using single and mixed gas permeation tests. A general trend of decreasing permeability and selectivity, that is, 36.79–35 of both CO2 and CH4 was observed by increasing the filler weight percentage (0.2–1.0) and pressure (1–5 bar). However, the highest CO2/CH4 selectivity of 38.49 was achieved by CA/γ‐CD‐MOF 0.4wt% MMM. © 2021 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • Ovaid Mehmood & Sarah Farrukh & Arshad Hussain & Mohammad Younas & Zarrar Salahuddin & Erum Pervaiz & Muhammad Ayoub, 2021. "Investigation of cellulose acetate/gamma‐cyclodextrin MOF based mixed matrix membranes for CO2/CH4 gas separation," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(2), pages 313-330, April.
    • Handle: RePEc:wly:greenh:v:11:y:2021:i:2:p:313-330
    DOI: 10.1002/ghg.2050
    as

    Download full text from publisher

    File URL: https://doi.org/10.1002/ghg.2050
    Download Restriction: no
    File URL: https://libkey.io/10.1002/ghg.2050?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Yangyang Liu & Zhiyong U. Wang & Hong‐Cai Zhou, 2012. "Recent advances in carbon dioxide capture with metal‐organic frameworks," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 2(4), pages 239-259, August.
    2. Hamidreza Sanaeepur & Bahram Nasernejad & Ali Kargari, 2015. "Cellulose acetate/nano‐porous zeolite mixed matrix membrane for CO2 separation," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 5(3), pages 291-304, June.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jia Yen Lai & Lock Hei Ngu & Siti Salwa Hashim, 2021. "A review of CO2 adsorbents performance for different carbon capture technology processes conditions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(5), pages 1076-1117, October.
    2. Slyvester Yew Wang Chai & Lock Hei Ngu & Bing Shen How, 2022. "Review of carbon capture absorbents for CO2 utilization," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 12(3), pages 394-427, June.
    3. Nicholas S. Siefert & Sarah Narburgh & Yang Chen, 2016. "Comprehensive Exergy Analysis of Three IGCC Power Plant Configurations with CO 2 Capture," Energies, MDPI, vol. 9(9), pages 1-19, August.
    4. Suwimol Wongsakulphasatch & Worapon Kiatkittipong & Janenipa Saupsor & Jatuphol Chaiwiseshphol & Pakorn Piroonlerkgul & Vudhichai Parasuk & Suttichai Assabumrungrat, 2017. "Effect of Fe open metal site in metal‐organic frameworks on post‐combustion CO 2 capture performance," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(2), pages 383-394, April.
    5. Taheri Najafabadi, Amin, 2015. "Emerging applications of graphene and its derivatives in carbon capture and conversion: Current status and future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1515-1545.
    6. Qiang Yang & Qianguo Lin & Sergio Sammarchi & Jia Li & Sa Li & Dong Wang, 2021. "Water vapor effects on CO2 separation of amine‐containing facilitated transport membranes (AFTMs) module: mathematical modeling using tanks‐in‐series approach," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(1), pages 52-68, February.
    7. Sittichain Pramchu & Atchara P. Jaroenjittichai & Yongyut Laosiritaworn, 2018. "Tuning carbon dioxide capture capability with structural and compositional design in mmen‐(Mg,Zn) (dobpdc) metal‐organic framework: density functional theory investigation," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(3), pages 580-586, June.
    8. Alfe, M. & Policicchio, A. & Lisi, L. & Gargiulo, V., 2021. "Solid sorbents for CO2 and CH4 adsorption: The effect of metal organic framework hybridization with graphene-like layers on the gas sorption capacities at high pressure," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wly:greenh:v:11:y:2021:i:2:p:313-330. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Wiley Content Delivery (email available below). General contact details of provider: https://doi.org/10.1002/(ISSN)2152-3878 .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.