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Group-embeddings for NMR spin dual symmetries, to λ SA ⊢ n: Determinate [ 10 BH] 12 2− $\left( {SU\left( {m \leqslant 12} \right) \times \mathcal{S}_{12} \downarrow \mathcal{I}} \right)$ natural subduction via symbolic $\mathcal{S}_n$ combinatorial generators: Complete sets of bijective maps, CNP-weights

Author

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  • F. Temme

Abstract

Modelling of the properties of high-spin isotopomers, as polyhedra- on-lattice-points which yield various symbolic-computational ${\mathcal{S}_{12} }$ -encodings of nuclear permutation (upto some specific SU(m) branching level), is important in deriving the spin-ensemble weightings of clusters, or cage-molecules. The mathematical determinacies of these, obtained here for higher m-valued $SU\left( m \right) \times \mathcal{S}_{12} \downarrow \mathcal{I}$ group embeddings, are compared with that of an established group embedding, in order to collate the spin physics of [ 11 BH] 12 2− $\left( {SU\left( {2\left( {m \leqslant 4} \right)} \right) \times \mathcal{S}_{12} \downarrow \mathcal{I}} \right)$ with that for [ 10 BH] 12 2− (SU(m ≤ 7) × ..)-analogue. The most symmetrical form of $\left[ {\left( {^{10} BH} \right) \left( {^{11} BH} \right)} \right]_6^{2 - } \left( {\left( {\mathcal{S}_6 \otimes \mathcal{S}_6 } \right) \downarrow \left( {\mathcal{S}_3 \otimes \mathcal{S}_3 } \right)} \right)$ anion provides a pertinent example of the $SU\left( {m > n} \right) \times \mathcal{S}_n \downarrow \mathcal{G}$ physics discussed in [10]. Retention of determinacy in the two $\mathcal{S}_{12} \downarrow \mathcal{I}$ cases is correlated to the completeness of the 1:1 bijective maps for natural embeddings of automorphic dual group NMR spin symmetries. The Kostka transformational coefficients of a suitable model ( $\mathcal{S}_n$ module, Schur fn.) play a important role. Our findings demonstrate that determinacy persists (to $SU\left( {m \sim {n \mathord{\left/ {\vphantom {n 2}} \right. \kern-\nulldelimiterspace} 2}} \right)\mathcal{S}_n$ branching levels) more readily for embeddings derived from (automorphic) finite groups dominated by odd-permutational class algebras, such as the above $\mathcal{S}_{12} \downarrow \mathcal{I}$ , or the $SU\left( {m \leqslant 3} \right) \times \mathcal{S}_6 \downarrow \mathcal{D}_3$ case discussed in [16a,15,3d], compared to other examples — (e.g. as respectively, in press, and in [17b]): $SU\left( m \right) \times \mathcal{S}_8 \downarrow \mathcal{D}_4$ , $SU\left( m \right) \times \mathcal{S}_{10} \downarrow \mathcal{D}_5$ . Generality of the symbolic algorithmic difference approach is stressed throughout and the corresponding dodecahedral $SU\left( m \right) \times \mathcal{S}_{20} \downarrow \mathcal{I}$ maps are outlined briefly — for the wider applicability of SF-difference mappings, or of comparable $\mathcal{S}_n$ -symbolic methods, (e.g.) via [7]. Copyright Società Italiana di Fisica, Springer-Verlag 1999

Suggested Citation

  • F. Temme, 1999. "Group-embeddings for NMR spin dual symmetries, to λ SA ⊢ n: Determinate [ 10 BH] 12 2− $\left( {SU\left( {m \leqslant 12} \right) \times \mathcal{S}_{12} \downarrow \mathcal{I}} \right)$ natural subdu," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 11(1), pages 177-185, September.
  • Handle: RePEc:spr:eurphb:v:11:y:1999:i:1:p:177-185:10.1007/s100510050927
    DOI: 10.1007/s100510050927
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