Hydrochemical characterization of groundwater quality using chemometric analysis and water quality indices in the foothills of Himalayas

Groundwater pollution of the watershed is mainly influenced by the multifaceted interactions of natural and anthropogenic process. To analyse the spatial–temporal variation and pollution source identification and apportionment, the dataset was subjected to a globally acknowledged coherent technique using water quality indices and chemometric techniques (principal component analysis (PCA) and cluster analysis. The bulk of the samples tested were below the BIS’s permissible levels. Groundwater samples from the pre- and post-monsoon seasons mostly contained the anions HCO−3 > Cl− > SO2−4 > NO−3, while the primary cations were Ca2+ > Mg2+ > Na+ > K+. Groundwater was alkaline and hard at most of the sites. According to hydro-geochemical facies and relationships, Piper diagrams, and principal component analysis, weathering, dissolution, leaching, ion exchange, and evaporation were the key mechanisms influencing groundwater quality. The hydrochemical facies classified the groundwater samples into the Ca-Mg-HCO3 type. For all the sampling locations, PIG was determined to be 0.43, 0.52, 0.47, 0.48, 1.00, and 0.70; respectively. The majority of the test locations fell into the low to medium contamination zone, as determined by the groundwater pollution index (PIG) and contamination index. Three principal components, which together account for 93.8% of the total variance, were identified via PCA. The study’s findings confirm the value of these statistical techniques in interpreting and understanding large datasets and offering reliable information to reduce the time and expense of programmes for monitoring and evaluating water quality.