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Metal–organic frameworks as selectivity regulators for hydrogenation reactions

Author

Listed:
  • Meiting Zhao

    (Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Kuo Yuan

    (Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
    School of Science, Tianjin University)

  • Yun Wang

    (Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University)

  • Guodong Li

    (Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Jun Guo

    (Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

  • Lin Gu

    (Institute of Physics, Chinese Academy of Sciences)

  • Wenping Hu

    (School of Science, Tianjin University
    Institute of Chemistry, Chinese Academy of Sciences)

  • Huijun Zhao

    (Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University)

  • Zhiyong Tang

    (Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology)

Abstract

The flavouring, perfume and pharmaceutical industries rely on the selective hydrogenation of α,β-unsaturated aldehydes to generate unsaturated alcohols; here, a new type of highly selective catalyst is described in which platinum nanoparticles are sandwiched between a core and a shell of a metal−organic framework.

Suggested Citation

  • Meiting Zhao & Kuo Yuan & Yun Wang & Guodong Li & Jun Guo & Lin Gu & Wenping Hu & Huijun Zhao & Zhiyong Tang, 2016. "Metal–organic frameworks as selectivity regulators for hydrogenation reactions," Nature, Nature, vol. 539(7627), pages 76-80, November.
    • Handle: RePEc:nat:nature:v:539:y:2016:i:7627:d:10.1038_nature19763
    DOI: 10.1038/nature19763
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    Citations

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    Cited by:

    1. Chuanhui Huang & Xinglong Shang & Xinyuan Zhou & Zhe Zhang & Xing Huang & Yang Lu & Mingchao Wang & Markus Löffler & Zhongquan Liao & Haoyuan Qi & Ute Kaiser & Dana Schwarz & Andreas Fery & Tie Wang &, 2023. "Hierarchical conductive metal-organic framework films enabling efficient interfacial mass transfer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Siliu Lyu & Chenxi Guo & Jianing Wang & Zhongjian Li & Bin Yang & Lecheng Lei & Liping Wang & Jianping Xiao & Tao Zhang & Yang Hou, 2022. "Exceptional catalytic activity of oxygen evolution reaction via two-dimensional graphene multilayer confined metal-organic frameworks," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Minchao Liu & Cheng Shang & Tiancong Zhao & Hongyue Yu & Yufang Kou & Zirui Lv & Mengmeng Hou & Fan Zhang & Qiaowei Li & Dongyuan Zhao & Xiaomin Li, 2023. "Site-specific anisotropic assembly of amorphous mesoporous subunits on crystalline metal–organic framework," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Li Zhai & Sara T. Gebre & Bo Chen & Dan Xu & Junze Chen & Zijian Li & Yawei Liu & Hua Yang & Chongyi Ling & Yiyao Ge & Wei Zhai & Changsheng Chen & Lu Ma & Qinghua Zhang & Xuefei Li & Yujie Yan & Xiny, 2023. "Epitaxial growth of highly symmetrical branched noble metal-semiconductor heterostructures with efficient plasmon-induced hot-electron transfer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Xiao Zhan & Miao Li & Xiaolin Zhao & Yaning Wang & Sha Li & Weiwei Wang & Jiande Lin & Zi-Ang Nan & Jiawei Yan & Zhefei Sun & Haodong Liu & Fei Wang & Jiayu Wan & Jianjun Liu & Qiaobao Zhang & Li Zhan, 2024. "Self-assembled hydrated copper coordination compounds as ionic conductors for room temperature solid-state batteries," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    6. Sirong Li & Zijun Zhou & Zuoxiu Tie & Bing Wang & Meng Ye & Lei Du & Ran Cui & Wei Liu & Cuihong Wan & Quanyi Liu & Sheng Zhao & Quan Wang & Yihong Zhang & Shuo Zhang & Huigang Zhang & Yan Du & Hui We, 2022. "Data-informed discovery of hydrolytic nanozymes," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    7. Wenlong Xu & Yuwei Zhang & Junjun Wang & Yixiu Xu & Li Bian & Qiang Ju & Yuemin Wang & Zhenlan Fang, 2022. "Defects engineering simultaneously enhances activity and recyclability of MOFs in selective hydrogenation of biomass," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    8. Hui Su & Wanlin Zhou & Wu Zhou & Yuanli Li & Lirong Zheng & Hui Zhang & Meihuan Liu & Xiuxiu Zhang & Xuan Sun & Yanzhi Xu & Fengchun Hu & Jing Zhang & Tiandou Hu & Qinghua Liu & Shiqiang Wei, 2021. "In-situ spectroscopic observation of dynamic-coupling oxygen on atomically dispersed iridium electrocatalyst for acidic water oxidation," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    9. Miao Guo & Sanjeevi Jayakumar & Mengfei Luo & Xiangtao Kong & Chunzhi Li & He Li & Jian Chen & Qihua Yang, 2022. "The promotion effect of π-π interactions in Pd NPs catalysed selective hydrogenation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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