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Multicolor hyperafterglow from isolated fluorescence chromophores

Author

Listed:
  • Xiao Zhang

    (Nanjing University of Posts & Telecommunications)

  • Mingjian Zeng

    (Nanjing University of Posts & Telecommunications)

  • Yewen Zhang

    (Nanjing University of Posts & Telecommunications)

  • Chenyu Zhang

    (Nanjing University of Posts & Telecommunications)

  • Zhisheng Gao

    (Nanjing University of Posts & Telecommunications)

  • Fei He

    (Nanjing University of Posts & Telecommunications)

  • Xudong Xue

    (Nanjing University of Posts & Telecommunications)

  • Huanhuan Li

    (Nanjing University of Posts & Telecommunications)

  • Ping Li

    (Nanjing University of Posts & Telecommunications)

  • Gaozhan Xie

    (Nanjing University of Posts & Telecommunications)

  • Hui Li

    (Nanjing University of Posts & Telecommunications)

  • Xin Zhang

    (Nanjing University of Posts & Telecommunications)

  • Ningning Guo

    (Nanjing University of Posts & Telecommunications)

  • He Cheng

    (Nanjing University of Posts & Telecommunications)

  • Ansheng Luo

    (Nanjing University of Posts & Telecommunications)

  • Wei Zhao

    (Nanjing University of Posts & Telecommunications)

  • Yizhou Zhang

    (Institute of Advanced Materials and Flexible Electronics (IAMFE) Nanjing University of Information Science and Technology)

  • Ye Tao

    (Nanjing University of Posts & Telecommunications)

  • Runfeng Chen

    (Nanjing University of Posts & Telecommunications)

  • Wei Huang

    (Nanjing University of Posts & Telecommunications
    Northwestern Polytechnical University)

Abstract

High-efficiency narrowband emission is always in the central role of organic optoelectronic display applications. However, the development of organic afterglow materials with sufficient color purity and high quantum efficiency for hyperafterglow is still great challenging due to the large structural relaxation and severe non-radiative decay of triplet excitons. Here we demonstrate a simple yet efficient strategy to achieve hyperafterglow emission through sensitizing and stabilizing isolated fluorescence chromophores by integrating multi-resonance fluorescence chromophores into afterglow host in a single-component copolymer. Bright multicolor hyperafterglow with maximum photoluminescent efficiencies of 88.9%, minimum full-width at half-maximums (FWHMs) of 38 nm and ultralong lifetimes of 1.64 s under ambient conditions are achieved. With this facilely designed polymer, a large-area hyperafterglow display panel was fabricated. By virtue of narrow emission band and high luminescent efficiency, the hyperafterglow presents a significant technological advance in developing highly efficient organic afterglow materials and extends the domain to new applications.

Suggested Citation

  • Xiao Zhang & Mingjian Zeng & Yewen Zhang & Chenyu Zhang & Zhisheng Gao & Fei He & Xudong Xue & Huanhuan Li & Ping Li & Gaozhan Xie & Hui Li & Xin Zhang & Ningning Guo & He Cheng & Ansheng Luo & Wei Zh, 2023. "Multicolor hyperafterglow from isolated fluorescence chromophores," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36105-y
    DOI: 10.1038/s41467-023-36105-y
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    References listed on IDEAS

    as
    1. Xin Ai & Emrys W. Evans & Shengzhi Dong & Alexander J. Gillett & Haoqing Guo & Yingxin Chen & Timothy J. H. Hele & Richard H. Friend & Feng Li, 2018. "Efficient radical-based light-emitting diodes with doublet emission," Nature, Nature, vol. 563(7732), pages 536-540, November.
    2. Jibiao Jin & He Jiang & Qingqing Yang & Lele Tang & Ye Tao & Yuanyuan Li & Runfeng Chen & Chao Zheng & Quli Fan & Kenneth Yin Zhang & Qiang Zhao & Wei Huang, 2020. "Thermally activated triplet exciton release for highly efficient tri-mode organic afterglow," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    3. Tao Wang & Zhubin Hu & Xiancheng Nie & Linkun Huang & Miao Hui & Xiang Sun & Guoqing Zhang, 2021. "Thermochromic aggregation-induced dual phosphorescence via temperature-dependent sp3-linked donor-acceptor electronic coupling," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    4. Hui Li & Jie Gu & Zijie Wang & Juan Wang & Fei He & Ping Li & Ye Tao & Huanhuan Li & Gaozhan Xie & Wei Huang & Chao Zheng & Runfeng Chen, 2022. "Single-component color-tunable circularly polarized organic afterglow through chiral clusterization," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    5. Yongfeng Zhang & Liang Gao & Xian Zheng & Zhonghao Wang & Chaolong Yang & Hailong Tang & Lunjun Qu & Youbing Li & Yanli Zhao, 2021. "Ultraviolet irradiation-responsive dynamic ultralong organic phosphorescence in polymeric systems," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    6. Xing Wang Liu & Weijun Zhao & Yue Wu & Zhengong Meng & Zikai He & Xin Qi & Yiran Ren & Zhen-Qiang Yu & Ben Zhong Tang, 2022. "Photo-thermo-induced room-temperature phosphorescence through solid-state molecular motion," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. Ryota Kabe & Chihaya Adachi, 2017. "Organic long persistent luminescence," Nature, Nature, vol. 550(7676), pages 384-387, October.
    8. Long Gu & Hongwei Wu & Huili Ma & Wenpeng Ye & Wenyong Jia & He Wang & Hongzhong Chen & Nan Zhang & Dongdong Wang & Cheng Qian & Zhongfu An & Wei Huang & Yanli Zhao, 2020. "Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    9. Dan Li & Yujie Yang & Jie Yang & Manman Fang & Ben Zhong Tang & Zhen Li, 2022. "Completely aqueous processable stimulus responsive organic room temperature phosphorescence materials with tunable afterglow color," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
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    Cited by:

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    2. Zongliang Xie & Yufeng Xue & Xianhe Zhang & Junru Chen & Zesen Lin & Bin Liu, 2024. "Isostructural doping for organic persistent mechanoluminescence," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Wenqing Xu & Guanheng Huang & Zhan Yang & Ziqi Deng & Chen Zhou & Jian-An Li & Ming-De Li & Tao Hu & Ben Zhong Tang & David Lee Phillips, 2024. "Nucleic-acid-base photofunctional cocrystal for information security and antimicrobial applications," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    4. Liang Gao & Jiayue Huang & Lunjun Qu & Xiaohong Chen & Ying Zhu & Chen Li & Quanchi Tian & Yanli Zhao & Chaolong Yang, 2023. "Stepwise taming of triplet excitons via multiple confinements in intrinsic polymers for long-lived room-temperature phosphorescence," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Kaijun Chen & Yongfeng Zhang & Yunxiang Lei & Wenbo Dai & Miaochang Liu & Zhengxu Cai & Huayue Wu & Xiaobo Huang & Xiang Ma, 2024. "Twofold rigidity activates ultralong organic high-temperature phosphorescence," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

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